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Line emission is strongly dependent on the local environmental conditions in which the emitting tracers reside. In this work, we focus on modelling the CO emission from simulated giant molecular clouds (GMCs), and study the variations in…
Aims. We attempt to understand the presence of gas phase CO below its freezing temperature in circumstellar disks. We study two promising mechanisms to explain this phenomenon: turbulent mixing and photodesorption. Methods. We compute the…
The temperatures of dust grains play important roles in the chemical evolution of molecular clouds. Unlike large grains, the temperature fluctuations of small grains induced by photons may be significant. Therefore, if the grain size…
Ice mantles that formed on top of dust grains are photoprocessed by the secondary ultraviolet (UV) field in cold and dense molecular clouds. UV photons induce photochemistry and desorption of ice molecules. Experimental simulations…
Current gas phase models do not account for the abundances of HNCO isomers detected in various environments, suggesting a formation in icy grain mantles. We attempted to study a formation channel of HNCO and its possible isomers by…
Cosmic rays (CRs) at sub-TeV energies play a fundamental role in the chemical and dynamical evolution of molecular clouds, as they control the ionisation, dissociation, and excitation of H$_{2}$. Their characterisation is important both for…
A major uncertainty in understanding the transport and feedback of cosmic-rays (CRs) within and beyond our Galaxy lies in the unknown CR scattering rates, which are primarily determined by wave-particle interaction at microscopic…
Cosmic rays are usually assumed to be the main ionization agent for the interior of molecular clouds where UV and X-ray photons cannot penetrate. Here we test this hypothesis by limiting ourselves to the case of diffuse clouds and assuming…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…
Cosmic rays (CRs) drive ionization and influence gas dynamics in molecular clouds (MCs), potentially impacting the resulting star formation outcomes. Although previous simulations of individual star formation have included methods for…
AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…
Interstellar ices are largely composed of frozen water. It is important to derive fundamental parameters for H$_2$O ice such as absorption and scattering opacities for which accurate complex refractive indexes are needed. The primary goal…
Abundances and partitioning of ices and gases produced by gas-grain chemistry are governed by adsorption and desorption on grains. Understanding astrophysical observations rely on laboratory measurements of adsorption and desorption rates…
There is long research interest in electron-induced reactions of halogenated molecules. It has been two decades since the cosmic-ray (CR) driven electron-induced reaction (CRE) mechanism for the ozone hole formation was proposed. The…
Hydrogen sulfide (H$_2$S) is thought to be efficiently formed on grain surfaces through the successive hydrogenation of S atoms. Its non-detection so far in astronomical observations of icy dust mantles thus indicates that effective…
The efficiency of radial transport of icy solid material from outer disk to the inner disk is currently unconstrained. Efficient radial transport of icy dust grains could significantly alter the composition of the gas in the inner disk. Our…
Interstellar grains are known to be important actors in the formation of interstellar molecules such as H$_2$, water, ammonia, and methanol. It has been suggested that the so-called interstellar complex organic molecules (iCOMs) are also…
Cosmic rays are an important source of heating in the interstellar medium, in particular in dense molecular cloud cores shielded from the external ultraviolet radiation field. The limits placed on the cosmic-ray ionization rate from…
Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…
Scattering and absorption of X-rays by interstellar dust is calculated for a model consisting of carbonaceous grains and amorphous silicate grains. The calculations employ realistic dielectric functions with structure near X-ray absorption…