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We report a benchmark theoretical investigation of both adiabatic and vertical electron affinities of five DNA and RNA nucleobases: adenine, guanine, cytosine, thymine and uracil using state-of-the-art equation of motion coupled cluster…

Chemical Physics · Physics 2014-09-26 Chintya Kumar Dutta , Turbasu Sengupta , Nayana Vaval , Sourav Pal

We investigate a spin-boson inspired model of electron transfer, where the diabatic coupling is given by a position-dependent phase, exp(iWx). We consider both equilibrium and nonequilibrium initial conditions. We show that, for this model,…

Chemical Physics · Physics 2022-08-30 Suraj Chandran , Yanze Wu , Hung-Hsuan Teh , David H. Waldeck , Joseph E. Subotnik

Inspired by the recently-reported strong electric-dipole (E1) transition between the weakly-bound first and second excited states, 3/2- at 765 keV and 1/2+ at 885 keV, in the nucleus 27Ne, the E1 transition is estimated in a model by…

Nuclear Theory · Physics 2019-09-04 Ikuko Hamamoto

Mathematical descriptions of the interplay between strong electron correlations and lattice degrees of freedom are of enormous importance in the development of new devices based on metal oxides such as VO$_{2}$ and the Cuprate…

Strongly Correlated Electrons · Physics 2020-12-03 Jamie M Booth

The coexistence of electric dipoles and itinerant electrons in a solid was postulated decades ago, before being experimentally established in several 'polar metals' during the last decade. Here, we report a concentration-driven…

Strongly Correlated Electrons · Physics 2023-10-13 Xiaohui Yang , Wanghua Hu , Jialu Wang , Zhuokai Xu , Tao Wang , Zhefeng Lou , Xiao Lin

Entangled photon pairs are essential for many applications in quantum technologies. Recent theoretical studies demonstrated that different types of entangled Bell states can be created in a constantly driven four-level quantum…

Mesoscale and Nanoscale Physics · Physics 2023-02-21 Tim Seidelmann , Michael Cosacchi , Moritz Cygorek , Doris E. Reiter , Alexei Vagov , Vollrath Martin Axt

Solid state physics deals with systems composed of atoms with strongly bound electrons. The tunneling probability of each electron is determined by interactions that typically extend to neighboring sites, as their corresponding wave…

Materials Science · Physics 2019-11-27 F. Ramírez-Ramírez , E. Flores-Olmedo , G. Báez , E. Sadurní , R. ~A. Méndez-Sánchez

The formation of anionic species in the interstellar medium from interaction of linear molecules containing carbon, nitrogen and hydrogen as atomic components (polyynes) with free electrons in the environment is modelled via a quantum…

Astrophysics of Galaxies · Physics 2015-06-05 F. Carelli , T. Grassi , F. Sebastianelli , F. A. Gianturco

We study the spin-dependent electronic excitations in alkali-metal nanoparticles. Using numerical and analytical approaches, we focus on the resonances in the response to spin-dependent dipole fields. In the spin-dipole absorption spectrum…

Mesoscale and Nanoscale Physics · Physics 2009-09-18 Yue Yin , Paul-Antoine Hervieux , Rodolfo A. Jalabert , Giovanni Manfredi , Emmanuel Maurat , Dietmar Weinmann

Planar rotors can be realized by confining molecular ions or charged nanoparticles together with atomic ions in a Paul trap. We study the case of molecular ions or charged nanoparticles that have an electric dipole moment which couples to…

Quantum Physics · Physics 2025-04-02 Monika Leibscher , Ferdinand Schmidt-Kaler , Christiane P. Koch

In the construction of diabatic vibronic Hamiltonians for quantum dynamics in the excited-state manifold of molecules, the coupling constants are often extracted solely from information on the excited-state energies. Here, a new protocol is…

Chemical Physics · Physics 2018-04-02 Maria Fumanal , Felix Plasser , Sebastian Mai , Chantal Daniel , Etienne Gindensperger

Associative electronic detachment (AED) between anions and neutral atoms leads to the detachment of the anion's electron resulting in the formation of a neutral molecule. It plays a key role in chemical reaction networks, like the…

Through a combined theoretical and experimental effort, we uncover a yet unidentified mechanism that strengthens considerably electron-phonon coupling in materials where electron accumulation leads to population of multiple valleys. Taking…

Mesoscale and Nanoscale Physics · Physics 2019-08-14 Evgeniy Ponomarev , Thibault Sohier , Marco Gibertini , Helmuth Berger , Nicola Marzari , Nicolas Ubrig , Alberto F. Morpurgo

We present a qualitative model for a fundamental process in molecular electronics: the change in conductance upon bond breaking. In our model a diatomic molecule is attached to spin-polarized contacts. Employing a Hubbard Hamiltonian,…

Materials Science · Physics 2008-06-24 Ali Goker , Francois Goyer , Matthias Ernzerhof

What are the ground states of an interacting, low-density electron system? In the absence of disorder, it has long been expected that as the electron density is lowered, the exchange energy gained by aligning the electron spins should…

Strongly Correlated Electrons · Physics 2020-12-07 Md. S. Hossain , M. K. Ma , K. A. Villegas Rosales , Y. J. Chung , L. N. Pfeiffer , K. W. West , K. W. Baldwin , M. Shayegan

We present a new scheme for rotations of a charge qubit associated with a singly ionized pair of donor atoms in a semiconductor host. The logical states of such a qubit proposed recently by Hollenberg et al. are defined by the lowest two…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 L. A. Openov

We consider $N$ interacting dipolar bosonic atoms at zero temperature in a double-well potential. This system is described by the two-space-mode extended Bose-Hubbard (EBH) Hamiltonian which includes (in addition to the familiar BH terms)…

Quantum Gases · Physics 2016-08-24 Michele Pizzardo , Giovanni Mazzarella , Luca Salasnich

From a fundamental and application point of view it is of importance to understand how charge carrier generation and transport in a conjugated polymer (CP):fullerene blend are affected by the blend morphology. In this work light-induced…

Soft Condensed Matter · Physics 2017-09-13 Tom J. Savenije , Andreas Sperlich , Hannes Kraus , Oleg G. Poluektov , Martin Heeney , Vladimir Dyakonov

We relate the phase separation observed in many crystals with pronounced electron correlations to the regions of negative electron compressibility. They were found in several models describing strong electron correlations. At low…

Strongly Correlated Electrons · Physics 2022-10-25 Alexei Sherman

We present here results of atomistic theory of electrons confined by metallic gates in a single layer of transition metal dichalcogenides. The electronic states are described by the tight-binding model and computed using a computational box…

Mesoscale and Nanoscale Physics · Physics 2020-01-22 Maciej Bieniek , Ludmila Szulakowska , Pawel Hawrylak
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