Related papers: Sulfur Ion Implantations Into Condensed CO2: Impli…
The surfaces of some icy moons, such as Jupiter's moon Europa, are heavily bombarded by energetic particles that can alter the surface materials and affect the composition of its exosphere. Detection of CO2 on Europa's surface indicate that…
The detection of CO2 on the Jovian satellite Europa by Galileo NIMS and recent mapping of the leading side by JWST has revealed that it is most concentrated in geologically young terrains, and its v3 asymmetric stretch appears as a spectral…
H$_2$O$_2$ is part of Europa's water-ice radiolytic cycle and a potential source of oxidants to Europa's subsurface ocean. However, factors controlling the concentration of this critical surface species remain unclear. Though laboratory…
The icy surface of Europa is continuously bombarded by ions and electrons from Jupiter's magnetosphere. The bombardment of the particles dissociates water molecules on the surface of Europa and introduces impurities to the icy surface. Such…
Observations of Europa's leading hemisphere reveal elevated H2O2 in the warmer, low latitude chaos terrains compared to the colder, polar regions. This distribution disagrees with prior laboratory radiolysis studies of pure water ice, which…
The early prediction and subsequent detection of an O$_2$ atmosphere on Europa, coupled with the discovery that Europa has an ocean under its ice mantle, has made this moon a prime astrobiologic target, soon to be visited by the JUICE and…
The surface of Europa could contain the compositional imprint of a underlying interior ocean, but competing hypotheses differ over whether spectral observations from the Galileo spacecraft show the signature of ocean evaporates or simply…
We present the results of experiments probing the retention of CO2 in crystalline water ice, frozen sodium chloride (NaCl) brines, and flash-frozen carbonated water using diffuse reflectance infrared spectroscopy. Characteristic absorptions…
Jupiter's moon Europa has a subsurface ocean, the chemistry of which is largely unknown. Carbon dioxide (CO$_2$) has previously been detected on the surface of Europa, but it was not possible to determine whether it originated from…
CO$_2$ ice has a phase transition at 35 K when its structure changes from amorphous to crystalline. Using Reflection absorption Infrared Spectroscopy (RAIRS), \"Oberg et al. observed that the photodesorption yield of CO$_2$ ice deposited at…
Europa has been modified by a variety of geologic processes, exposing internally-derived materials that are heavily irradiated by charged particles trapped in Jupiter's magnetosphere. Prior spectral analysis of H2O ice on Europa relied on…
We investigate the effects produced mainly by broadband soft X-rays up to 2 keV (plus fast (keV) photoelectrons and low-energy (eV) induced secondary electrons) in the ice mixtures containing H2O:CO2:NH3:SO2 (10:1:1:1) at two different…
Sulfur dioxide (SO2) is a sulfur-containing molecule expected to exist as a solid in the interstellar medium (ISM). In this study, we performed laboratory experiments and computational analyses on the surface reactions of solid SO2 with…
Sulfur is an abundant element in the cosmos and it is thus an important contributor to astrochemistry in the interstellar medium and in the Solar System. Astronomical observations of the gas and of the solid phases in the dense…
In a previous paper (Chassefi\`ere et al., Icarus 223, 878-891, 2013), we have shown that most volcanic sulfur released to early Mars atmosphere could have been trapped in the cryosphere under the form of CO2-SO2 clathrates. Huge amounts of…
We present hemispherically resolved spectra of the surface of Europa from ~3.1--4.13 microns, which we obtained using the near infrared spectrometer NIRSPEC on the Keck II telescope. These include the first high-quality L-band spectra of…
Competing processes shape Europa's surface: geological activity replenishes material through resurfacing, while bombardment by charged particles alters surface chemical composition. Each process leaves distinct spectral signatures. We…
The surfaces of icy moons are primarily composed of water ice that can be mixed with other compounds, such as carbon dioxide. The carbon dioxide (CO$_2)$ stretching fundamental band observed on Europa and Ganymede appears to be a…
Europa's leading hemisphere chaos regions have a spectral feature at 450 nm that has been attributed to absorption by crystal defects in irradiated sodium chloride, known as F-centers. Some discrepancies exist between the laboratory data of…
Hydrogen sulfide (H2S) is thought to be an important sulfur reservoir in interstellar ices. It serves as a key precursor to complex sulfur-bearing organics, and has been proposed to play a significant role in the origin of life. Although…