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Few-body systems with large scattering length a have universal properties that do not depend on the details of their interactions at short distances. The rate constant for three-body recombination of bosonic atoms of mass m into a shallow…

Other Condensed Matter · Physics 2008-11-26 H. -W. Hammer , Timo A. Lahde , L. Platter

The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation the potential energy between an excited atom (without fine structure) and a ground state diatomic molecule at large separations.…

Quantum Physics · Physics 2017-04-11 M. Lepers , O. Dulieu , V. Kokoouline

Genuine multipartite entanglement is crucial for quantum information and related technologies but quantifying it has been a long-standing challenge. Most proposed measures do not meet the ``genuine'' requirement, making them unsuitable for…

Quantum Physics · Physics 2024-06-25 Songbo Xie , Daniel Younis , Yuhan Mei , Joseph H. Eberly

The vast majority of mesons can be understood as quark-antiquark states. Yet, various other possibilities exists: glueballs (bound-state of gluons), hybrids (quark-antiquark plus gluon), and four-quark states (either as diquark-antidiquark…

High Energy Physics - Phenomenology · Physics 2016-04-20 Francesco Giacosa

The finite-basis, pair formulation of the Spectral Theory of chemical bonding is briefly surveyed. Solutions of the Born-Oppenheimer polyatomic Hamiltonian totally antisymmetric in electron exchange are obtained from diagonalization of an…

Chemical Physics · Physics 2023-02-07 Jeffrey D. Mills

The way atoms attach to each other defines the function(s), e.g., mechanical, optical, electronic, of a given material. The nature of the chemical bond is, therefore, one of the most fundamental issues in materials. Both ionic interactions,…

Materials Science · Physics 2019-07-10 Yevgeny Rakita , Thomas Kirchartz , Gary Hodes , David Cahen

The ground and first excited states of the decuplet baryons are studied using the two-point QCD sum rule approach. The mass and residue of these states are computed and compared with the existing experimental data and other theoretical…

High Energy Physics - Phenomenology · Physics 2017-04-26 T. M. Aliev , K. Azizi , H. Sundu

We report a systematic study of the weak chemical bond between two benzene molecules. We first show that it is possible to obtain a very good description of the C_2 dimer and the benzene molecule, by using pseudopotentials for the…

Other Condensed Matter · Physics 2009-11-13 Sandro Sorella , Michele Casula , Dario Rocca

Recently, the correlation theory of the chemical bond was developed, which applies concepts of quantum information theory for the characterization of chemical bonds, based on the multiorbital correlations within the molecule. Here for the…

Chemical Physics · Physics 2020-05-08 Jan Brandejs , Libor Veis , Szilárd Szalay , Gergely Barcza , Jiří Pittner , Örs Legeza

In this work, we use the Born-Oppenheimer approximation where the potential between atoms can be approximated as a function of distance between the two nuclei to study the four-quark bound states. By the approximation, Heitler and London…

High Energy Physics - Phenomenology · Physics 2015-09-02 Xue-Wen Liu , Hong-Wei Ke , Yi-Bing Ding , Xue-Qian Li

Weakly bound molecules have physical properties without atomic analogues, even as the bond length approaches dissociation. In particular, the internal symmetries of homonuclear diatomic molecules result in formation of two-body superradiant…

In the rapidly emerging field of nanotechnology, as well as in biology where chemical reaction phenomena take place in systems with characteristic length scales ranging from micrometer to the nanometer range, understanding of chemical…

Statistical Mechanics · Physics 2007-05-23 Z. Konkoli , A. Karlsson , O. Orwar

Recent rsearches have shown that the lengths of the chemical bonds, whether completely or partially covalent or ionic, are sums of the radii of the adjacent atoms and/or ions. On investigating the bond length data for the molecular…

Chemical Physics · Physics 2008-01-29 Raji Heyrovska , Saraswathi Narayan

According to the correspondence principle, classical mechanics and quantum mechanics agree in the semiclassical limit, although presently it has become more and more clear how intriguing would be to try to fix a boundary between them. Here…

Chemical Physics · Physics 2019-12-18 Andrea Carati , Luigi Galgani , Fabrizio Gangemi , Roberto Gangemi

A parameterization strategy for molecular models on the basis of force fields is proposed, which allows a rapid development of models for small molecules by using results from quantum mechanical (QM) ab initio calculations and thermodynamic…

Chemical Physics · Physics 2009-04-22 Bernhard Eckl , Jadran Vrabec , Hans Hasse

Raman scattering measurements are performed on benzene and a number of $p$-oligophenyls including biphenyl, $p$-terphenyl, $p$-quaterphenyl, $p$-quinquephenyl, and $p$-sexiphenyl at ambient conditions. The vibrational modes of the intra-…

Materials Science · Physics 2018-02-01 Kai Zhang , Xiao-Jia Chen

The formation of multipartite quantum entanglement by repeated operation of one and two qubit gates is examined. The resulting entanglement is evaluated using two measures: the average bipartite entanglement and the Groverian measure. A…

Quantum Physics · Physics 2009-11-13 Yonatan Most , Yishai Shimoni , Ofer Biham

We consider the nonrelativistic four-boson system in two dimensions interacting via a short-range attractive potential. For a weakly attractive potential with one shallow two-body bound state with binding energy B_2, the binding energies…

Other Condensed Matter · Physics 2015-06-24 L. Platter , H. -W. Hammer , U. -G. Meißner

We introduce a vector-based interpretation of the chemical bond within the quantum theory of atoms in molecules (QTAIM), the bond-path framework set $\mathbb{B} = \{p, q, r\}$, to follow variations in the 3-D morphology of all bonds for the…

Chemical Physics · Physics 2018-05-08 Wei Jie Huang , Alireza Azizi , Tianlv Xu , Steven R. Kirk , Samantha Jenkins

We develop a correlated-electron minimal model for the normal state of charged phenanthrene ions in the solid state, within the reduced space of the two lowest antibonding molecular orbitals of phenanthrene. Our model is general and can be…

Strongly Correlated Electrons · Physics 2014-06-25 Tirthankar Dutta , Sumit Mazumdar