Related papers: The vanishing of excess heat for nonequilibrium pr…
We discuss via general arguments and examples when and why the steady nonequilibrium heat capacity vanishes with temperature. The framework is the one of Markov jump processes on finite connected graphs where the condition of local detailed…
The extended Third Law of thermodynamics for nonequilibrium jump processes is studied in previous collaborative papers (Kh et al.,2023) [1,2], where the nonequilibrium heat capacity and the excess heat with the corresponding quasipotential…
We show how to extend the concept of heat capacity to nonequilibrium systems. The main idea is to consider the excess heat released by an already dissipative system when slowly changing the environment temperature. We take the framework of…
The Nernst heat theorem is probed from purely thermodynamic arguments connected with the second law of thermodynamics, and alien to the vanishing of the specific heats, or to the unattainability of the zeroth isotherm. If the proof is…
By starting from the Euler chain rule of three thermodynamic quantities, it is proved that both the Nernst equation and the vanishing heat capacity at absolute zero temperature are mutually deducible and equivalent. Simultaneously, it is…
One general consequence of the Nernst theorem is derived, i.e., the various heat capacities of a thermodynamic system under different constraints approach zero as the temperature approaches absolute zero. The temperature dependence of the…
A corollary of the third law of thermodynamics is that the heat capacities of a system approach zero as the temperature approaches absolute zero Kevin. Many have attempted to take the corollary as the third law, but two counterexamples has…
We study the asymptotic dynamics of arbitrary linear quantum open systems which are periodically driven while coupled with generic bosonic reservoirs. We obtain exact results for the heat flowing into the network, which are valid beyond the…
We investigate how introducing slow, time-dependent perturbations to a steady, nonequilibrium process alters the expected (excess) values of important observables, such as the dynamical activity and entropy flux. When we make a cyclic…
The third law of thermodynamics has been verified experimentally, but how to perfectly express such a law in theory has become a cross-century problematic issue. It is found from the recent researches that by introducing an innovative…
Close to equilibrium, the excess heat governs the static fluctuations. We study the heat capacity in that McLennan regime, i.e., in linear order around equilibrium, using an expression in terms of the average energy that extends the…
The third law of thermodynamics in the form of the unattainability principle states that exact ground-state cooling requires infinite resources. Here we investigate the amount of non-equilibrium resources needed for approximate cooling. We…
The notion of a nonequilibrium heat capacity is important for bio-energetics and for calorimetry of active materials more generally. It centers around the notion of excess heat or excess work dissipated during a quasistatic relaxation…
The third law of thermodynamics has a controversial past and a number of formulations due to Planck, Einstein, and Nernst. It's most accepted version, the unattainability principle, states that "any thermodynamic process cannot reach the…
The zeroth principle of thermodynamics in the form "temperature is uniform at equilibrium" is notoriously violated in relativistic gravity. Temperature uniformity is often derived from the maximization of the total number of microstates of…
The third law of thermodynamics, also known as the Nernst unattainability principle, puts a fundamental bound on how close a system, whether classical or quantum, can be cooled to a temperature near to absolute zero. On the other hand, a…
According to the Nernst theorem or, equivalently, the third law of thermodynamics, the absolute zero temperature is not attainable. Starting with an initial positive temperature, we show that there exist solutions to a Kelvin-Voigt model…
Thermodynamics, the branch of physics concerned with the description of macroscopic bodies, heat exchange and the conversion of different forms of energy is based on four laws: the zeroth law, which states that bodies in thermal contact…
The Principle of Unattainability rules out the attainment of absolute zero temperature by any finite physical means, no matter how idealised they could be. Nevertheless, we clarify that the Third Law of Thermodynamics, as defined by…
The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that…