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Excitons, bound electron-hole pairs, in Two-Dimensional Hybrid Organic Inorganic Perovskites (2D HOIPs) are capable of forming hybrid light-matter states known as exciton-polaritons (E-Ps) when the excitonic medium is confined in an optical…

Two-dimensional (2D) heterostructures (HS) formed by transition-metal dichalcogenide (TMDC) monolayers offer a unique platform for the study of intralayer and interlayer excitons as well as moir\'e-pattern-induced features. Particularly,…

Mesoscale and Nanoscale Physics · Physics 2021-11-15 Mohammed Adel Aly , Manan Shah , Lorenz Maximilian Schneider , Kyungnam Kang , Martin Koch , Eui-Hyeok Yang , Arash Rahimi-Iman

Semiconducting MXenes are an intriguing two-dimensional (2D) material class with promising electronic and optoelectronic properties. Here, we focused on recently prepared Hf-based MXenes, namely Hf$_3$C$_2$O$_2$ and Hf$_2$CO$_2$. Using the…

Materials Science · Physics 2024-04-03 Nilesh Kumar , Miroslav Kolos , Sitangshu Bhattacharya , František Karlický

In this letter, we present non-degenerate ultrafast optical pump-probe studies of the carrier recombination dynamics in MoS$_{2}$ monolayers. By tuning the probe to wavelengths much longer than the exciton line, we make the probe…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Haining Wang , Changjian Zhang , Farhan Rana

The electron-hole liquid, which features a macroscopic population of correlated electrons and holes, may offer a path to room temperature semiconductor devices that harness collective electronic phenomena. We report on the gas-to-liquid…

Mesoscale and Nanoscale Physics · Physics 2019-02-05 Trevor B. Arp , Dennis Pleskot , Vivek Aji , Nathaniel M. Gabor

Decoupling charge and heat transport is essential for optimizing thermoelectric materials. Strategies to inhibit lattice-driven heat transport, however, also compromise carrier mobility, limiting the performance of most thermoelectrics,…

Inherent properties of superconducting Bi2Sr2CaCu2O8+x films, such as the high superconducting transition temperature Tc, efficient Josephson coupling between neighboring CuO layers, and fast quasiparticle relaxation dynamics, make them a…

Excitonic semiconductors have been a subject of research for photovoltaic applications for many decades. Among them, the organic polymers and small molecules based solar cells have now exceeded 19% power conversion efficiency (PCE). While…

Applied Physics · Physics 2023-02-10 Zekun Hu , Da Lin , Jason Lynch , Kevin Xu , Deep Jariwala

Phenomena involving electron transfer are ubiquitous in nature, photosynthesis and enzymes or protein activity being prominent examples. Their deep understanding thus represents a mandatory scientific goal. Moreover, controlling the…

Chemical Physics · Physics 2017-12-01 Carlo Andrea Rozzi , Filippo Troiani , Ivano Tavernelli

Excitons diffusing to a charge-separating interface is a necessary step to convert energy into current in next-generation photovoltaics. In this report, made possible by a new ultrafast spectrometer design, we compare exciton dynamics…

This work develops an analytical model to consistently interpret the steady-state and small-perturbation response (both in the time and frequency domain) of photoanodes for solar water-splitting. In addition to accounting for the…

Materials Science · Physics 2025-03-20 Paola Ragonese , Chiara Maurizio , Boris Kalinic , Thomas Kirchartz , Sandheep Ravishankar

Since dissipative processes are ubiquitous in semiconductors, characterizing how electronic and thermal energy transduce and transport at the nanoscale is vital for understanding and leveraging their fundamental properties. For example, in…

The interaction of exciton and charge transfer (CT) states plays a central role in photo-induced CT processes in chemistry, biology and physics. In this work, we use a combination of two-dimensional electronic spectroscopy (2D-ES),…

Carrier multiplication (CM), a photo-physical process to generate multiple electron-hole pairs by exploiting excess energy of free carriers, is explored for efficient photovoltaic conversion of photons from the blue solar band,…

While being extensively studied as an important physical process to alter exciton population in nanostructures at fs time scale, carrier multiplication has not been considered seriously as a major mechanism for phase transition. Real-time…

Materials Science · Physics 2016-09-20 Junhyeok Bang , Y. Y. Sun , X. -Q. Liu , F. Gao , S. B. Zhang

Exciton and polaron pair dissociation is a key functional aspect of photovoltaic devices. To improve upon the current state of interfacial transport models, we augment the existing classical models of dielectric interfaces by incorporating…

Materials Science · Physics 2017-05-08 Michael J. Waters , Daniel Hashemi , John Kieffer

Chemical vapor deposition (CVD) allows lateral edge epitaxy of transition metal dichalcogenide heterostructures with potential applications in optoelectronics. Critical for carrier and exciton transport is the quality of the two materials…

Modeling the charge-generation process is highly important to understand device physics and optimize power conversion efficiency of bulk-heterojunction (BHJ) organic solar cells (OSCs). Free carriers are generated by both ultrafast exciton…

Mesoscale and Nanoscale Physics · Physics 2016-12-06 Zi Shuai Wang , Wei E. I. Sha , Wallace C. H. Choy

Hot carrier effect, a phenomenon where charge carriers generated by photon absorption remain energetic by not losing much energy, has been one of the leading strategies in increasing solar cell efficiency. Nanostructuring offers an…

Mesoscale and Nanoscale Physics · Physics 2024-09-27 Imam Makhfudz , Hamidreza Esmaielpour , Yaser Hajati , Gregor Koblmüller , Nicolas Cavassilas

In order to provide the best possible performance, modern infrared photodetector designs necessitate extremely precise modeling of the superlattice absorber region. We advance the Rode's method for the Boltzmann transport equation in…

Materials Science · Physics 2023-07-05 Rohit Kumar , Anup Kumar Mandia , Anuja Singh , Bhaskaran Muralidharan