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We study the influence of a scanning nano-electrode on fluorescence excitation spectra of single terrylene molecules embedded in thin p-terphenyl films at cryogenic temperatures. We show that applied voltages less than 10 V can result in…

Chemical Physics · Physics 2010-09-17 Ilja Gerhardt , Gert Wrigge , Vahid Sandoghdar

Spectra of the differential tunneling conductivity for ultrathin lead films grown on Si(111)7x7 single crystals with a thickness from 9 to 50 monolayers have been studied by low-temperature scanning tunneling microscopy and spectroscopy.…

Mesoscale and Nanoscale Physics · Physics 2019-06-12 S. S. Ustavschikov , A. V. Putilov , A. Yu. Aladyshkin

The evolution of charge carriers in photoexcited room temperature ZnO nanoparticles in solution is investigated using ultrafast ultraviolet photoluminescence spectroscopy, ultrafast Zn K-edge absorption spectroscopy and ab-initio molecular…

The internal photoeffect in polythiopentacene (PTP) films is investigated. It is discovered that, in capacitor cells, the spectral dependence of the frontal photo-emf Vf correlates with the PTP absorption spectrum, while that of the back…

Materials Science · Physics 2015-03-23 M. P. Gorishnyi

Single chlorophyll-a molecules, a vital resource for the sustenance of life on Earth, have been investigated by using scanning-tunneling-microscope manipulation and spectroscopy on a gold substrate at 4.6 K. The chlorophyll-a binds on…

Soft Condensed Matter · Physics 2009-11-11 Violeta Iancu , Saw-Wai Hla

Linear and non-linear spectroscopies are powerful tools used to investigate the energetics and dynamics of electronic excited states of both molecules and crystals. While highly accurate \emph{ab initio} calculations of molecular spectra…

Materials Science · Physics 2019-09-26 Alan M. Lewis , Timothy C. Berkelbach

A microscopic physical analysis of the various resistive effects involved in the electronic detection of single biomolecules in a nanopore of a MoS2 nanoribbon is presented. The analysis relies on a combined experimental-theoretical…

Mesoscale and Nanoscale Physics · Physics 2020-04-23 Mingye Xiong , Michael Graf , Nagendra Athreya , Aleksandra Radenovic , Jean-Pierre Leburton

Deterministic control of excitonic properties is key to advancing nanoscale optoelectronic and quantum technologies and to understanding diverse physical, optical, chemical, and biological phenomena. At the molecular scale, these properties…

The low temperature spin dynamics of a Fe8 Single-Molecule Magnet was studied under circularly polarized electromagnetic radiation allowing us to establish clearly photon-assisted tunneling. This effect, while linear at low power, becomes…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 L. Sorace , W. Wernsdorfer , C. Thirion , A. -L. Barra , M. Pacchioni , D. Mailly , B. Barbara

Strong enhancement of molecular circular dichroism has the potential to enable efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded by insufficient yield and low enantiomeric excess. Here, we…

We present an extension of the tunneling theory for scanning tunneling microcopy (STM) to include different types of vibrational-electronic couplings responsible for inelastic contributions to the tunnel current in the strong-coupling…

Photon statistics is a powerful tool for characterizing the emission dynamics of nanoscopic systems and their photophysics. Recent advances that combine correlation spectroscopy with scanning tunneling microscopy-induced luminescence (STML)…

Mesoscale and Nanoscale Physics · Physics 2018-12-20 Pablo Merino , Anna Rosławska , Christopher C. Leon , Abhishek Grewal , Christoph Große , Cesar González , Klaus Kuhnke , Klaus Kern

We consider several fundamental optical phenomena involving single molecules in biased metal-molecule-metal junctions. The molecule is represented by its highest occupied and lowest unoccupied molecular orbitals, and the analysis involves…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

We present a fully ab initio, non-perturbative description of the optical limiting properties of a metal-free phthalocyanine, by simulating the effects of a broadband electric field of increasing intensity. The results confirm reverse…

Materials Science · Physics 2014-05-26 Caterina Cocchi , Deborah Prezzi , Alice Ruini , Elisa Molinari , Carlo A. Rozzi

The Persistent Photoconductivity (PPC) effect was studied in individual tin oxide (SnO2) nanobelts as a function of temperature, in air, helium, and vacuum atmospheres, and low temperature Photoluminescence measurements were carried out to…

Materials Science · Physics 2012-12-12 E. R. Viana , J. C. González , G. M. Ribeiro , A. G. de Oliveira

Hybrid heterostructures combining transition metal dichalcogenides (TMDs) with light-harvesting dyes are promising materials for next-generation optoelectronics. Yet, controlling and understanding interfacial charge transfer mechanisms in…

Understanding light-matter interaction at the nanoscale requires probing the optical properties of matter at the individual nano-absorber level. To this end, we have developed a nanomechanical photothermal sensing platform that can be used…

Optics · Physics 2024-06-07 Kostas Kanellopulos , Robert G. West , Silvan Schmid

Phenomena that are highly sensitive to magnetic fields can be exploited in sensors and non-volatile memories. The scaling of such phenomena down to the single molecule level may enable novel spintronic devices. Here we report…

Mesoscale and Nanoscale Physics · Physics 2015-10-09 Ben Warner , Fadi El Hallak , Henning Prüser , John Sharp , Mats Persson , Andrew J. Fisher , Cyrus F. Hirjibehedin

In this paper we review the applicability of autofluorescent proteins for single-molecule imaging in biology. The photophysical characteristics of several mutants of the Green Fluorescent Protein (GFP) and those of DsRed are compared and…

Optics · Physics 2007-05-23 Laurent Cognet , Françoise Coussen , Daniel Choquet , Brahim Lounis

Layered materials have attracted significant interest because of their unique properties. Van der Waals heterostructures based on transition-metal dichalcogenides have been extensively studied because of potential optoelectronic…