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The effect of quantum and thermal fluctuations on the phase diagram of spin-2 BECs is examined. They are found to play an important role in the nematic part of the phase diagram, where a mean-field treatment of two-body interactions is…

Other Condensed Matter · Physics 2012-02-23 Ari Turner , Ryan Barnett , Eugene Demler , Ashvin Vishwanath

The density functional theory (DFT) is a remarkably successful theory of electronic structure of matter. At the foundation of this theory lies the Kohn-Sham (KS) equation. In this paper, we describe the long-time behaviour of the…

Analysis of PDEs · Mathematics 2021-05-11 Fabio Pusateri , Israel Michael Sigal

Practical density functional theory (DFT) owes its success to the groundbreaking work of Kohn and Sham that introduced the exact calculation of the non-interacting kinetic energy of the electrons using an auxiliary mean-field system.…

Chemical Physics · Physics 2023-11-17 P. del Mazo-Sevillano , J. Hermann

We derive the fluctuation theorem for quantum-state statistics that can be obtained when we initially measure the total energy of a quantum system at thermal equilibrium, let the system evolve unitarily, and record the quantum-state data…

Statistical Mechanics · Physics 2018-08-01 Naoto Tsuji , Masahito Ueda

Nematic order resulting from the partial melting of density-waves has been proposed as the mechanism to explain nematicity in iron-based superconductors. An outstanding question, however, is whether the microscopic electronic model for…

Superconductivity · Physics 2016-02-26 M. H. Christensen , Jian Kang , B. M. Andersen , R. M. Fernandes

Density functional approximations to the exchange-correlation energy of Kohn-Sham theory, such as the local density approximation and generalized gradient approximations, lack the well-known integer discontinuity, a feature that is critical…

Chemical Physics · Physics 2015-06-18 Martin A. Mosquera , Adam Wasserman

Intense time-periodic laser fields can transform the electronic structure of a solid into strongly modified Floquet-Bloch bands. While this suggests multiple pathways to induce electronic orders such as superconductivity or charge density…

Strongly Correlated Electrons · Physics 2019-01-14 Nagamalleswararao Dasari , Martin Eckstein

In time-dependent density-functional theory, exchange and correlation (xc) beyond the adiabatic local density approximation can be described in terms of viscoelastic stresses in the electron liquid. In the time domain, this leads to a…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 H. O. Wijewardane , C. A. Ullrich

We calculate fluctuation corrections to the longitudinal conductivity of disordered superconductors subject to an external magnetic field. We derive analytic expressions that are valid in the entire metallic part of the temperature-magnetic…

Mesoscale and Nanoscale Physics · Physics 2013-08-07 Brian Tarasinski , Georg Schwiete

Gould and Pittalis [Phys. Rev. Lett. 123, 016401 (2019)] recently revealed a density-driven (DD) correlation energy that is specific to many-electron ensembles and must be accounted for by approximations. We derive in this Letter a general…

Chemical Physics · Physics 2020-06-22 Emmanuel Fromager

The fluctuation-dissipation theorem is a central theorem in nonequilibrium statistical mechanics by which the evolution of velocity fluctuations of the Brownian particle under a fluctuating environment is intimately related to its…

Statistical Mechanics · Physics 2015-05-14 Jen-Tsung Hsiang , Tai-Hung Wu , Da-Shin Lee

Density functional theory underlies the most successful and widely used numerical methods for electronic structure prediction of solids. However, it has the fundamental shortcoming that the universal density functional is unknown. In…

Disordered Systems and Neural Networks · Physics 2020-09-23 M. Michael Denner , Mark H. Fischer , Titus Neupert

Materials with correlated electrons often respond very strongly to external or internal influences, leading to instabilities and states of matter with broken symmetry. This behavior can be studied theoretically either by evaluating the…

Strongly Correlated Electrons · Physics 2017-08-15 J. Kunes , I. Leonov , P. Augustinsky , V. Krapek , M. Kollar , D. Vollhardt

The most challenging scenario for Kohn-Sham density functional theory, that is when the electrons move relatively slowly trying to avoid each other as much as possible because of their repulsion (strong-interaction limit), is reformulated…

Strongly Correlated Electrons · Physics 2015-06-05 Giuseppe Buttazzo , Luigi De Pascale , Paola Gori-Giorgi

We present a real-space formulation and higher-order finite-difference implementation of periodic Orbital-free Density Functional Theory (OF-DFT). Specifically, utilizing a local reformulation of the electrostatic and kernel terms, we…

Computational Physics · Physics 2015-12-23 Swarnava Ghosh , Phanish Suryanarayana

With the development of low order scaling methods for performing Kohn-Sham Density Functional Theory, it is now possible to perform fully quantum mechanical calculations of systems containing tens of thousands of atoms. However, with an…

Chemical Physics · Physics 2020-04-03 William Dawson , Stephan Mohr , Laura E. Ratcliff , Takahito Nakajima , Luigi Genovese

Due to efficient scaling with electron number N, density functional theory (DFT) is widely used for studies of large molecules and solids. Restriction of an exact mean-field theory to local potential functions has recently been questioned.…

Other Condensed Matter · Physics 2015-06-24 Robert K. Nesbet

A fundamental weakness of density functional theory (DFT) is the difficulty in making systematic improvements to approximations for the exchange and correlation functionals. In this paper, we follow a wave-function-based approach [N.I.…

Chemical Physics · Physics 2018-10-05 Timothy J. Callow , Nikitas I. Gidopoulos

Mixed order transitions are those which show a discontinuity of the order parameter as well as a divergent correlation length. We show that the behaviour of the order parameter correlation function along the transition line of mixed order…

Statistical Mechanics · Physics 2019-09-04 Mustansir Barma , Satya N. Majumdar , David Mukamel

Order-by-disorder, whereby fluctuations lift an accidental classical ground state degeneracy to stabilize a subset of ordered states, is a recurrent and prominent theme in the field of frustrated magnetism where magnetic moments are subject…

Strongly Correlated Electrons · Physics 2025-05-27 Alexander Hickey , Daniel Lozano-Gómez , Michel J. P. Gingras