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Ionic Current Rectification (ICR) can appear in nanopores, causing a diode-like behavior that originates from different efficiency of ion transport through the pore channel with respect to the applied voltage bias polarity. This effect is…

We characterize the role of electrostatic fluctuations on the charge selectivity of cylindrical nanopores confining electrolyte mixtures. To this end, we develop an extended one-loop theory that can account for correlation effects induced…

Soft Condensed Matter · Physics 2014-03-05 Sahin Buyukdagli , T. Ala-Nissila

The polarisation conversion of a linear polarised electromagnetic wave incident onto a two-dimensional (2D) electron system at an angle is theoretically studied. We consider the 2D system located at the interface between two dielectric…

Condensed Matter · Physics 2009-11-07 V. V. Popov , T. V. Teperik

Short nanopores have various applications in biosensing, desalination, and energy conversion. Here, the modulation of charged exterior surfaces on ionic transport is investigated through simulations with sub-200 nm long nanopores under…

Soft Condensed Matter · Physics 2024-02-08 Long Ma , Zhe Liu , Jia Man , Jianyong Li , Zuzanna S. Siwy , Yinghua Qiu

We employ molecular dynamics simulations to investigate ion and water transport driven by an electric field through quasi-two-dimensional nanoslits with a tapered geometry. Despite the absence of surface charge on the channel walls and the…

Soft Condensed Matter · Physics 2025-09-29 Tim Veenstra , Gerardo Campos-Villalobos , Giuliana Giunta , René van Roij , Marjolein Dijkstra

Ion mobility and ionic conductance in nanodevices are known to deviate from bulk behavior, a phenomenon often attributed to surface effects. We demonstrate that dielectric mismatch between the electrolyte and the surface can qualitatively…

Soft Condensed Matter · Physics 2018-09-17 Hanne S. Antila , Erik Luijten

We report on resistive switching of memristive electrochemical metallization devices using 3D kinetic Monte Carlo simulations describing the transport of ions through a solid state electrolyte of an Ag/TiO$_{\text{x}}$/Pt thin layer system.…

Materials Science · Physics 2017-06-06 Sven Dirkmann , Thomas Mussenbrock

Solid-state electrolytes, by enabling lithium metal anodes, may significantly increase the energy density of current lithium-ion batteries. However, similar to their liquid counterparts, these hard and stiff electrolytes can still be…

Chemical Physics · Physics 2024-10-04 Rajeev Gopal , Longan Wu , Youngju Lee , Jinzhao Guo , Peng Bai

Microscopy observations show that suspensions of synthetic and natural nano-layered smectite clay particles submitted to a strong external electric field undergo a fast and extended structuring. This structuring results from the interaction…

Soft Condensed Matter · Physics 2009-11-11 J. O. Fossum , Y. Meheust , K. P. S. Parmar , K. D. Knudsen , K. J. Maloy , D. M. Fonseca

The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many phenomena originated from ion correlation. An important…

Soft Condensed Matter · Physics 2022-09-26 Nikhil R. Agrawal , Rui Wang

Structural and ion-ordering phase transitions limit the viability of sodium-ion intercalation materials in grid scale battery storage by reducing their lifetime. However, the combination of phenomena in nanoparticulate electrodes creates…

A general strategy for the realization of electric and magnetic quasi-trapped modes located at the same spectral position is presented. This strategy's application makes it possible to design metasurfaces allowing switching between the…

Reverse osmosis (RO) is a method to desalinate water with membranes and an applied pressure. Very important in the theory of mass transport in RO is the concentration polarization (CP) layer, which develops on the upstream side of the…

Chemical Physics · Physics 2023-10-03 P. M. Biesheuvel , S. Porada , I. Ryzhkov , M. Elimelech

Ion transport in highly-confined space is important to various applications, such as biosensing and seawater desalination with nanopores. All-atom molecular dynamics simulations are conducted to investigate the transport of Na$^+$ and…

Mesoscale and Nanoscale Physics · Physics 2019-07-30 Zhongwu Li , Yinghua Qiu , Yan Zhang , Min Yue , Yunfei Chen

The effect of spin-disorder scattering on perpendicular transport in a magnetic monolayer is considered within the single-site Coherent Potential Approximation (CPA). The exchange interaction between a conduction electron and localized…

Disordered Systems and Neural Networks · Physics 2009-11-07 Alireza Saffarzadeh

Metal nanoparticles are receiving increased scientific attention owing to their unique physical and chemical properties that make them suitable for a wide range of applications in diverse fields, such as electrochemistry, biochemistry, and…

Chemical Physics · Physics 2020-10-09 Bendix Petersen , Rafael Roa , Joachim Dzubiella , Matej Kanduc

We develop a theory of charge storage in ultra-narrow slit-like pores of nano\-structured electrodes. Our analysis is based on the Blume-Capel model in external field, which we solve analytically on a Bethe lattice. The obtained solutions…

Soft Condensed Matter · Physics 2020-01-08 Maxym Dudka , Svyatoslav Kondrat , Olivier Bénichou , Alexei A. Kornyshev , Gleb Oshanin

Porous electrodes composed of multiphase active materials are widely used in Li-ion batteries, but their dynamics are poorly understood. Two-phase models are largely empirical, and no models exist for three or more phases. Using a modified…

Chemical Physics · Physics 2014-02-07 Todd R. Ferguson , Martin Z. Bazant

Nanoscale polarization switching in ferroelectric materials by Piezoresponse Force Microscopy (PFM) in weak and strong indentation limits is analyzed using exact solutions for electrostatic and coupled electroelastic fields below the tip.…

Materials Science · Physics 2009-11-10 Sergei V. Kalinin , A. Gruverman , J. Shin , A. P. Baddorf , E. Karapetian , M. Kachanov

We suggest a possible realization of a solid-state memory capacitive (memcapacitive) system. Our approach relies on the slow polarization rate of a medium between plates of a regular capacitor. To achieve this goal, we consider a…

Mesoscale and Nanoscale Physics · Physics 2019-05-07 J. Martinez , M. Di Ventra , Yu. V. Pershin