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Atomic layers of black phosphorus (P) isolated from its layered bulk make a new two-dimensional (2D) semiconducting crystal with sizable direct bandgap, high carrier mobility, and promises for 2D electronics and optoelectronics. However,…

Mesoscale and Nanoscale Physics · Physics 2023-05-03 Zenghui Wang , Arnob Islam , Rui Yang , Xu-Qian Zheng , Philip X. -L. Feng

Two-dimensional (2D) materials, such as graphene and transition metal dichalcogenides have attracted great attention because of the rich physics and potential applications in next-generation nano-sized electronic devices. Recently,…

Materials Science · Physics 2015-05-25 Xiaolong Chen , Yingying Wu , Zefei Wu , Shuigang Xu , Lin Wang , Yu Han , Weiguang Ye , Tianyi Han , Yuheng He , Yuan Cai , Ning Wang

High-performance infrared photodetection underpins various applications spanning surveillance, environmental monitoring, optical communications and biomedical imaging. However, conventional bulk detectors remain limited by poor spectral…

Solution dispersions of two-dimensional (2D) black phosphorus (BP), often referred to as phosphorene, are achieved by solvent exfoliation. These pristine, electronic-grade BP dispersions are produced with anhydrous, organic solvents in a…

Black phosphorus (BP) has recently emerged as an alternative 2D semiconductor owing to its fascinating electronic properties such as tunable bandgap and high charge carrier mobility. The structural investigation of few-layer BP, such as…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 Yangjin Lee , Jun-Yeong Yoon , Declan Scullion , Jeongsu Jang , Elton J G Santos , Hu Young Jeong , Kwanpyo Kim

The effect of quantum confinement in the optical absorption spectra of atomically thin {\alpha}-In2Se3 crystals is studied, observing a huge thickness-dependent shift in the optical band gap of exfoliated {\alpha}-In2Se3 flakes. The band…

Mesoscale and Nanoscale Physics · Physics 2016-10-19 Jorge Quereda , Robert Biele , Gabino Rubio-Bollinger , Nicolás Agraït , Roberto D'Agosta , Andres Castellanos-Gomez

We investigate unusual surface plasmons polariton (SPP) propagation and light-matter interactions in ultrathin black phosphorus (BP) films, a 2D material that exhibits exotic electrical and physical properties due to its extremely…

Mesoscale and Nanoscale Physics · Physics 2016-10-12 D. Correas-Serrano , J. S. Gomez-Diaz , A. Alvarez Melcon , Andrea Alù

Through infrared spectroscopy, we systematically study the pressure effect on electronic structures of few-layer black phosphorus (BP) with layer number ranging from 2 to 13. We reveal that the pressure-induced shift of optical transitions…

Tuning band gaps in two-dimensional (2D) materials is of great interest in the fundamental and practical aspects of contemporary material sciences. Recently, black phosphorus (BP) consisting of stacked layers of phosphorene was…

Materials Science · Physics 2017-09-13 Sun-Woo Kim , Hyun Jung , Hyun-Jung Kim , Jin-Ho Choi , Su-Huai Wei , Jun-Hyung Cho

We provide a tight-binding model parametrization for black phosphorus (BP) with an arbitrary number of layers. The model is derived from partially self-consistent $GW_0$ approach, where the screened Coulomb interaction $W_0$ is calculated…

Materials Science · Physics 2015-08-19 A. N. Rudenko , Shengjun Yuan , M. I. Katsnelson

Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here we…

We have characterized the growth of ZnO using sequential infiltration synthesis (SiS) on PS-b-PMMA block copolymers (BCP) of spherical and cylindrical sub-20nm morphologies and studied how the photoluminescence of these nanostructures…

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new twodimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure…

We have calculated numerically electron exchange, correlation energies and dynamical polarization function for newly discovered silicene, germanene and black phosphorus (BP), consisting of puckered layers of elemental phosphorus atoms,…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Andrii Iurov , Godfrey Gumbs , Danhong Huang

We study the environmental instability of mechanically exfoliated few-layer black phosphorus (BP). From continuous measurements of flake topography over several days, we observe an increase of over 200% in volume due to the condensation of…

Stacking two-dimensional (2D) materials into multi-layers or heterostructures, known as van der Waals (vdW) epitaxy, is an essential degree of freedom for tuning their properties on demand. Few-layer black phosphorus (FLBP), a material with…

Materials Science · Physics 2016-02-17 Zhi-Xin Hu , Xianghua Kong , Jingsi Qiao , Bruce Normand , Wei Ji

Controlling the bandgap through local-strain engineering is an exciting avenue for tailoring optoelectronic materials. Two-dimensional crystals are particularly suited for this purpose because they can withstand unprecedented…

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

Mesoscale and Nanoscale Physics · Physics 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

Optical devices capable of suppressing diffraction nature of light are of great technological importance to many nanophotonic applications. One important technique to achieve diffractionless optics is to exploit field canalization effect.…

Optics · Physics 2021-12-16 Po-Han Chang , Charles Lin , Amr S. Helmy

The possibility of hybridizing collective electronic motion with mid-infrared (mid-IR) light to form surface polaritons has made van der Waals layered materials a versatile platform for extreme light confinement and tailored nanophotonics.…