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Organic-inorganic halide perovskites (OIHPs) are promising optoelectronic materials, but their instability under radiation environments restricts their durability and practical applications. Here we employ electron and synchrotron X-ray…

Ultrafast vibrational dynamics of inorganic-organic hybrid lead halide perovskite CH3NH3PbI$ in the room-temperature tetragonal phase is investigated under moderate photoexcitation slightly below the band gap. Time-resolved optical Kerr…

Materials Science · Physics 2021-11-02 Kunie Ishioka , Terumasa Tadano , Masatoshi Yanagida , Yasuhiro Shirai , Kenjiro Miyano

The MAPbI$_3$ halide perovskite single crystals are studied at 5 K temperature using the photoluminescence excitation spectroscopy. Two non-interacting types of states are determined: bound excitons and defect-related states. Excitation of…

Mesoscale and Nanoscale Physics · Physics 2020-05-07 A. O. Murzin , N. I. Selivanov , V. O. Kozlov , I. I. Ryzhov , A. V. Emeline , Yu. V. Kapitonov

Metal halide perovskites have shown great performance as solar energy materials, but their outstanding optoelectronic properties are paired with unusually strong anharmonic effects. It has been proposed that this intriguing combination of…

We report the discovery of phenomena consistent with bad-metal relaxation dynamics in the metallic regime of an optical-lattice Hubbard model. The transport lifetime induced by inter-particle scattering for a mass current of atoms excited…

Quantum Gases · Physics 2018-08-29 Wenchao Xu , William McGehee , William Morong , Brian DeMarco

We report a dynamic light scattering study of the fluctuation modes in a thermotropic liquid crystalline mixture of monomer and dimer compounds that exhibits the twist-bend nematic ($\mathrm{N_{TB}}$) phase. The results reveal a spectrum of…

The evolution of the bismuth crystal structure upon excitation of its A$_{1g}$ phonon has been intensely studied with short pulse optical lasers. Here we present the first-time observation of a hard x-ray induced ultrafast phase transition…

We present thermodynamic, structural and transport measurements on Ba(Fe0.973Cr0.027)2As2 single crystals. All measurements reveal sharp anomalies at ~ 112 K. Single crystal x-ray diffraction identifies the structural transition as a first…

Materials Science · Physics 2009-07-28 S. L. Bud'ko , S. Nandi , N. Ni , A. Thaler , A. Kreyssig , A. Kracher , J. -Q. Yan , A. I. Goldman , P. C. Canfield

We report investigations of the structural, magnetic, electrical transport and thermal properties of five compositions of the metallic perovskite GdRh$_3$C$_{1-x}$B$_x$ ($0.00 \le x \le 1.00$). Our results show that all the five…

Strongly Correlated Electrons · Physics 2020-09-09 Abhishek Pandey , A. K. Singh , Shovan Dan , K. Ghosh , I. Das , S. Tripathi , U. Kumar , R. Ranganathan , D. C. Johnston , Chandan Mazumdar

We investigated temperature dependent optical conductivity spectra of Nd0.7Sr0.3MnO3 single crystal. We found that polishing and surface scattering effects on the Nd0.7Sr0.3MnO3 crystal surfaces could significantly distort the optical…

Strongly Correlated Electrons · Physics 2007-05-23 H. J. Lee , J. H. Jung , Y. S. Lee , J. S. Ahn , T. W. Noh , K. H. Kim , S-W. Cheong

Fundamentally understanding the lattice dynamics and microscopic mechanisms of thermal transport in cubic hybrid organic-inorganic perovskites remains elusive, primarily due to their strong anharmonicity and frequent phase transitions. In…

Despite the tremendous interest in halide perovskites in solar cells, the reason that the all-inorganic perovskite CsPbI$_3$ is unstable at room temperature remains mysterious. Here single-crystal X-ray diffraction and powder pair…

Materials Science · Physics 2020-07-08 Daniel B. Straus , Shu Guo , Milinda Abeykoon , Robert J. Cava

In complex electronic materials, coupling between electrons and the atomic lattice gives rise to remarkable phenomena, including colossal magnetoresistance and metal-insulator transitions. Charge-ordered phases are a prototypical…

One dimensional lepidocrocite titanium dioxide filaments are investigated with respect to their thermal and aqueous stability. Structural and phase evolution are examined using in situ heating in vacuum within transmission electron…

Using finite-temperature phonon calculations and the Lyddane-Sachs-Teller relations, we calculate ab initio the static dielectric constants of 78 semiconducting oxides and fluorides with cubic perovskite structures at 1000 K. We first…

Materials Science · Physics 2020-11-26 Ambroise van Roekeghem , Jesús Carrete , Stefano Curtarolo , Natalio Mingo

Solar cells based on hybrid perovskites have shown high efficiency while possessing simple processing methods. To gain a fundamental understanding of their properties on an atomic level, we investigate single crystals of CH3NH3PbI3 with a…

Materials Science · Physics 2017-07-14 T. A. Tyson , W. Gao , Y. -S. Chen , S. Ghose , Y. Yan

We report a detailed magnetic, dielectric and Raman studies on partially disordered and biphasic double perovskite La2NiMnO6. DC and AC magnetic susceptibility measurements show two magnetic anomalies at TC1 ~ 270 K and TC2 ~ 240 K, which…

Materials Science · Physics 2015-06-18 Pradeep Kumar , S. Ghara , B. Rajeswaran , D. V. S. Muthu , A. Sundaresan , A. K. Sood

The low ionization energy of an $A$ site molecule is a very important factor, which determines the thermodynamical stability of $A$PbI$_3$ hybrid halide perovskites, while the size of the molecule governs the stable phase at room…

Materials Science · Physics 2018-02-13 Chao Zheng , Oleg Rubel

The tri-layered perovskite Sr4Rh3O10 is reported for the first time. High-pressure and high-temperature heating (6 GPa and 1500 C) brought about successful preparation of a polycrystalline sample of the expected member at n=3 of…

Strongly Correlated Electrons · Physics 2007-05-23 K. Yamaura , Q. Huang , D. P. Young , E. Takayama-Muromachi

We study the single crystal growth and the electronic properties of TbIrIn5. The single crystals of TbIrIn5 were grown using the flux method. The analysis of the x-ray diffraction pattern shows high-quality single crystals formed in a…

Strongly Correlated Electrons · Physics 2024-01-31 Ayusa Aparupa Biswal , Kartik K. Iyer , Kalobaran Maiti