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The nature of the lattice instability connected to the structural transition and superconductivity of (Sr,Ca)$_3$Ir$_4$Sn$_{13}$ is not yet fully understood. In this work density functional theory (DFT) calculations of the phonon…

Superconductivity · Physics 2014-02-20 David A. Tompsett

Electron-phonon superconductors at high pressures have displayed the highest values of critical superconducting temperature $T_c$ on record, now rapidly approaching room temperature. Despite the importance of high-$P$ superconductivity in…

Superconductivity · Physics 2021-04-07 Chandan Setty , Matteo Baggioli , Alessio Zaccone

We present a constrained density functional perturbation theory scheme for the calculation of structural and harmonic vibrational properties of insulators in the presence of an excited and thermalized electron-hole plasma. The method is…

Materials Science · Physics 2021-10-13 Giovanni Marini , Matteo Calandra

We investigate phonon transport in perovskite strontium titanate (SrTiO3) which is stable above its phase transition temperature (~105 K) by using first-principles molecular dynamics and anharmonic lattice dynamics. Unlike conventional…

Computational Physics · Physics 2015-06-09 Lei Feng , Takuma Shiga , Junichiro Shiomi

The ability to finely tune optoelectronic properties in semiconductors is crucial for the development of advanced technologies, ranging from photodetectors to photovoltaics. In this work, we propose a novel strategy to achieve such…

Amorphous solids manifest puzzling effects of mysterious degrees of freedom that give rise to a heat capacity and phonon scattering in great excess over what would be expected for a solid that has a unique vibrational ground state. Of…

Disordered Systems and Neural Networks · Physics 2018-10-11 Vassiliy Lubchenko

We examine coherent phonons in a strongly driven sample of optimally-doped high temperature superconductor YBa$_2$Cu$_3$O$_{7-\delta}$. We observe a non-linear lattice response of the 4.5\,THz copper-oxygen vibrational mode at high…

Engineering of phonons, i.e., collective lattice vibrations in crystals, is essential for manipulating physical properties of materials such as thermal transport, electron-phonon interaction, confinement of lattice vibration, and optical…

Materials Science · Physics 2022-02-04 Seung Gyo Jeong , Ambrose Seo , Woo Seok Choi

Understanding the microscopic processes affecting the bulk thermal conductivity is crucial to develop more efficient thermoelectric materials. PbTe is currently one of the leading thermoelectric materials, largely thanks to its low thermal…

Materials Science · Physics 2011-06-07 O. Delaire , J. Ma , K. Marty , A. F. May , M. A. McGuire , M. -H. Du , D. J. Singh , A. Podlesnyak , G. Ehlers , M. Lumsden , B. C. Sales

We study the non-equilibrium diffusion dynamics of supersonic lattice solitons in a classical chain of atoms with nearest-neighbor interactions coupled to a heat bath. As a specific example we choose an interaction with cubic anharmonicity.…

Soft Condensed Matter · Physics 2009-11-07 Edward Arevalo , Franz G. Mertens , Yuri Gaididei , A. R. Bishop

In semiconductors almost all heat is conducted by phonons (lattice vibrations), which is limited by their quasi-particle lifetimes. Phonon-phonon interactions represent scattering mechanisms that produce thermal resistance. In…

We investigated the lattice dynamics of the unconventional superconductor LiFeAs using inelastic neutron scattering experiments and density-functional theory (DFT) calculations. By comparing the neutron scattering intensities with…

The breakdown of the quasiparticle approximation (QPA) for phonons in strongly anharmonic materials necessitates advanced first-principles frameworks for accurate lattice dynamics and thermal transport predictions. We develop a…

Materials Science · Physics 2025-12-23 Yi Xia

Anharmonicity and local disorder (polymorphism) are ubiquitous in perovskite physics, inducing various phenomena observed in scattering and spectroscopy experiments. Several of these phenomena still lack interpretation from first-principles…

Materials Science · Physics 2023-08-30 Marios Zacharias , George Volonakis , Feliciano Giustino , Jacky Even

Motivated by the absence of experimental superconductivity in the metallic Pm-3n phase of AlH3 despite the predictions, we reanalyze its vibrational and superconducting properties at pressures above 99 GPa making use of first-principles…

Superconductivity · Physics 2021-05-05 Pugeng Hou , Francesco Belli , Raffaello Bianco , Ion Errea

The effect of inclusion of the planar phonon anisotropy on thermo-electrical behavior of graphene is analyzed. Charge transport is simulated by means of Direct Simulation Monte Carlo technique coupled with numerical solution of the phonon…

Mesoscale and Nanoscale Physics · Physics 2023-05-30 Marco Coco

The anharmonicity resulted from the intrinsic phonon interaction is neglected by quasiharmonic approximation. Although the intensive researches about anharmonicity have been done, up to now the free energy contributed by the anharmonicity…

Statistical Mechanics · Physics 2007-05-23 Zhongqing Wu , Renata M. Wentzcovitch

We present a lattice dynamics study of orthorhombic antimony sulphide (Sb2S3) obtained using density-functional calculations in conjunction with the supercell force-constant method. The effect of Born effective charges is taken into account…

Materials Science · Physics 2016-07-06 Yun Liu , Kun Ting Eddie Chua , Tze Chien Sum , Chee Kwan Gan

A previously proposed variational approach for momentum-conserving systems [J. Liu et.al., Phys. Rev. E 91, 042910 (2015)] is extended to systematically investigate general momentum-nonconserving nonlinear lattices. Two intrinsic identities…

Statistical Mechanics · Physics 2016-09-20 Junjie Liu , Baowen Li , Changqin Wu

We calculate the lattice dielectric function of strongly anharmonic rutile $\mathrm{TiO}_2$ from ab initio anharmonic lattice dynamics methods. Since an accurate calculation of the $\Gamma$ point phonons is essential for determining optical…

Materials Science · Physics 2023-03-24 Tomohito Amano , Tamio Yamazaki , Ryosuke Akashi , Terumasa Tadano , Shinji Tsuneyuki