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An analytic approach to the electron transport phenomena in molecular devices is presented. Analyzed devices are composed of organic molecules attached to the two semi-infinite electrodes. Molecular system is described within the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Kamil Walczak

With the objective to understand microscopic principles governing thermal energy flow in nanojunctions, we study phononic heat transport through metal-molecule-metal junctions using classical molecular dynamics (MD) simulations. Considering…

Mesoscale and Nanoscale Physics · Physics 2022-11-23 Jonathan J. Wang , Jie Gong , Alan J. H. McGaughey , Dvira Segal

The exploring and understanding the electronic properties of molecules connected to metallic leads is a vital part of nanoscience if molecule is to have a future. This thesis documents a study for various families of organic and…

Computational Physics · Physics 2016-12-13 Oday A. Al-Owaedi

We study theoretically the length dependence of both conductance and thermopower in metal-molecule-metal junctions made up of dithiolated oligophenylenes contacted to gold electrodes. We find that while the conductance decays exponentially…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 F. Pauly , J. K. Viljas , J. C. Cuevas

The rational design of single molecule electrical components requires a deep and predictive understanding of structure-function relationships. Here we explore the relationship between chemical substituents and the conductance of…

Interference represents one of the most striking manifestation of quantum physics in low-dimensional systems. Despite evidences of quantum interference in charge transport have been known for a long time, only recently signatures of…

Mesoscale and Nanoscale Physics · Physics 2015-09-16 Luca Vannucci , Flavio Ronetti , Giacomo Dolcetto , Matteo Carrega , Maura Sassetti

Motivated by recent experiments, we present here an ab initio study of the impact of the phonon transport on the thermal conductance and thermoelectric figure of merit of C$_{60}$-based single-molecule junctions. To be precise, we combine…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 Jan Christopher Klöckner , Robert Siebler , Juan Carlos Cuevas , Fabian Pauly

We study thermoelectric effects in Kondo correlated quantum dot coupled to ferromagnetic electrodes by calculating conductance, thermopower and thermal conductance in the Kondo regime. We also study the effect of the asymmetry in the…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 M. Krawiec , K. I. Wysokinski

Within the framework of nonequilibrium Green's functions, we investigate the thermoelectric transport in a single molecular junction with electron-phonon and electron-electron interactions. By transforming into a displaced phonon basis, we…

Mesoscale and Nanoscale Physics · Physics 2012-04-26 Jie Ren , Jian-Xin Zhu , James E. Gubernatis , Chen Wang , Baowen Li

The thermoelectric transport through a molecular bridge is discussed, with an emphasis on the effects of inelastic processes of the transport electrons caused by the coupling to the vibrational modes of the molecule. In particular it is…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 O. Entin-Wohlman , Y. Imry , A. Aharony

Thermopower of molecular junctions is sensitive to details in the junction and may increase, decrease, or saturate with increasing chain length, depending on the system. Using McConnell's theory for exponentially suppressed transport…

Mesoscale and Nanoscale Physics · Physics 2014-06-17 Olov Karlström , Mikkel Strange , Gemma C. Solomon

The effect of vibrational motion on resonant charge transport through single molecule junctions is investigated. The study is based on a combination of first-principles electronic structure calculations to characterize the system and…

Other Condensed Matter · Physics 2007-12-24 Claudia Benesch , Martin Cizek , Jiri Klimes , Michael Thoss , Wolfgang Domcke

We present a microscopic theory of single-electron tunneling through metallic nanoparticles connected to the electrodes through molecular bridges. It combines the theory of electron transport through molecular junctions with the description…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

We present a theoretical study of the transport characteristics of molecular junctions, where first-row diatomic molecules are attached to (001) gold and platinum electrodes. We find that the conductance of all of these junctions is of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 J. Ferrer , V. M. Garcia-Suarez

This thesis investigates the mechanically controlled break junctions, with a particular emphasis on elucidating the behaviour of molecular currents at room temperature. The core of this experimental investigation involves a detailed…

Mesoscale and Nanoscale Physics · Physics 2024-09-17 Giovanna Angelis Schmidt

We study the thermopower of a junction between a metal and a strongly correlated semiconductor. Both in the electronic ferroelectric regime and in the Kondo insulator regime the thermoelectric figures of merit, ZT, of these junctions are…

Strongly Correlated Electrons · Physics 2009-07-20 Massimo Rontani , L. J. Sham

The realization of self-assembled molecular-electronic films, whose room-temperature transport properties are controlled by quantum interference (QI), is an essential step in the scale-up QI effects from single molecules to parallel arrays…

In this work we study thermoelectric properties of graphene nanoribbons with side-attached organic molecules. By adopting a single-band tight binding Hamiltonian and the Green's function formalism, we calculated the transmission and Seebeck…

Mesoscale and Nanoscale Physics · Physics 2013-06-26 L. Rosales , C. D. Nunez , M. Pacheco , A. Latge , P. A. Orellana

Molecular bridges covalently bonded to two ferromagnetic electrodes can transform ferromagnetic materials and produce intriguing spin transport characteristics. This paper discusses the impact of molecule induced strong coupling on spin…

Materials Science · Physics 2019-12-04 Pawan Tyagi , Edward Friebe

Measurements of the thermal conductance of single-molecule junctions have recently been reported for the first time. It is presently unclear, how much the heat transport can be controlled through molecule-internal effects. The search for…

Mesoscale and Nanoscale Physics · Physics 2025-10-01 Matthias Blaschke , Fabian Pauly
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