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Related papers: Uniaxial negative thermal expansion in a tetragona…

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Thermal expansion is a problem in many technological applications and its control represents a challenge in materials design. In this Letter, after studying the correlation between thermal expansion, cubic-to-rhombohedral transition and…

Materials Science · Physics 2018-09-13 Andrea Sanson

The cubic Prussian Blue (PB) analog, Zn3 [Fe(CN)6]2, has been studied by X-ray powder diffraction and inelastic neutron scattering (INS). X-ray data collected at 300 and 84 K revealed negative thermal expansion (NTE) behaviour for this…

Materials Science · Physics 2011-08-17 S Adak , L L Daemen , H Nakotte

The physical properties of the spinel LiGaCr4S8 have been studied with neutron diffraction, X-ray diffraction, magnetic susceptibility and heat capacity measurements. The neutron diffraction and synchrotron X-ray diffraction data reveal…

Negative thermal expansion (NTE) - the phenomenon where some materials shrink rather than expand when heated - is both intriguing and useful, but remains poorly understood. Current understanding hinges on the role of specific vibrational…

Materials Science · Physics 2020-09-23 Martin T Dove , Juan Du , Zhongsheng Wei , David A Keen , Matthew G Tucker , Anthony E Phillips

Neutron powder diffraction has been used to investigate the structural and magnetic behavior of the isoelectronically doped Fe pnictide material PrFe1-xRuxAsO. Substitution of Ru for Fe suppresses the structural and magnetic phase…

Superconductivity · Physics 2016-11-11 Yuen Yiu , V. Ovidiu Garlea , Michael A. McGuire , Ashfia Huq , David Mandrus , Stephen E. Nagler

We report the superconductivity at enhanced temperature of 5.2 K in the polycrystalline sample of ZrTe3 and Ni intercalated ZrTe3. ZrTe3 is a Charge Density Wave (T = 63K) compound, which is known to superconduct only below 2K in single…

Superconductivity · Physics 2015-06-05 C. S. Yadav , P. L. Paulose

ZnNi(CN)$_4$ is a 3D framework material consisting of two interpenetrating PtS-type networks in which tetrahedral [ZnN$_4$] units are linked by square-planar [NiC$_4$] units. Both the parent compounds, cubic Zn(CN)$_2$ and layered…

We study negative thermal expansion (NTE) in model lattices with multiple atoms per cell and first- and second-nearest neighbor interactions using the (anharmonic) Morse potential. By exploring the phase space of neighbor distances and…

Materials Science · Physics 2016-06-15 Joseph T. Schick , Andrew M. Rappe

Scandium fluoride (ScF3) belongs to a class of negative thermal expansion (NTE) materials. It shows a strong lattice contraction up to about 1000 K switching to expansion at higher temperatures. Here the NTE effect in ScF3 is studied in the…

Materials Science · Physics 2020-02-25 D. Bocharov , M. Krack , Yu. Rafalskij , A. Kuzmin , J. Purans

Materials with negative thermal expansion (NTE), which contract upon heating, are of great interest both technically and fundamentally. Here, we report giant NTE covering room temperature in mechanically milled antiperovksite GaNxMn3…

Materials exhibiting zero thermal expansion (ZTE), namely, volume invariance during temperature change, can resist thermal shock and are highly desired in modern industries as high-precision components. However, pure ZTE materials are rare,…

Materials Science · Physics 2021-09-09 Jun Liu , Bei Ding , Yuan Yao , Xuekui Xi , Zhenxiang Cheng , Jianli Wang , Chin-wei Wang , Guangheng Wu , Wenhong Wang

Negative thermal expansion (NTE) describes the anomalous propensity of materials to shrink when heated. Since its discovery, the NTE effect has been found in a wide variety of materials with an array of magnetic, electronic and structural…

Materials Science · Physics 2018-11-09 Connor A. Occhialini , G. G. Guzmán-Verri , Sahan U. Handunkanda , Jason N. Hancock

We report a significant enhancement of superconducting transition temperature ($\textit{T}_\textrm{c}$) of transition metal dichalcogenide (TMD) superconductor $\textrm{NbTe}_2$ from 0.56 K to 2.8 K. Detailed x-ray structure analysis…

We report the temperature evolution of the Dirac band in semiconducting zirconium pentatelluride (ZrTe$_5$) using magneto-infrared spectroscopy. We find that the band gap is temperature independent at low temperatures and increases with…

The thermal and lattice dynamical properties of seven silicon clathrate framework structures are investigated with ab initio density functional methods (frameworks I, II, IV, V, VII, VIII, and H). The negative thermal expansion (NTE)…

Materials Science · Physics 2014-01-28 Ville J. Härkönen , Antti J. Karttunen

We observe superconductivity below a critical temperature TC = 1.8 K in single-crystal Ir3Te8, which also exhibits normal-state diamagnetism and a linear temperature dependence of electrical resistivity for a wide temperature interval, 20 K…

Zr6CoAl2-type Zr6RuTe2 is found to show bulk superconductivity below the superconducting transition temperature Tc = 1.1 K, according to the electrical resistivity, magnetization, and heat capacity measurements using synthesized…

We report the thermal expansion, critical behavior, magnetocaloric effect (MCE), and magnetoresistance ($MR$) on the polycrystalline Mn$_{1.4}$Fe$_{3.6}$Si$_{3}$ compound around the ferromagnetic transition. A large negative volume thermal…

Strongly Correlated Electrons · Physics 2021-08-11 Vikram Singh , R. Nath

We report the first experimental evidence for the intimate connection between superconductivity and antiferromagnetism in Rb0.8Fe2Se2-xTex single crystal under negative chemical pressure by substituting Se with isovalent Te atoms.…

Superconductivity · Physics 2012-05-25 Dachun Gu , Liling Sun , Qi Wu , Chao Zhang , Jing Guo , Peiwen Gao , Yue Wu , Xiaoli Dong , Xi Dai , Zhongxian Zhao

The anomalous thermal expansion in a layered 3$d$-5$d$ based triple perovskite iridate Ba$_{3}$CoIr$_{2}$O$_{9}$ is investigated using high resolution synchrotron diffraction. Below the magneto-structural transition at 107\,K, the onset of…

Strongly Correlated Electrons · Physics 2021-04-21 Charu Garg , Antonio Cervellino , Sunil Nair