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In the search for new renewable energy to replace fossil fuels, Hydrogen is one of the most promising candidates for clean energy production. But cheap Hydrogen separation and storage is still a big challenge. Photoelectrochemical devices…

Materials Science · Physics 2022-11-10 R. C. Bastidas Briceño , V. I. Fernandez , R. E. Alonso

Hydrogen is one of the most promising candidates for clean energy production. Photoelectrochemical devices look promising for the decomposition of the water molecule into 2H$_2$ + O$_2$. Oxynitrides, like the solid solution…

Materials Science · Physics 2024-10-07 R. C. Bastidas Briceño , V. I. Fernandez , R. E. Alonso

Metal sulfides are emerging as an important class of materials for photocatalytic applications, because of their high photo responsive nature in the wide visible light range. CdS in this class of materials, have a direct band gap of 2.4 eV,…

Materials Science · Physics 2019-12-19 Sulakshana Shenoy , Kartick Tarafder

Perovskite photoelectrodes are being extensively studied in search for photocatalytic materials that can produce hydrogen through water splitting. The solar-to-hydrogen efficiency of these materials is critically dependent on the…

Applied Physics · Physics 2019-06-26 Yihuang Xiong , Ismaila Dabo

Highly-efficient water splitting based on solar energy is one of the most attractive research focuses in the energy field. Searching for more candidate photocatalysts that can work under visible-light irradiation are highly demanded.…

Materials Science · Physics 2024-09-17 Yun-Lai Zhu , Jun-Hui Yuan , Ya-Qian Song , Sheng Wang , Kan-Hao Xue , Ming Xu , Xiao-Min Cheng , Xiang-Shui Miao

Beta-phase gallium oxide ($\beta$-Ga$_2$O$_3$) research has gained accelerated pace due to its superiorly large bandgap and commercial availability of large-diameter native substrates. However, the high acceptor activation energy obstructs…

Polar heterogeneous photocatalysts were shown to lead to enhanced charge-carrier separation that results in superior activity for example for photocatalytic water splitting. Promising photocatalyst materials such as oxynitrides can be…

Materials Science · Physics 2019-02-28 Nathalie Vonrüti , Ulrich Aschauer

Band engineering is employed thoroughly and targets technologically scalable photoanodes for solar water splitting applications. Complex and costly recipes are necessary, often for average performances. Here we report simple photoanode…

Materials Science · Physics 2023-04-18 Stefan Stanescu , Théo Alun , Yannick J. Dappe , Dris Ihiawakrim , Ovidiu Ersen , Dana Stanescu

The improved photocatalytic water splitting using 2D materials has technological importance for economically viable renewable energy. The present study focuses on the effect of uniaxial, biaxial, and vertical strain on the energy gap and…

Materials Science · Physics 2023-01-11 Soumendra Kumar Das , Lokanath Patra , Prasanjit Samal , Pratap K Sahoo

Perovskite SrTiO3 (STO) is an attractive photocatalyst for solar water splitting, but suffers from a limited photoresponse in the ultraviolet spectral range due to its wide band gap. By means of hybrid density functional theory…

Materials Science · Physics 2021-06-16 Y. S. Hou , S. Ardo , R. Q. Wu

The electronic properties of epitaxial heterojunctions consisting of the prototypical perovskite oxide semiconductor,n-SrTiO3 and the high-mobility Group IV semiconductor p-Ge have been investigated. Hard x-ray photoelectron spectroscopy…

The heterostructure consisting of the Mott insulator LaVO$_3$ and the band insulator SrTiO$_3$ is considered a promising candidate for future photovoltaic applications. Not only does the (direct) excitation gap of LaVO$_3$ match well the…

Photocatalytic water splitting represents a very promising but at the same time very challenging contribution to a clean and renewable route to produce hydrogen fuel. Developing efficient and cost-effective photocatalysts for water…

Materials Science · Physics 2023-01-12 Manjari Jain , Deepika Gill , Sanchi Monga , Saswata Bhattacharya

To overcome current serious energy and environmental issues, photocatalytic water splitting holds great promise because it requires only solar energy as an energy input to produce hydrogen. Two-dimensional (2D) semiconductors and…

Materials Science · Physics 2022-10-11 Vei Wang , Gang Tang , Ya-Chao Liu , Yun-Ye Liang , Hiroshi Mizuseki , Yoshiyuki Kawazoe , Wen-Tong Geng

Favourable band alignment and excellent visible light response are vital for photochemical water splitting. In this work, we have theoretically investigated how ferroelectric polarization and its reversibility in direction can be utilized…

Applied Physics · Physics 2020-09-03 Dimuthu Wijethunge , Lei Zhang , Cheng Tang , Aijun Du

The photocatalytic water-splitting process is thermodynamically challenging and requires catalysts with suitable band structures, as well as the presence of supporting cocatalysts. By considering the unique charge carrier mobility in…

Chemical Physics · Physics 2025-10-20 Ho Truong Nam Hai , Makoto Arita , Kaveh Edalati

In this work, using a hybrid density functional theory (DFT) based calculation, we propose a new two-dimensional (2D) B-C-N material, $g-B_{3}C_{2}N_{3}$, with the promising prospect of metal-free photocatalysis. A comprehensive…

Materials Science · Physics 2022-07-14 Sreejani Karmakar , Souren Adhikary , Sudipta Dutta

Photocatalytic water splitting has attracted considerable attention for renewable energy production. Since the first reported photocatalytic water splitting by titanium dioxide, this material remains one of the most promising…

Materials Science · Physics 2026-03-24 Marija Stojkovic , Edward Linscott , Nicola Marzari

Preparation of solid solutions represents an effective means to improve the photocatalytic properties of semiconductor-based materials. Nevertheless, the effects of site-occupancy disorder on the mixing stability and electronic properties…

Materials Science · Physics 2018-12-11 Joel Shenoy , Judy N. Hart , Ricardo Grau-Crespo , Neil L. Allan , Claudio Cazorla

With photoelectrochemical water splitting being one of the most promising approaches for clean energy production and storage, the search for efficient photoelectrode materials is greater than ever. Gallium phosphide (GaP) is a…

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