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Multi-configurational approaches yield universal wave function parameterizations that can qualitatively well describe electronic structures along reaction pathways. For quantitative results, multi-reference perturbation theory is required…

Chemical Physics · Physics 2016-09-08 Christopher J. Stein , Vera von Burg , Markus Reiher

In electronic structure theory, variational methods offer a valuable paradigm for approximating electronic ground states. However, for historical reasons, this principle is mostly restricted to model chemistries in pre-defined fixed basis…

Quantum Physics · Physics 2025-11-17 Fabian Langkabel , Stefan Knecht , Jakob S. Kottmann

This work is a collection of initial calculations and formal considerations within the Salpeter-Sucher exact equal-time relativistic quantum electrodynamics framework. The calculations are carried out as preparation for the computation of…

Chemical Physics · Physics 2024-06-11 Adám Margócsy , Edit Mátyus

A quantum electrodynamics (QED) correction surface for the simplest polyatomic and polyelectronic system H$_3^+$ is computed using an approximate procedure. This surface is used to calculate the shifts to vibration-rotation energy levels…

Chemical Physics · Physics 2014-06-27 Lorenzo Lodi , Oleg L. Polyansky , Jonathan Tennyson , Alexander Alijah , Nikolai F. Zobov

Excitations of a relativistic geometry are used to represent the theory of quantum electrodynamics. The connection excitations and the frame excitations reduce, respectively, to the electromagnetic field operator and electron field…

General Physics · Physics 2007-05-23 Gustavo R. Gonzalez-Martin

The physical reasons in favour of a two dimensional topological model of quantum electrodynamics are discussed. It is shown that in accord with this model there is a new uncertainty relation for photon which is compatible with QED.

Mesoscale and Nanoscale Physics · Physics 2007-05-23 F. Ghaboussi

Electromagnetic effects are increasingly being accounted for in lattice quantum chromodynamics computations. Because of their long-range nature, they lead to large finite-size effects over which it is important to gain analytical control.…

High Energy Physics - Lattice · Physics 2016-03-23 Z. Fodor , C. Hoelbling , S. D. Katz , L. Lellouch , A. Portelli , K. K. Szabo , B. C. Toth

We discuss a general approach to a realistic theory of the electronic structure in materials containing correlated d- or f- electrons. The main feature of this approach is the taking into account the energy dependence of the electron…

Strongly Correlated Electrons · Physics 2009-10-30 A. I. Lichtenstein , M. I. Katsnelson

The theory relevant to the study of matter in equilibrium with the radiation field is thermal quantum electrodynamics (TQED). We present a formulation of the theory, suitable for non relativistic fluids, based on a joint functional integral…

Quantum Physics · Physics 2009-11-13 Pascal R. Buenzli , Philippe A. Martin , Marc D. Ryser

The quantum electrodynamics formalism to treat the interelectronic-interaction correction of first order in $1/Z$ to the two-electron part of the nuclear recoil effect on binding energies in atoms and ions is developed. The nonperturbative…

Atomic Physics · Physics 2019-07-24 A. V. Malyshev , I. S. Anisimova , D. V. Mironova , V. M. Shabaev , G. Plunien

QED corrections to the $g$ factor of Li-like and B-like ions in a wide range of nuclear charges are presented. Many-electron contributions as well as radiative effects on the one-loop level are calculated. Contributions resulting from the…

Atomic Physics · Physics 2020-07-15 H. Cakir , V. A. Yerokhin , N. S. Oreshkina , B. Sikora , I. I. Tupitsyn , C. H. Keitel , Z. Harman

The effects of a magnetic field on the energy and on the spin of free electrons are computed in the framework of quantum field theory. In the case of a constant moderate field and with relatively slow electrons, the derived formulae are…

Quantum Physics · Physics 2018-03-14 C. Verzegnassi , R. Germano , P. Kurian

This work provides a relativistic, digital quantum simulation scheme for both $2+1$ and $3+1$ dimensional quantum electrodynamics (QED), based on a discrete spacetime formulation of theory. It takes the form of a quantum circuit, infinitely…

Quantum Physics · Physics 2024-10-30 Nathanaël Eon , Giuseppe Di Molfetta , Giuseppe Magnifico , Pablo Arrighi

This review article deals with some case studies of relativistic and correlation effects in atomic systems. After a brief introduction to relativistic many-electron theory, a number of applications ranging from correlation energy to parity…

Atomic Physics · Physics 2007-05-23 B. P. Das , K. V. P. Latha , Bijaya K. Sahoo , Chiranjib Sur , Rajat K Chaudhuri , D. Mukherjee

Research on strongly correlated electron systems faces a fundamental challenge due to the complex nature of intrinsic many-body correlations. A key strategy to address this challenge lies in advancing experimental methods that can directly…

Strongly Correlated Electrons · Physics 2026-03-31 Yuehua Su , Guoya Zhang , Chao Zhang , Dezhong Cao

In this article, we present a unified reciprocal quantum electrodynamics (QED) formulation of quantum light-matter interaction. For electron-light interactions, we bridge the underlying theories of Photon-Induced Near-field Electron…

Quantum Physics · Physics 2019-04-12 Yiming Pan , Avraham Gover

In this paper we set a framework in which experiments whose goal is to test QED predictions can be used in a more general way to test non-linear electrodynamics (NLED) which contains low-energy QED as a special case. We review some of these…

Optics · Physics 2017-05-31 M Fouché , R Battesti , C Rizzo

This thesis focuses on the experimental creation and detection of a variety of quantum correlations using nuclear magnetic resonance hardware. Quantum entanglement, being most common and counter-intuitive, is one of the main type considered…

Quantum Physics · Physics 2019-05-16 Amandeep Singh

The manipulation of individual charged particles has been deeply explored in physics's theoretical and experimental domains during the past decades. It is the pillar of several existing devices used for metrology and sensing and is a…

Quantum Physics · Physics 2024-10-25 Marko Toroš , Patrick Andriolo , Martine Schut , Sougato Bose , Anupam Mazumdar

Magnetic effects on free electron systems have been studied extensively in the context of spin-to-orbital angular momentum conversion. Starting from the Dirac equation, we derive a fully relativistic expression for the energy of free…

Quantum Physics · Physics 2018-06-19 P. Kurian
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