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The equilibrium optical phonons of graphene are well characterized in terms of anharmonicity and electron-phonon interactions, however their non-equilibrium properties in the presence of hot charge carriers are still not fully explored.…

Mesoscale and Nanoscale Physics · Physics 2018-02-15 C. Ferrante , A. Virga , L. Benfatto , M. Martinati , D. De Fazio , U. Sassi , C. Fasolato , A. K. Ott , P. Postorino , D. Yoon , G. Cerullo , F. Mauri , A. C. Ferrari , T. Scopigno

Few-layer graphene possesses low-energy carriers which behave as massive fermions, exhibiting intriguing properties in both transport and light scattering experiments. Lowering the excitation energy of resonance Raman spectroscopy down to…

Radio-frequency compressed ultrafast electron diffraction has been used to probe the coherent and incoherent coupling of impulsive electronic excitation at 1.55 eV (800 nm) to optical and acoustic phonon modes directly from the perspective…

Materials Science · Physics 2015-06-23 Robert P. Chatelain , Vance R. Morrison , Bart L. M. Klarenaar , Bradley J. Siwick

The fine structure of the Dirac energy spectrum in graphene induced by electron-optical phonon coupling is investigated in the portion of the spectrum near the phonon emission threshold. The derived new dispersion equation in the immediate…

Mesoscale and Nanoscale Physics · Physics 2013-07-29 S. M. Badalyan , F. M. Peeters

We modulate the atomic structure of bilayer graphene by driving its lattice at resonance with the in-plane E1u lattice vibration at 6.3um. Using time- and angle-resolved photoemission spectroscopy (tr-ARPES) with extreme ultra-violet (XUV)…

Coherent coupling of Dirac fermion magneto-excitons with an optical phonon is observed in graphite as marked magnetic-field dependent splittings and anti-crossing behavior of the two coupled modes. The sharp magneto-phonon resonance occurs…

Materials Science · Physics 2015-05-19 J. Yan , S. Goler , T. D. Rhone , M. Han , R. He , P. Kim , V. Pellegrini , A. Pinczuk

We present an analysis of deep-UV Raman measurements of graphite, graphene and carbon nanotubes. For excitation energies above the strong optical absorption peak at the $M$ point in the Brillouin zone ($\approx 4.7\,\text{eV}$), we…

Materials Science · Physics 2015-08-03 Christoph Tyborski , Felix Herziger , Roland Gillen , Janina Maultzsch

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

We theoretically investigate the double-resonance Raman spectrum of monolayer graphene down to infrared laser excitation energies. By using first-principles density functional theory calculations, we improve upon previous theoretical…

Mesoscale and Nanoscale Physics · Physics 2025-05-21 Lorenzo Graziotto , Francesco Macheda , Thibault Sohier , Matteo Calandra , Francesco Mauri

We have investigated the effects of ozone treatment on graphene by Raman scattering. Sequential ozone short-exposure cycles resulted in increasing the $p$ doping levels as inferred from the blue shift of the 2$D$ and $G$ peak frequencies,…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 F. Alzina , H. Tao , J. Moser , Y. Garcia , A. Bachtold , C. M. Sotomayor-Torres

We perform Raman scattering experiments on natural graphite in magnetic fields up to 45 T, observing a series of peaks due to interband electronic excitations over a much broader magnetic field range than previously reported. We also…

Mesoscale and Nanoscale Physics · Physics 2012-03-14 Y. Kim , Y. Ma , A. Imambekov , N. G. Kalugin , A. Lombardo , A. C. Ferrari , J. Kono , D. Smirnov

Gate-modulated low-temperature Raman spectra reveal that the electric field effect (EFE), pervasive in contemporary electronics, has marked impacts on long wavelength optical phonons of graphene. The EFE in this two dimensional honeycomb…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Jun Yan , Yuanbo Zhang , Philip Kim , Aron Pinczuk

In this letter, we report that the special coupling between Dirac fermion and lattice vibrations, in other words, electron-phonon coupling (EPC), in silicene layers on Ag(111) surface was probed by an in-situ Raman spectroscopy. We find the…

Materials Science · Physics 2015-05-20 Jincheng Zhuang , Xun Xu , Yi Du , Kehui Wu , Lan Chen , Weichang Hao , Jiaou Wang , Wai Kong Yeoh , Xiaolin Wang , Shi Xue Dou

We show that the electron-phonon coupling in graphene, in contrast with the non-relativistic two-dimensional electron gas, leads to shifts in the phonon frequencies that are non-trivial functions of the electronic density. These shifts can…

Strongly Correlated Electrons · Physics 2013-05-29 A. H. Castro Neto , Francisco Guinea

Magneto Raman scattering study of the E$_{2g}$ optical phonons in multi-layer epitaxial graphene grown on a carbon face of SiC are presented. At 4.2K in magnetic field up to 33 T, we observe a series of well pronounced avoided crossings…

Materials Science · Physics 2015-05-13 C. Faugeras , M. Amado , P. Kossacki , M. Orlita , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

Electron-phonon coupling directly determines the stability of cooperative order in solids, including superconductivity, charge and spin density waves. Therefore, the ability to enhance or reduce electron-phonon coupling by optical driving…

Here we use pristine graphene samples in order to analyze how the Raman peaks intensity, measured at 2.4 eV and 1.96 eV excitation energy, changes with the amount of doping. The use of pristine graphene allows investigating the intensity…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 C. Casiraghi

We report the observation of an intense anomalous peak at 1608 cm$^{-1}$ in the Raman spectrum of graphene associated to the presence of chromium nanoparticles in contact with graphene. Bombardment with an electron beam demonstrates that…

A Raman study of a back gated bilayer graphene sample is presented. The changes in the Fermi level induced by charge transfer splits the Raman G-band, hardening its higher component and softening the lower one. These two components are…

Mesoscale and Nanoscale Physics · Physics 2008-12-16 L. M. Malard , D. C. Elias , E. S. Alves , M. A. Pimenta

We present low-temperature Raman measurements on gate tunable graphene encapsulated in hexagonal boron nitride, which allows to study in detail the Raman G and 2D mode frequencies and line widths as function of the charge carrier density.…

Mesoscale and Nanoscale Physics · Physics 2023-02-15 Jens Sonntag , Kenji Watanabe , Takashi Taniguchi , Bernd Beschoten , Christoph Stampfer
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