Related papers: Dissociation slowdown by collective optical respon…
We study the dissociation dynamics of a diatomic molecule, modeled as a Morse oscillator, coupled to an optical cavity. In both classical and quantum dynamics simulations, a marked suppression of the dissociation probability is observed for…
An unstable condensate of diatomic molecules will coherently disassociate into correlated pairs of atoms. This dissociation process exhibits very rich quantum dynamics depending on the quantum statistics of the constituent atoms. We show…
We study numerically the slow (subradiant) decay of the fluorescence of motionless atoms after a weak pulsed excitation. We show that, in the linear-optics regime and for an excitation detuned by several natural linewidths, the slow decay…
Slow light in photonic crystals and other periodic structures is associated with stationary points of the photonic dispersion relation, where the group velocity of light vanishes. We show that in certain cases, the vanishing group velocity…
Quantum dynamics of the photoisomerization of a single 3,3'-diethyl-2,2'-thiacynine iodide molecule embedded in an optical microcavity was theoretically studied. The molecule was coupled to a single cavity mode via the quantum Rabi…
The fast dynamics of molecular polaritonics is scrutinized theoretically through the implementation of two-dimensional spectroscopy protocols. We derive conceptually simple and computationally efficient formulas to calculate two-dimensional…
Photodissociation is the dominant removal process of molecules in any region exposed to intense ultraviolet (UV) radiation. This includes diffuse and translucent interstellar clouds, dense photon-dominated regions, high velocity shocks, the…
We consider the photodissociation of ground-state bosonic molecules trapped in an optical lattice potential into two-component fermionic atoms. The system is assumed to be described by a one-band resonantly-coupled Bose-Fermi Hubbard model.…
Understanding the quantum dynamics of strongly coupled molecule-cavity systems remains a significant challenge in molecular polaritonics. This work develops a comprehensive self-consistent model simulating electromagnetic interactions of…
A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…
In our model the electron dynamics are described by a two-state approximation. This might appear a rough approximation since it neglects coupling through excited electronic states and ionization channels. However at high intensity (laser…
We study theoretically the squeezing spectrum and second-order correlation function of the output light for an optomechanical system in which a mechanical oscillator modulates the cavity linewidth (dissipative coupling). We find strong…
We analyze the photon statistics of a weakly driven optomechanical system and discuss the effect of photon blockade under single photon strong coupling conditions. We present an intuitive interpretation of this effect in terms of displaced…
The propagation of polarized photons in optical media can be effectively modeled by means of quantum dynamical semigroups. These generalized time evolutions consistently describe phenomena leading to loss of phase coherence and dissipation…
We propose a strategy for enabling photodissociation of a normally photostable molecule through coupling to a nanoparticle plasmon. The large possible coupling on the single-molecule level combined with the highly lossy nature of plasmonic…
We theoretically demonstrate that chemical reaction rate constant can be significantly suppressed by coupling molecular vibrations with an optical cavity, exhibiting both the collective coupling effect and the cavity-frequency modification…
Optical solitons are known to be classically stable objects which are robust to perturbations. In this work, we show that due to quantum mechanical effects, an optical soliton that is initially in a classical soliton coherent state will…
The dipolar dissociation of molecular oxygen due to 21-35 eV energy electron collision has been studied using the time sliced velocity map imaging technique. A rough estimation about the threshold of the process and the kinetic energy and…
Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…
An ab initio simulation of strong-field photodissociation of diatomic molecules was developed, inspired by recent dissociation experiments of F2-. The transition between electronic states was modeled, including the laser pulse and…