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The local electronic structure of muons (Mu) as dilute pseudo-hydrogen in single-crystalline $\beta$-Ga$_2$O$_3$ has been studied by the muon spin rotation/relaxation ($\mu$SR). High-precision measurements over a long time range of $\sim$25…

Materials Science · Physics 2023-02-01 M. Hiraishi , H. Okabe , A. Koda , R. Kadono , T. Ohsawa , N. Ohashi , K. Ide , T. Kamiya , H. Hosono

The study on the electronic state of muon as pseudo-hydrogen (represented by the elemental symbol Mu) has long been appreciated as one of the few methods to experimentally access the electronic state of dilute hydrogen (H) in semiconductors…

Materials Science · Physics 2022-09-16 M. Hiraishi , H. Okabe , A. Koda , R. Kadono , H. Hosono

The electronic and magnetic states of $\beta$-MnO$_{2}$ in terms of hydrogen impurities have been investigated by muon spin rotation ($\mu$SR) technique combined with density-functional theory (DFT) calculations for muon as pseudo-hydrogen.…

Materials Science · Physics 2024-01-05 H. Okabe , M. Hiraishi , A. Koda , S. Takeshita , K. M. Kojima , I. Yamauchi , T. Ohsawa , N. Ohashi , H. Sato , R. Kadono

We report on the local electronic structure of interstitial muon (Mu) as pseudo-hydrogen in In-Ga-Zn oxide (IGZO) semiconductor studied by muon spin rotation/relaxation ($\mu$SR) experiment. In polycrystalline (c-) IGZO, it is inferred that…

Materials Science · Physics 2019-09-19 K. M. Kojima , M. Hiraishi , H. Okabe , A. Koda , 2 R. Kadono , K. Ide , S. Matsuishi , H. Kumomi , T. Kamiya , H. Hosono

In this paper, using a standard quantum chemistry approach based on pseudopotentials for atomic core representation, Gaussian basis sets, and effective core polarization potentials, we investigate the electronic properties of the MgH$^+$…

Quantum Physics · Physics 2015-05-13 Mireille Aymar , Romain Guérout , Mohamed Sahlaoui , Olivier Dulieu

The formation of hydrogen-like muonium (Mu) has been studied as a function of implantation energy in intrinsic Si, thin films of condensed van der Waals gases (N2, Ne, Ar, Xe), fused and crystalline quartz and sapphire. By varying the…

Other Condensed Matter · Physics 2009-11-13 T. Prokscha , E. Morenzoni , D. G. Eshchenko , N. Garifianov , H. Glueckler , R. Khasanov , H. Luetkens , A. Suter

Hydrogen is a promising energy carrier that can push forward the energy transition because of its high energy density (142 MJ kg-1), variety of potential sources, low weight and low environmental impact, but its storage for automotive…

Magnesium dihydride ($\mgh$) stores 7.7 weight % hydrogen, but it suffers from a high thermodynamic stability and slow (de)hydrogenation kinetics. Alloying Mg with lightweight transition metals (TM = Sc, Ti, V, Cr) aims at improving the…

Materials Science · Physics 2009-02-04 Suleyman Er , Dhirendra Tiwari , Gilles A. de Wijs , Geert Brocks

Intermetallic compounds such as {A$_{2}$B$_{7}$} alloys are promising candidates for mobile hydrogen storage applications due to their high and reversible hydrogen absorption capacity. We compute the absorption isotherm of…

Developing solid-state hydrogen storage materials is as pressing as ever, which requires a comprehensive understanding of the dehydrogenation chemistry of a solid-state hydride. Transition state search and kinetics calculations are…

Materials Science · Physics 2024-04-30 Chaoqun Li , Weijie Yang , Hao Liu , Xinyuan Liu , Xiujing Xing , Zhengyang Gao , Shuai Dong , Hao Li

Liquid metallic hydrogen (LMH) was recently produced under static compression and high temperatures in bench-top experiments. Here, we report a study of the optical reflectance of LMH in the pressure region of 1.4-1.7 Mbar and use the Drude…

Materials Science · Physics 2022-06-01 Mohamed Zaghoo , Isaac F. Silvera

The structure, lattice dynamics and mechanical properties of the magnesium hydroxide have been investigated with static density functional theory calculations as well as \it {ab initio} molecular dynamics. The hypothesis of a superstructure…

Reversible hydrogen uptake and the metal/dielectric transition make the Mg/MgH$_2$ system a prime candidate for solid state hydrogen storage and dynamic plasmonics. However, high dehydrogenation temperatures and slow dehydrogenation hamper…

Plutonium dihydride and trihydride show strikingly similar crystal structures when viewed as close-packed Pu planes with ABC and AB stacking, respectively. The similarity serves as a framework for density functional theory (DFT)…

Materials Science · Physics 2013-07-03 Sven P. Rudin

The current energy transition imposes a rapid implementation of energy storage systems with high energy density and eminent regeneration and cycling efficiency. Metal hydrides are potential candidates for generalized energy storage, when…

Using two first-principles computer simulation techniques, path integral Monte-Carlo and density functional theory molecular dynamics, we derive the equation of state of magnesium in the regime of warm dense matter, with densities ranging…

Materials Science · Physics 2020-08-20 Felipe González-Cataldo , François Soubiran , Burkhard Militzer

Magnesium alanate Mg(AlH4)2 has recently raised interest as a potential material for hydrogen storage. We apply ab initio calculations to characterize structural, electronic and energetic properties of Mg(AlH4)2. Density functional theory…

Materials Science · Physics 2007-05-23 M. J. van Setten , G. A. de Wijs , V. A. Popa , G. Brocks

We have used diffusion Monte Carlo (DMC) calculations to study the structural properties of magnesium hydride (MgH$_2$), including the pressure-volume equation of state, the cohesive energy and the enthalpy of formation from magnesium bulk…

Materials Science · Physics 2009-11-13 M. Pozzo , D. Alfè

We combine two first-principles computer simulation techniques, path integral Monte-Carlo and density functional theory molecular dynamics, to determine the equation of state of magnesium oxide in the regime of warm dense matter, with…

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