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Efficient representations of the Hamiltonian such as double factorization drastically reduce circuit depth or number of repetitions in error corrected and noisy intermediate scale quantum (NISQ) algorithms for chemistry. We report a…

We demonstrate a method that merges the quantum filter diagonalization (QFD) approach for hybrid quantum/classical solution of the time-independent electronic Schr\"odinger equation with a low-rank double factorization (DF) approach for the…

Quantum Physics · Physics 2022-03-21 Jeffrey Cohn , Mario Motta , Robert M. Parrish

Quantum phase estimation based on qubitization is the state-of-the-art fault-tolerant quantum algorithm for computing ground-state energies in chemical applications. In this context, the 1-norm of the Hamiltonian plays a fundamental role in…

Variational algorithms are a promising paradigm for utilizing near-term quantum devices for modeling electronic states of molecular systems. However, previous bounds on the measurement time required have suggested that the application of…

We propose a class of randomized quantum Krylov diagonalization (rQKD) algorithms capable of solving the eigenstate estimation problem with modest quantum resource requirements. Compared to previous real-time evolution quantum Krylov…

Quantum Physics · Physics 2023-03-29 Nicholas H. Stair , Cristian L. Cortes , Robert M. Parrish , Jeffrey Cohn , Mario Motta

Quantum computing is a promising technology that harnesses the peculiarities of quantum mechanics to deliver computational speedups for some problems that are intractable to solve on a classical computer. Current generation noisy…

Numerical Analysis · Mathematics 2022-09-16 Daan Camps , Efekan Kökcü , Lindsay Bassman , Wibe A. de Jong , Alexander F. Kemper , Roel Van Beeumen

In fault-tolerant quantum computing, the cost of calculating Hamiltonian eigenvalues using the quantum phase estimation algorithm is proportional to the constant scaling the Hamiltonian matrix block-encoded in a unitary circuit. We present…

Quantum Physics · Physics 2024-12-03 Konrad Deka , Emil Zak

Achieving chemical accuracy for strongly correlated molecules is a defining milestone for first-generation, fault-tolerant quantum computers, yet the factorial growth of three, four, and six-index tensor contractions in coupled-cluster…

Deep neural networks (DNNs) have achieved great success in a wide range of computer vision areas, but the applications to mobile devices is limited due to their high storage and computational cost. Much efforts have been devoted to compress…

Computer Vision and Pattern Recognition · Computer Science 2019-05-14 Yiming Hu , Jianquan Li , Xianlei Long , Shenhua Hu , Jiagang Zhu , Xingang Wang , Qingyi Gu

Clustering on NISQ hardware is constrained by data loading and limited qubits. We present \textbf{qc-kmeans}, a hybrid compressive $k$-means that summarizes a dataset with a constant-size Fourier-feature sketch and selects centroids by…

Quantum Physics · Physics 2025-11-18 Pedro Chumpitaz-Flores , My Duong , Ying Mao , Kaixun Hua

We introduce novel algorithms for the quantum simulation of molecular systems which are asymptotically more efficient than those based on the Trotter-Suzuki decomposition. We present the first application of a recently developed technique…

This study examines several techniques to improve the efficiency of the linearized multireference driven similarity renormalization group truncated to one- and two-body operators [MR-LDSRG(2)]. We propose a sequential MR-LDSRG(2)…

Chemical Physics · Physics 2019-03-29 Tianyuan Zhang , Chenyang Li , Francesco A. Evangelista

Simulating quantum dynamics is expected to be performed more easily on a quantum computer than on a classical computer. However, the currently available quantum devices lack the capability to implement fault-tolerant quantum algorithms for…

Quantum Physics · Physics 2022-02-28 Kian Hwee Lim , Tobias Haug , Leong Chuan Kwek , Kishor Bharti

We present a hardware-efficient optimization scheme for quantum chemistry calculations, utilizing the Sampled Quantum Diagonalization (SQD) method. Our algorithm, optimized SQD (SQDOpt), combines the classical Davidson method technique with…

Quantum Physics · Physics 2025-03-05 Nora Bauer , Kübra Yeter-Aydeniz , George Siopsis

Applications of quantum simulation algorithms to obtain electronic energies of molecules on noisy intermediate-scale quantum (NISQ) devices require careful consideration of resources describing the complex electron correlation effects. In…

Quantum Physics · Physics 2020-04-17 Mekena Metcalf , Nicholas P. Bauman , Karol Kowalski , Wibe A. de Jong

Hamiltonian simulation is a key quantum algorithm for modeling complex systems. To implement a Hamiltonian simulation, it is typically decomposed into a list of Pauli strings, each corresponds to an RZ rotation gate with many Clifford…

Quantum Physics · Physics 2025-10-16 Yingheng Li , Xulong Tang , Paul Hovland , Ji Liu

It is crucial to reduce the resources required to run quantum algorithms and simulate physical systems on quantum computers due to coherence time limitations. With regards to Hamiltonian simulation, a significant effort has focused on…

Quantum Physics · Physics 2022-12-01 Diana B. Chamaki , Stuart Hadfield , Katherine Klymko , Bryan O'Gorman , Norm M. Tubman

Variational quantum algorithms are promising applications of noisy intermediate-scale quantum (NISQ) computers. These algorithms consist of a number of separate prepare-and-measure experiments that estimate terms in a Hamiltonian. The…

Quantum Physics · Physics 2020-06-25 Andrew Zhao , Andrew Tranter , William M. Kirby , Shu Fay Ung , Akimasa Miyake , Peter Love

During the noisy intermediate-scale quantum (NISQ) era, quantum computational approaches refined to overcome the challenge of limited quantum resources are highly valuable. However, the accuracy of the molecular properties predicted by most…

Quantum Physics · Physics 2023-12-20 Shih-Kai Chou , Jyh-Pin Chou , Alice Hu , Yuan-Chung Cheng , Hsi-Sheng Goan

Quantum computing applications in the noisy intermediate-scale quantum (NISQ) era require algorithms that can generate shallower circuits feasible for today's quantum systems. This is particularly challenging for quantum chemistry…

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