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We study the role of strong electron confinement in surface-enhanced Raman scattering from molecules adsorbed on small noble-metal particles. We describe a new source of Raman signal enhancement which originates from different behavior of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Vitaliy N. Pustovit , Tigran V. Shahbazyan

We present a theoretical study of the dispersion relation of surface plasmon resonances of mesoscopic metal-dielectric-metal microspheres. By analyzing the solutions to Maxwell's equations, we obtain a simple geometric condition for which…

Optics · Physics 2009-11-11 Keisuke Hasegawa , Charles A. Rohde , Miriam Deutsch

We simulate the localized surface plasmon resonances of an Au nanoparticle within tunneling proximity of a Au substrate and demonstrate that the modes may be identified with those responsible for light emission from a scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2012-07-18 J. Mitra , Lei Feng , Michael G. Boyle , P. Dawson

We study an optical response of a system of two parallel close metallic cylinders having nanoscale dimensions. Surface plasmon excitation in the gap between the cylinders are specifically analyzed. In particular, resonance frequencies and…

In the present article the SPP propagation in an attenuating medium is investigated. The analytical calculations of the total electric-field Green's tensor of a metal-dielectric interface structure are provided and novel explicit…

Quantum Physics · Physics 2017-04-05 Zahra Mohammadi , Fardin Kheirandish

We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

This study presents a self-consistent, quantum-informed model for the decay dynamics of localized surface plasmons (LSPs) in spherical metal nanoparticles (NPs), described as plasmonic quasi-particles (PQPs). By bridging classical…

Optics · Physics 2026-05-15 Krystyna Kolwas

Surface waves on a metal nanosphere are described in terms of quantum electrodynamics. The interaction of surface waves with a quantum oscillator is discussed in the dipole approximation. The increase in the spontaneous emission rate of the…

Optics · Physics 2013-01-23 A. M. Leontovich , V. V. Lidsky

Single gold nanoparticles can act as nanoantennas for enhancing the fluorescence of emitters in their near-fields. Here we present experimental and theoretical studies of scanning antenna-based fluorescence microscopy as a function of the…

We investigate plasmon resonances in gold nanoparticles to enhance the quantum yield of upconverting materials. For this purpose, we use a rate equation model that describes the upconversion of trivalent erbium based upconverters. Changes…

In this work we study the strong confinement effects on the electromagnetic response of metallic nanoparticles. We calculate the field enhancement factor for nanospheres of various radii by using optical constants obtained from both…

Mesoscale and Nanoscale Physics · Physics 2018-02-20 Mario Zapata-Herrera , Jefferson Flórez , Angela Camacho , Hanz Y. Ramirez

Surface-enhanced Raman spectroscopy (SERS) allows single-molecule detection due to the strong field localization occurring at sharp bends or kinks of the metal-vacuum interface. An important question concerns the limits of the signal…

Optics · Physics 2008-06-19 Sanshui Xiao , Niels Asger Mortensen , Antti-Pekka Jauho

Strong near-field enhancements (NFEs) of nanophotonic structures are believed to be closely related to high Purcell factors (FP). Here, we theoretically show that the correlation is partially correct; the extinction cross section ({\sigma})…

Optics · Physics 2024-01-17 Xu-Tao Tang , Lin Ma , Yue You , Xiao-Jing Du , Hua Qiu , Xi-Hua Guan , Jun He , Zhong-Jian Yang

The temperature dependence of the surface plasmon resonance in small metal spheres is calculated using an electron gas model within the Random Phase Approximation. The calculation is mainly devoted to the study of spheres with diameters up…

Mesoscale and Nanoscale Physics · Physics 2017-06-07 Claudia Fasolato , Francesco Sacchetti , Pietro Tozzi , Caterina Petrillo

In this paper we discuss the field enhancement due to surface plasmons resonances of metallic nanostructures, in particular nano spheres on top of a metal, and find maximum field enhancement of the order of 10^2, intensities enhancement of…

Mesoscale and Nanoscale Physics · Physics 2012-12-06 Nicolas Garcia , Ming Bai

Nano- and microparticles are popular media to enhance optical signals, including fluorescence from a dye proximal to the particle. Here we show that homogeneous, lossless, all-dielectric spheres with diameters in the mesoscale range,…

We investigate the coupling of a single molecule to a single spherical gold nanoparticle acting as a nano-antenna. Using scanning probe technology, we position the particle in front of the molecule with nanometer accuracy and measure a…

Other Condensed Matter · Physics 2009-11-11 S. Kuehn , U. Hakanson , L. Rogobete , V. Sandoghdar

Surface plasmons on metals can concentrate light into sub-nanometric volumes and on these near atomic length scales the electronic response at the metal interface is smeared out over a Thomas-Fermi screening length. This nonlocality is a…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Yu Luo , A. I. Fernandez-Dominguez , Aeneas Wiener , S. A. Maier , J. B. Pendry

Surface plasmon polaritons (SSP), moving along a smooth curved interface between two isotropic media with slowly varying dielectric permittivities and magnetic permeabilities and supporting SSP, are studied theoretically. Solutions of…

Optics · Physics 2011-04-20 Maria V. Perel , Dmitry Yu. Zaika

The ability to engineer localized surface plasmon resonances at large scale usually relies on precise nanoscale patterning. Here, we demonstrate that mid-infrared plasmonic responses can instead emerge in unpatterned polysilicon films…