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This study examines a new formulation of non-equilibrium thermodynamics, which gives a conditional derivation of the ``maximum entropy production'' (MEP) principle for flow and/or chemical reaction systems at steady state. The analysis uses…

Populations and Evolution · Quantitative Biology 2009-08-25 Robert K. Niven

Chemical processes in closed systems are poorly controllable since they always relax to equilibrium. Living systems avoid this fate and give rise to a much richer diversity of phenomena by operating under nonequilibrium conditions. Recent…

Chemical Physics · Physics 2019-09-11 Emanuele Penocchio , Riccardo Rao , Massimiliano Esposito

The entropy production rate of nonequilibrium systems is studied via the Fokker-Planck equation. This approach, based on the entropy production rate equation given by Schnakenberg from a master equation, requires information of the…

Statistical Mechanics · Physics 2015-08-10 Haitao Yu , Jiulin Du

In this article a classification of some proposed macroscopic entropy production (MEP) principles is given. With the help of simple electrical network models, at least six interesting and most used principles are distinguished: the least…

Statistical Mechanics · Physics 2007-05-23 Stijn Bruers

For a system described by a multivariate probability density function obeying the fluctuation theorem, the average dissipation is lower-bounded by the degree of asymmetry of the marginal distributions (namely the relative entropy between…

Statistical Mechanics · Physics 2021-08-18 Michele Campisi , Lorenzo Buffoni

In the context of non-equilibrium statistical physics, the entropy production rate is an important concept to describe how far a specific state of a system is from its equilibrium state. In this paper, we establish a central limit theorem…

Probability · Mathematics 2015-09-02 Ran Wang , Lihu Xu

This Letter presents a neural estimator for entropy production, or NEEP, that estimates entropy production (EP) from trajectories of relevant variables without detailed information on the system dynamics. For steady state, we rigorously…

Statistical Mechanics · Physics 2020-10-06 Dong-Kyum Kim , Youngkyoung Bae , Sangyun Lee , Hawoong Jeong

With nontrivial entropy production, first passage process is one of the most common nonequilibrium process in stochastic thermodynamics. Using one dimensional birth and death precess as a model framework, approximated expressions of mean…

Statistical Mechanics · Physics 2021-08-04 Yunxin Zhang

We consider conservative quantum evolutions possibly interrupted by macroscopic measurements. When started in a nonequilibrium state, the resulting path-space measure is not time-reversal invariant and the weight of time-reversal breaking…

Statistical Mechanics · Physics 2007-05-23 I. Callens , W. De Roeck , T. Jacobs , C. Maes , K. Netocny

New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…

Statistical Mechanics · Physics 2021-05-05 Paul M. Riechers , Mile Gu

Living and non-living active matter consumes energy at the microscopic scale to drive emergent, macroscopic behavior including traveling waves and coherent oscillations. Recent work has characterized non-equilibrium systems by their total…

Statistical Mechanics · Physics 2021-01-22 Daniel S. Seara , Benjamin B. Machta , Michael P. Murrell

The dynamics of molecular collisions in a macroscopic body are encoded by the parameter Thermodynamic entropy - a statistical measure of the number of molecular configurations that correspond to a given macrostate. Directionality in the…

Populations and Evolution · Quantitative Biology 2020-05-22 Lloyd Demetrius , Christian Wolf

The entropy production rate associated with broken time-reversal symmetry provides an essential characterization of nanosystems out of equilibrium, from driven colloidal particles to molecular motors. Limited access to the dynamical states…

Statistical Mechanics · Physics 2020-11-25 Gianluca Teza , Attilio L. Stella

We study quantum conditional entropy production, which quantifies the irreversibility of system-environment evolution from the perspective of a third system, called the reference. The reference is initially correlated with the system. We…

Quantum Physics · Physics 2022-08-01 Kun Zhang , Xuanhua Wang , Qian Zeng , Jin Wang

The entropy produced when a quantum system is driven away from equilibrium can be decomposed in two parts, one related with populations and the other with quantum coherences. The latter is usually based on the so-called relative entropy of…

Quantum technology is progressing towards fast quantum control over systems interacting with small environments. Hence such technologies are operating in a regime where the environment remembers the system's past, and the applicability of…

Quantum Physics · Physics 2015-12-04 Sai Vinjanampathy , Kavan Modi

The entropy production rate is a central quantity in non-equilibrium statistical physics, scoring how far a stochastic process is from being time-reversible. In this paper, we compute the entropy production of diffusion processes at…

Statistical Mechanics · Physics 2023-06-19 Lancelot Da Costa , Grigorios A. Pavliotis

A typical strategy of realizing an adiabatic change of a many-particle system is to vary parameters very slowly on a time scale $t_\text{r}$ much larger than intrinsic equilibration time scales. In the ideal case of adiabatic state…

Statistical Mechanics · Physics 2021-03-24 Philipp S. Weiß , Dennis Hardt , Achim Rosch

We establish a fundamental connection between score-based diffusion models and non-equilibrium thermodynamics by deriving performance limits based on entropy rates. Our main theoretical contribution is a lower bound on the negative…

Machine Learning · Computer Science 2025-10-08 Nathan X. Kodama , Michael Hinczewski

Small nonequilibrium systems in contact with a heat bath can be analyzed with the framework of stochastic thermodynamics. In such systems, fluctuations, which are not negligible, follow universal relations such as the fluctuation theorem.…

Statistical Mechanics · Physics 2018-10-29 Andre C Barato , Raphael Chetrite , Alessandra Faggionato , Davide Gabrielli
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