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Short-range order (SRO) in Fe-rich Fe-Cr alloys is investigated by means of atomistic off-lattice Monte Carlo simulations in the semi-grand canonical ensemble using classical interatomic potentials. The SRO parameter defined by Cowley…

Materials Science · Physics 2010-09-03 Paul Erhart , Alfredo Caro , Magdalena Serrano de Caro , Babak Sadigh

To describe chemical ordering in solid solutions systems Warren-Cowley short-range parameters are ordinarily used. However, they are not directly suited for application to long-range ordered systems, as they do not converge to zero for…

Chemical Physics · Physics 2016-12-21 Markus Stana , Bogdan Sepiol , Rafal Kozubski , Michael Leitner

In solids, chemical short-range order (CSRO) refers to the self-organisation of atoms of certain species occupying specific crystal sites. CSRO is increasingly being envisaged as a lever to tailor the mechanical and functional properties of…

Chemical short-range order (CSRO), a form of nanoscale special atom arrangement, has been found to significantly alter material properties such as dislocation motion and defect dynamics in various alloys. Here, we use Fe-Ni-Cr alloys to…

Materials Science · Physics 2023-05-19 Hamdy Arkoub , Miaomiao Jin

Metallic alloys often form phases - known as solid solutions - in which chemical elements are spread out on the same crystal lattice in an almost random manner. The tendency of certain chemical motifs to be more common than others is known…

Materials Science · Physics 2024-06-21 Killian Sheriff , Yifan Cao , Tess Smidt , Rodrigo Freitas

Short-range ordering (SRO) tendency for disordered alloys is considered as competition between chemical ordering and geometric (mainly, difference in atomic radius for constituents) effects. Especially for multicomponent (including the…

Materials Science · Physics 2019-05-22 Koretaka Yuge , Shouno Ohta

Chemical short-range order (SRO) provides new opportunities for tuning alloy properties, but conventional computational thermodynamics frameworks such as CALPHAD, based on Bragg-Williams mean-field approximations, cannot properly describe…

Materials Science · Physics 2025-08-12 Chuliang Fu

Traditional metallic alloys are mixtures of elements where the atoms of minority species tend to distribute randomly if they are below their solubility limit, or lead to the formation of secondary phases if they are above it. Recently, the…

The effect of chemical short-range order (CSRO) on primary radiation damage in MoNbTaVW high-entropy alloys is investigated using hybrid Monte Carlo/molecular dynamics simulations with a machine-learned potential. We show that CSRO enhances…

Materials Science · Physics 2025-07-17 Jiahui Liu , Shuo Cao , Yanzhou Wang , Zheyong Fan , Guocai Lv , Ping Qian , Yanjing Su

Chemical short-range order (SRO) affects the distribution of elements throughout the solid-solution phase of metallic alloys, thereby modifying the background against which microstructural evolution occurs. Investigating such…

Materials Science · Physics 2024-07-10 Yifan Cao , Killian Sheriff , Rodrigo Freitas

Short-range ordering (SRO) in multi-principal element alloys influences material properties such as strength and corrosion. While some degree of SRO is expected at equilibrium, predicting the kinetics of its formation is challenging. We…

Materials Science · Physics 2024-07-02 Anas Abu-Odeh , Bin Xing , Penghui Cao , Blas Pedro Uberuaga , Mark Asta

Exploiting Chemical Short-Range Order (CSRO) is a promising avenue for manipulating the properties of alloys. However, existing modeling frameworks are not sufficient to predict CSRO in multicomponent alloys (>3 components) in an efficient…

Materials Science · Physics 2024-02-16 Chu-Liang Fu , Rajendra Prasad Gorrey , Bi-Cheng Zhou

Short-range order (SRO) in disordered alloys is typically interpreted as competition between chemical effect of negative (or positive) energy gain by mixing constituent elements and geometric effects comes from difference in effective…

Disordered Systems and Neural Networks · Physics 2018-05-24 Koretaka Yuge

We present theoretical study of ordering phenomena in binary $C_{1-x}B_{x}$, $C_{1-x}N_{x}$ and ternary $B_{x}C_{1-x-y}N_{y}$ alloys forming two-dimensional, graphene-like systems. For calculating energy of big systems (20 000 atoms in the…

Mesoscale and Nanoscale Physics · Physics 2017-01-11 Agnieszka Jamróz , Jacek A. Majewski

In high-entropy alloys (HEAs), the local chemical fluctuations from disordered solute solution state into segregation, precipitation and ordering configurations are complex due to the large number of elements. In this work, the cluster…

Materials Science · Physics 2017-05-05 A. Fernandez-Caballero , J. S. Wrobel , P. M. Mummery , D. Nguyen-Manh

In multicomponent lattice problems, e.g., in alloys, and at crystalline surfaces and interfaces, atomic arrangements exhibit spatial correlations that dictate the kinetic and thermodynamic phase behavior. These correlations emerge from…

Statistical Mechanics · Physics 2024-03-28 Abhijit Chatterjee

We develop a percolation model for face centered cubic binary alloys with chemical short-range order (SRO) to account for chemical ordering/clustering that occurs in nominally random solid solutions. We employ a lattice generation scheme…

Materials Science · Physics 2024-08-28 Abhinav Roy , Karl Sieradzki , James M. Rondinelli , Ian D. McCue

An idealized high entropy oxide is characterized by perfect chemical disorder and perfect positional order. In this work, we investigate the extent to which short-range order (SRO) and local structural distortions impede that idealized…

Electronic-structure methods based on density-functional theory (DFT) were used to directly quantify the effect of chemical short-range order (SRO) on thermodynamic, structural, and electronic properties of archetypal face-centered-cubic…

Materials Science · Physics 2023-05-16 Will Morris , Duane D. Johnson , Prashant Singh

Order parameters based on spherical harmonics and Fourier coefficients already play a significant role in condensed matter research in the context of systems of spherical or point particles. Here, we extend these types of order parameter to…

Soft Condensed Matter · Physics 2010-12-22 Aaron S. Keys , Christopher R. Iacovella , Sharon C. Glotzer
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