English
Related papers

Related papers: Inverse molecular design and parameter optimizatio…

200 papers

In this paper, we propose a novel recovery based finite element method for the Cahn-Hilliard equation. One distinguishing feature of the method is that we discretize the fourth-order differential operator in a standard $C^0$ linear finite…

Numerical Analysis · Mathematics 2019-12-30 Minqiang Xu , Hailong Guo , Qingsong Zou

Computing many eigenpairs of the Schr{\"o}dinger operator presents a computational bottleneck in large-scale quantum simulations due to the global communication overhead of explicit orthogonalization. To address this issue, we propose a…

Numerical Analysis · Mathematics 2026-05-26 Shengyue Wang , Aihui Zhou

Offline model-based optimization aims to maximize a black-box objective function with a static dataset of designs and their scores. In this paper, we focus on biological sequence design to maximize some sequence score. A recent approach…

Computational Engineering, Finance, and Science · Computer Science 2023-04-26 Can Chen , Yingxue Zhang , Xue Liu , Mark Coates

We derive several numerical methods for designing optimized first-order algorithms in unconstrained convex optimization settings. Our methods are based on the Performance Estimation Problem (PEP) framework, which casts the worst-case…

Optimization and Control · Mathematics 2025-07-29 Yassine Kamri , Julien M. Hendrickx , François Glineur

We construct an abstract pseudodifferential calculus with operator-valued symbol, adapted to the treatment of Coulomb-type interactions, and we apply it to study the quantum evolution of molecules in the Born-Oppenheimer approximation, in…

Analysis of PDEs · Mathematics 2008-09-23 Andre' Martinez , Vania Sordoni

We study a class of algorithms for solving bilevel optimization problems in both stochastic and deterministic settings when the inner-level objective is strongly convex. Specifically, we consider algorithms based on inexact implicit…

Optimization and Control · Mathematics 2022-07-12 Michael Arbel , Julien Mairal

The gradient descent method aims at finding local minima of a given multivariate function by moving along the direction of its gradient, and hence, the algorithm typically involves computing all partial derivatives of a given function,…

Quantum Physics · Physics 2025-02-25 Nhat A. Nghiem

The discovery of molecules with tailored optoelectronic properties such as specific frequency and intensity of absorption or emission is a major challenge in creating next-generation organic light-emitting diodes (OLEDs) and photovoltaics.…

Chemical Physics · Physics 2022-04-27 James David Green , Eric Gabriel Fuemmeler , Timothy J. H. Hele

In this paper, a class of high order numerical schemes is proposed for solving Hamilton-Jacobi (H-J) equations. This work is regarded as an extension of our previous work for nonlinear degenerate parabolic equations, see Christlieb et al.…

Numerical Analysis · Mathematics 2019-01-30 Andrew Christlieb , Wei Guo , Yan Jiang

We show that sampling or interpolation formulas in reproducing kernel Hilbert spaces can be obtained by reproducing kernels whose dual systems form molecules, ensuring that the size profile of a function is fully reflected by the size…

Functional Analysis · Mathematics 2022-05-04 José Luis Romero , Jordy Timo van Velthoven , Felix Voigtlaender

A numerical scheme is presented for approximating fractional order Poisson problems in two and three dimensions. The scheme is based on reformulating the original problem posed over $\Omega$ on the extruded domain…

Numerical Analysis · Mathematics 2019-05-27 Mark Ainsworth , Christian Glusa

Many areas of science and engineering encounter data defined on spherical manifolds. Modelling and analysis of spherical data often necessitates spherical harmonic transforms, at high degrees, and increasingly requires efficient computation…

Computational Physics · Physics 2025-06-19 Matthew A. Price , Jason D. McEwen

A semidefinite program (SDP) is a particular kind of convex optimization problem with applications in operations research, combinatorial optimization, quantum information science, and beyond. In this work, we propose variational quantum…

Quantum Physics · Physics 2024-06-19 Dhrumil Patel , Patrick J. Coles , Mark M. Wilde

Over the last decade, it has been demonstrated that many systems in science and engineering can be modeled more accurately by fractional-order than integer-order derivatives, and many methods are developed to solve the problem of fractional…

Computer Vision and Pattern Recognition · Computer Science 2016-08-11 Qi Yang , Dali Chen , Tiebiao Zhao , YangQuan Chen

We present high-precision quantum computing simulations of three-body atoms (He, H$^-$) and molecules (H$_2^+$, HD$^+$), the latter being studied beyond the Born-Oppenheimer approximation. The Non-Iterative Disentangled Unitary Coupled…

Quantum Physics · Physics 2025-10-22 Mohammad Haidar , Hugo D. Nogueira , J. -Ph. Karr

We outline refined versions of two major quantum algorithms for performing principal component analysis and solving linear equations. Our methods are exponentially faster than their classical counterparts and even previous quantum…

Quantum Physics · Physics 2025-04-02 Nhat A. Nghiem

We derive a stochastic gradient algorithm for semidefinite optimization using randomization techniques. The algorithm uses subsampling to reduce the computational cost of each iteration and the subsampling ratio explicitly controls…

Optimization and Control · Mathematics 2011-08-30 Alexandre d'Aspremont

We consider optimal design of infinite-dimensional Bayesian linear inverse problems governed by partial differential equations that contain secondary reducible model uncertainties, in addition to the uncertainty in the inversion parameters.…

Optimization and Control · Mathematics 2020-06-23 Alen Alexanderian , Noemi Petra , Georg Stadler , Isaac Sunseri

Since the first observations of interstellar molecules, astrochemical simulations have been employed to model and understand its formation and destruction path- ways. With the advent of high-resolution telescopes such as JWST and ALMA, the…

The differentiable programming paradigm is a cornerstone of modern scientific computing. It refers to numerical methods for computing the gradient of a numerical model's output. Many scientific models are based on differential equations,…