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An abstract network approach is proposed for the description of the dynamics in reactive processes. The phase space of the variables (concentrations in reactive systems) is partitioned into a finite number of segments, which constitute the…

Statistical Mechanics · Physics 2015-06-17 A. Provata , E. Panagakou

The physics of active systems of self-propelled particles, in the regime of a dense liquid state, is an open puzzle of great current interest, both for statistical physics and because such systems appear in many biological contexts. We…

Soft Condensed Matter · Physics 2017-10-26 Saroj Kumar Nandi , Nir S. Gov

Quasiclassical methods for non-adiabatic quantum dynamics can reveal new features of quantum effects, such as tunneling evolution, that are harder to reveal in standard treatments based on wave functions of stationary states. Here, these…

General Relativity and Quantum Cosmology · Physics 2022-05-06 Martin Bojowald , Pip Petersen

The process of nuclear multifragmentation has been implemented, together with evaporation and fission channels of the disintegration of excited remnants in nucleus-nucleus collisions using percolation theory and the intranuclear cascade…

Nuclear Theory · Physics 2009-11-07 G. Musulmanbekov , A. Al--Haidary

Here we first develop the thermodynamics of microcanonical phase transitions of first and second order in systems which are thermodynamically stable in the sense of van Hove. We show how both kinds of phase transitions can unambiguously be…

Condensed Matter · Physics 2019-08-17 D. H. E. Gross , M. E. Madjet , O. Schapiro

We explore the relation between the quantum and semiclassical instanton approximations for the reaction rate constant. From the quantum instanton expression, we analyze the contributions to the rate constant in terms of minimum-action paths…

Chemical Physics · Physics 2019-10-16 Christophe L. Vaillant , Manish J. Thapa , Jiří Vaníček , Jeremy O. Richardson

The atomic nucleus, viewed as a system of bound quarks, should, in principle, be described within an effective theory of low-energy quantum chromodynamics. This paper provides an overview of recently developed models that embody essential…

Nuclear Theory · Physics 2026-05-05 B. Kosyakov , E. Popov , M. Vronsky

We developed a general theoretical approach and a user-ready computer code that permit to study the dynamics of collisional energy transfer and ro-vibrational energy exchange in complex molecule-molecule collisions. The method is a mixture…

Chemical Physics · Physics 2024-02-06 Carolin Joy , Bikramaditya Mandal , Dulat Bostan , Marie-Lise Dubernet , Dmitri Babikov

The task of a first principles theoretical calculation of the rate of gas to liquid nucleation has remained largely incomplete despite the existence of reliable results from unbiased simulation studies at large supersaturation. Although the…

Soft Condensed Matter · Physics 2024-02-26 Subhajit Acharya , Biman Bagchi

A novel mechanism of prompt nuclear fragmentation is proposed. Assuming micro-canonical or canonical equilibrium, it is shown that a strong enhancement of the accessible phase space volume, due to the diffuceness of the nuclear surface,…

Nuclear Theory · Physics 2009-10-31 J. Toke , W. U. Schroeder

Electron Transfer (ET) reactions are modeled by the dynamics of a quantum two-level system (representing the electronic state) coupled to a thermalized bath of classical harmonic oscillators (representing the nuclei degrees of freedom).…

Chemical Physics · Physics 2014-11-24 Serge Aubry

We study the non-integrable Dicke model, and its integrable approximation, the Tavis-Cummings model, as functions of both the coupling constant and the excitation energy. Excited-state quantum phase transitions (ESQPT) are found analyzing…

Quantum Physics · Physics 2014-03-24 M. A. Bastarrachea-Magnani , S. Lerma-Hernandez , J. G. Hirsch

We study the kinetics of the first order phase separation transition in boson-fermion cold-atom mixtures. At sufficiently low temperatures such a transition is driven by quantum fluctuations responsible for the formation of critical nuclei…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Dmitry Solenov , Dmitry Mozyrsky

Geometrically frustrated interactions may render classical ground-states macroscopically degenerate. The connection between classical and quantum liquids and how the degeneracy is affected by quantum fluctuations is, however, less well…

Strongly Correlated Electrons · Physics 2019-05-31 Miguel M. Oliveira , Pedro Ribeiro , Stefan Kirchner

The many approaches that have been pursued in seeking an understanding of nuclear rotational dynamics are reviewed and reassessed with a view to their development in the light of recent progress and the research tools that are now…

Nuclear Theory · Physics 2017-10-12 David J. Rowe

As a companion work to [1], this Note presents a series of simple formulae and explicit results that illustrate and highlight why classical variational phase-field models cannot possibly predict fracture nucleation in elastic brittle…

Materials Science · Physics 2024-11-22 Farhad Kamarei , John E. Dolbow , Oscar Lopez-Pamies

Nucleation, the birth of a stable cluster from disorder, is inherently stochastic. Yet up to date, there are no quantitative studies on NaCl nucleation that accounts for its stochastic nature. Here, we report the first stochastic treatment…

The quasi-chemical organization of the potential distribution theorem -- molecular quasi-chemical theory (QCT) -- enables practical calculations and also provides a conceptual framework for molecular hydration phenomena. QCT can be viewed…

Chemical Physics · Physics 2021-05-14 Dilipkumar N. Asthagiri , Michael E. Paulaitis , Lawrence R. Pratt

We explore the emergence of complex structures within reaction networks, focusing on nuclear reaction networks relevant to stellar nucleosynthesis. The work presents a theoretical framework rooted in Chemical Organization Theory (COT) to…

Solar and Stellar Astrophysics · Physics 2026-01-13 Pedro Maldonado-Lang , Clément Vidal

Differences in activities in colloidal particles are sufficient to drive phase separation between active and passive (or less active) particles, even if they have only excluded volume interactions. In this paper, we study the phase…

Soft Condensed Matter · Physics 2020-05-27 Efe Ilker , Jean-François Joanny