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In this paper we analyse the importance of a detailed description of the electronic transitions in ultra-small nanoparticles through the optical response to very small changes of size in systems, whose dimensions are in the subnanometric…
Fundamental upper bounds are given for the plasmonic multipole absorption and scattering of a rotationally invariant dielectric sphere embedded in a lossy surrounding medium. A specialized Mie theory is developed for this purpose and when…
Here we demonstrate a novel smart magnetoplasmonic heterostructure for efficient control of light. It consists of gold nanoparticles embedded in a thin magnetic film covered with a gold layer pierces with periodic nanoslit array. Unique…
We have studied the optical properties of metallic nanoparticles with arbitrary shape. We performed theoretical calculations of the absorption, extinction and scattering efficiencies, which can be directly compared with experiments, using…
Wet-chemistry synthesized Gold nanourchins (Au NUs), characterized by spiky morphologies with spherical cores, exhibit complex and geometry-dependent plasmonic properties distinct from those of symmetrical nanostructures. While plasmon…
For a transparent projection screen based on metallic nanoparticle's localized surface plasmon resonance (LSPR), in the ideal case the metallic nanoparticles dispersed in a transparent matrix only selectively scatter red, green and blue…
Understanding and mastering the mechanical properties of metallic nanoparticles is crucial for their use in a wide range of applications. In this context, we use atomic-scale (Molecular Dynamics) and continuous (Finite Elements)…
In this paper we study, in the time domain, the interaction between localized surface plasmons and photons in arbitrarily shaped metal nanoparticles, by using the Hopfield approach to quantize the plasmon modes, where the electron…
The theory of surface electromagnetic waves (SEMWs) propagating at optical frequencies along the interface of an isotropic noble metal [e.g., gold (Au)] and a uniaxial crystal [e.g., Rutile (TiO$_2$)] is revisited with the Drude-Lorentz…
X-ray diffraction studies of nanoporous gold face the poorly understood diffraction scenario where large coherent crystals are riddled with nanoscale holes. Theoretical considerations derived in this study show that the ligament size of the…
Diamond 1 - 10 micrometers thick membranes are platform for photonic, quantum and opto-mechanic devices with applications across UV-IR spectral ranges. IR characterization of diamond gratings in reflection and transmission showed a change…
The factors controlling the size and morphology of nanoparticles have so far been poorly understood. Data-driven techniques are an exciting avenue to explore this field through the identification of trends and correlations in data. However,…
As part of a consortium between academic and industry, this PhD work investigates the interest and capabilities of organic photo-sensors (OPS) for the optical characterization of suspensions and two-phase flows. The principle of new optical…
We present the first world-wide inter-laboratory comparison of small-angle X-ray scattering (SAXS) for nanoparticle sizing. The measurands in this comparison are the mean particle radius, the width of the size distribution and the particle…
Theoretical description of oscillations of electron liquid in large metallic nanospheres (with radius of few tens nm) is formulated within random-phase-approximation semiclassical scheme. Spectrum of plasmons is determined including both…
We predict the strong enhancement in the photoabsorption of small Mg clusters in the region of 4-5 eV due to the resonant excitation of the plasmon oscillations of cluster electrons. The photoabsorption spectra for neutral Mg clusters…
We present theoretical and experimental studies of the optical response of L-shaped silver nanoparticles. The scattering spectrum exhibits several plasmon resonances that depend sensitively on the polarization of the incident…
Harnessing hot electrons and holes resulting from the decay of localized surface plasmons in nanomaterials has recently led to new devices for photovoltaics, photocatalysis and optoelectronics. Properties of hot carriers are highly tunable…
The plasmonic properties of sphere-like bcc Na nanoclusters ranging from Na$_{15}$ to Na$_{331}$ have been studied by real-time time-dependent local density approximation calculations. The optical absorption spectrum, density response…
Enhanced optical absorption of molecules in the vicinity of metallic nanostructures is key to a number of surface-enhanced spectroscopies and of great general interest to the fields of plasmonics and nano-optics. Yet, experimental access to…