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High-pressure structural search was performed on the hydrogen-rich compound LuBeH$_8$ at pressures up to 200 GPa. We found a $Fm\overline{3}m$ structure that exhibits stability and superconductivity above 100 GPa. Our phonon dispersion,…

Superconductivity · Physics 2024-08-26 Bin Li , Yeqian Yang , Yuxiang Fan , Cong Zhu , Shengli Liu , Zhixiang Shi

The discoveries of high-temperature superconductivity in H3S and LaH10 have excited the search for superconductivity in compressed hydrides. In contrast to rapidly expanding theoretical studies, high-pressure experiments on hydride…

Superconductivity · Physics 2021-09-15 Wuhao Chen , Dmitrii V. Semenok , Xiaoli Huang , Haiyun Shu , Xin Li , Defang Duan , Tian Cui , Artem R. Oganov

The discovery of new high-temperature superconductors is one of the most critical problems in materials, chemistry, and physics. This work systematically investigates fluorite-like structures of XBeH8 (X is Ac, Th, Pa, U, and Np) to gain…

Superconductivity · Physics 2022-09-07 Zhongyu Wan , Tianyi Yang , Wenjun Xu , Ruiqin Zhang

In the last five years a large number of new high-temperature superconductors have been predicted and experimentally discovered among hydrogen-rich crystals, at pressures which are way too high to meet any practical application. In this…

Superconductivity · Physics 2021-08-04 Simone Di Cataldo , Christoph Heil , Wolfgang von der Linden , Lilia Boeri

Ternary hydrides are considered as the ideal candidates with high critical temperature (Tc) stabilized at submegabar pressure, evidenced by the recent discoveries in LaBeH8 (110 K at 80 GPa) and LaB2H8 (106 K at 90 GPa). Here, we…

Superconductivity · Physics 2024-12-02 Tingting Gu , Wenwen Cui , Jian Hao , Jingming Shi , Artur P. Durajski , Hanyu Liu , Yinwei Li

It has been a hot issue to search for hydrides at high pressure with high superconducting transition temperature (Tc). In this work, ternary hydrogen-rich compounds KYHn (n = 1-16) were studied and calculated using the density function…

Superconductivity · Physics 2021-10-27 LingYan Chen

Motivated by the recent discovery of near-room temperature superconductivity in high-pressure superhydrides, we investigate from first-principles the high-pressure superconducting phase diagram of the ternary Ca-B-H system, using ab-initio…

Superconductivity · Physics 2020-08-26 Simone Di Cataldo , Wolfgang von der Linden , Lilia Boeri

The study of superconductivity in compressed hydrides is of great interest due to measurements of high critical temperatures (Tc) in the vicinity of room temperature, beginning with the observations of LaH10 at 170-190 GPa. However, the…

Advances in theoretical calculations boosted the searches for high temperature superconductors, such as sulfur hydrides and rare-earth polyhydrides. However, the required extremely high pressures for stabilizing these superconductors…

Superconductivity · Physics 2024-09-09 Xiangru Tao , Aiqin Yang , Yundi Quan , Biao Wan , Shuxiang Yang , Peng Zhang

The high pressure phases of HBr are explored with an ab initio crystal structure search. By taking into account the contribution of zero-point energy (ZPE), we find that the P4/nmm phase of HBr is thermodynamically stable in the pressure…

Superconductivity · Physics 2017-08-31 Qinyan Gu , Pengchao Lu , Kang Xia , Jian Sun , Dingyu Xing

Here we report targeted high-pressure synthesis of two novel high-$T_C$ hydride superconductors, $P6_3/mmc$-$ThH_9$ and $Fm\bar{3}m$-$ThH_{10}$, with the experimental critical temperatures ($T_C$) of 146 K and 159-161 K and upper critical…

Inspired by the first boron-carbon (B-C) clathrate SrB$_3$C$_3$ and the ternary borohydride KB$_2$H$_8$ [Miao et al., Phys. Rev. B 104 L100504 (2021)], we have performed first-principles density functional theory calculations of the…

Superconductivity · Physics 2024-05-24 Bin Li , Yulan Cheng , Cong Zhu , Jie Cheng , Shengli Liu

Barium hydrides are of interest for their potential in both ionic conductivity and superconductivity. Recently, a superconducting hydride BaH$_{12}$ containing H$_2$ and H${_3}^{-1}$ molecular units was experimentally reported with a…

Superconductivity · Physics 2025-10-07 Yue-Wen Fang , Ion Errea

New stable thorium decahydride $Fm\bar{3}m$-$ThH_{10}$, a record high-temperature superconductor with $T_C$ up to 241 K ($-32^{\circ}C$), critical field $H_C$ up to 71T and superconducting gap ${\Delta_0}$ = 52 meV at 80-100 GPa was…

The search for high-temperature superconductors in hydrides under high pressure has always been a research hotspot. Hydrogen-based superconductors offer an avenue to achieve the long-sought goal of superconductivity at room temperature. We…

Superconductivity · Physics 2023-05-22 Ming Xu , Defang Duan , Wendi Zhao , Decheng An , Hao Song , Tian Cui

Inspired by the synthesis of the high-pressure Fm-3m LaH10 superconducting superhydride, systematic density functional theory (DFT) calculations are performed to study ternaries that could be derived from it by replacing two of the hydrogen…

Superconductivity · Physics 2024-01-02 Nisha Geng , Katerina P. Hilleke , Francesco Belli , Pratik Kumar Das , Eva Zurek

Hydrogen-rich ternary hydrides are promising candidates for high-Tc superconductivity at megabar pressures, yet their chemical space is vast and largely unexplored. Combining evolutionary structure searches with first-principles…

Inspired by recent predictions of superconductivity in B-C framework clathrates, we employ density functional theory to explore potential superconductors among hexagonal hydride-substituted compounds with compositions XB$_8$C, XB$_7$C$_2$,…

Superconductivity · Physics 2025-03-11 Bin Li , Yuxiang Fan , Chuanhui Yin , Junjie Zhai , Cong Zhu , Zhisi Cao , Jie Cheng , Shengli Liu

Superconductivity in highly-pressurized hydrides became primary direction for the exploration of fundamental upper limit for the superconducting transition temperature, Tc, after Drozdov et al (Nature 2015, 525, 73) discovered…

Superconductivity · Physics 2023-08-28 E. F. Talantsev

The recent surprising discovery of superconductivity with critical temperature $T_c$ = 32 K in MoB$_2$ above 70 GPa has led to the search for related materials that may superconduct at similarly high $T_c$ values and lower pressures. We…

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