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Incorporating conservation laws explicitly into matrix product states (MPS) has proven to make numerical simulations of quantum many-body systems much less resources consuming. We will discuss here, to what extent this concept can be used…

Quantum Physics · Physics 2011-12-16 Dominik Muth

We present a number conserving particle-hole RPA theory for collective excitations in the transition from normal to superfluid nuclei. The method derives from an RPA theory developed long ago in quantum chemistry using antisymmetric geminal…

Nuclear Theory · Physics 2019-09-04 J. Dukelsky , J. E. García-Ramos , J. M. Arias , P. Pérez-Fernández , P. Schuck

The random phase approximation (RPA) for the correlation energy functional of density functional theory has recently attracted renewed interest. Formulated in terms of the Kohn-Sham (KS) orbitals and eigenvalues, it promises to resolve some…

Other Condensed Matter · Physics 2009-11-13 Hong Jiang , Eberhard Engel

The optimized effective potential (OEP) method presents an unambiguous way to construct the Kohn-Sham potential corresponding to a given diagrammatic approximation for the exchange-correlation functional. The OEP from the random-phase…

Materials Science · Physics 2023-07-18 Stefan Riemelmoser , Merzuk Kaltak , Georg Kresse

The random phase approximation (RPA) has received a considerable interest in the field of modeling systems where noncovalent interactions are important. Its advantages over widely used density functional theory (DFT) approximations are the…

Chemical Physics · Physics 2019-12-04 Marcin Modrzejewski , Sirous Yourdkhani , Jiri Klimes

We explore several random phase approximation (RPA) correlation energy variants within the adiabatic-connection fluctuation-dissipation theorem approach. These variants differ in the way the exchange interactions are treated. One of these…

Chemical Physics · Physics 2014-04-08 János G. Angyán , Ru-Fen Liu , Julien Toulouse , Georg Jansen

The random phase approximation (RPA) builds in correlations left out by mean-field theory. In full 0-hbar-omega shell-model spaces we calculate the Hartree-Fock + RPA binding energy, and compare it to exact diagonalization. We find that in…

Nuclear Theory · Physics 2009-11-07 Ionel Stetcu , Calvin W. Johnson

We explore different variants of the random phase approximation (RPA) to the correlation energy derived from closed-shell ring-diagram approximations to coupled cluster doubles theory. We implement these variants in range-separated…

Chemical Physics · Physics 2011-09-01 Julien Toulouse , Wuming Zhu , Andreas Savin , Georg Jansen , János G. Angyán

Conservation laws are one of the most generic and useful concepts in physics. In nonlinear optical parametric processes, conservation of photonic energy, momenta and parity often lead to selection rules, restricting the allowed polarization…

The ground-state correlation energy calculated in the random-phase approximation (RPA) is known to be identical to that calculated using a subset of terms appearing in coupled-cluster theory with double excitations. In particular, this…

Chemical Physics · Physics 2019-04-16 Timothy C. Berkelbach

We address the study of a class of 1D nonlocal conservation laws from a numerical point of view. First, we present an algorithm to numerically integrate them and prove its convergence. Then, we use this algorithm to investigate various…

Numerical Analysis · Mathematics 2013-03-26 Paulo Amorim , Rinaldo M. Colombo , Andreia Teixeira

We present an analytic proof demonstrating the equivalence between the Random Phase Approximation (RPA) to the ground state correlation energy and a ring-diagram simplification of the Coupled Cluster Doubles (CCD) equations. In the CCD…

Other Condensed Matter · Physics 2009-11-13 Gustavo E. Scuseria , Thomas M. Henderson , Danny C. Sorensen

We revisit the connection between equation-of-motion coupled cluster (EOM-CC) and random phase approximation (RPA) explored recently by Berkelbach [J. Chem. Phys. 149, 041103 (2018)] and unify various methodological aspects of these diverse…

Chemical Physics · Physics 2020-12-17 Varun Rishi , Ajith Perera , Rodney J. Bartlett

Conservation laws of the nonlinear Schr\"{o}dinger equation are studied in the presence of higher-order nonlinear optical effects including the third-order dispersion and the self-steepening. In a context of group theory, we derive a…

solv-int · Physics 2009-10-31 Jongbae Kim , Q-Han Park , H. J. Shin

The numerical integration of phase-field equations is a delicate task which needs to recover at the discrete level intrinsic properties of the solution such as energy dissipation and maximum principle. Although the theory of energy…

Numerical Analysis · Mathematics 2021-03-16 Chaoyu Quan , Tao Tang , Jiang Yang

Relativistic Continuum Random Phase Approximation (CRPA) is used to investigate collective excitation phenomena in several spherical nuclei along the periodic table. We start from relativistic mean field calculations based on a covariant…

Nuclear Theory · Physics 2011-03-21 J. Daoutidis , P. Ring

Random phase approximation ground state contains electronic configurations where two (and more) identical electrons can occupy the same molecular spin-orbital violating the Pauli exclusion principle. This overcounting of electronic…

Chemical Physics · Physics 2017-10-25 Daniel S. Kosov

Finite volume methods are proposed for computing approximate pathwise entropy/kinetic solutions to conservation laws with a rough path dependent flux function. For a convex flux, it is demonstrated that rough path oscillations may lead to…

Numerical Analysis · Mathematics 2018-02-05 Håkon Hoel , Kenneth Hvistendahl Karlsen , Nils Henrik Risebro , Erlend Briseid Storrøsten

We derive a fundamental conservation law of operator current for master equations describing reduced quantum systems. If this law is broken, the temporal integral of the current operator of an arbitrary system observable does not yield in…

Quantum Physics · Physics 2012-03-09 J. Salmilehto , P. Solinas , M. Möttönen

We introduce a new string matching problem called order-preserving matching on numeric strings where a pattern matches a text if the text contains a substring whose relative orders coincide with those of the pattern. Order-preserving…

Data Structures and Algorithms · Computer Science 2013-02-19 Jinil Kim , Peter Eades , Rudolf Fleischer , Seok-Hee Hong , Costas S. Iliopoulos , Kunsoo Park , Simon J. Puglisi , Takeshi Tokuyama