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Quantum chemistry simulations that accurately predict the properties of materials are among the most highly anticipated applications of quantum computing. It is widely believed that simulations running on quantum computers will allow for…

The ground state properties of quantum many-body systems are a subject of interest across chemistry, materials science, and physics. Thus, algorithms for finding ground states can have broad impacts. Variational quantum algorithms are one…

Quantum Physics · Physics 2023-09-28 James B. Larsen , Matthew D. Grace , Andrew D. Baczewski , Alicia B. Magann

Interesting problems in quantum computation take the form of finding low-energy states of (pseudo)spin systems with engineered Hamiltonians that encode the problem data. Motivated by the practical possibility of producing very…

Quantum Physics · Physics 2022-05-11 Jiajin Feng , Biao Wu , Frank Wilczek

Quantum computing uses the physical principles of very small systems to develop computing platforms which can solve problems that are intractable on conventional supercomputers. There are challenges not only in building the required…

Quantum Physics · Physics 2024-11-19 Dieter Jaksch , Peyman Givi , Andrew J. Daley , Thomas Rung

We compare recently proposed methods to compute the electronic state energies of the water molecule on a quantum computer. The methods include the phase estimation algorithm based on Trotter decomposition, the phase estimation algorithm…

Quantum Physics · Physics 2019-07-24 Teng Bian , Daniel Murphy , Rongxin Xia , Ammar Daskin , Sabre Kais

Models of interacting many-body quantum systems that may realize new exotic phases of matter, notably quantum spin liquids, are challenging to study using even state-of-the-art classical methods such as tensor network simulations. Quantum…

Quantum Physics · Physics 2025-04-16 Aaron Szasz , Ed Younis , Wibe Albert de Jong

An alternative quantum algorithm for the discrete logarithm problem is presented. The algorithm uses two quantum registers and two Fourier transforms whereas Shor's algorithm requires three registers and four Fourier transforms. A crucial…

Quantum Physics · Physics 2007-05-23 Wim van Dam

The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…

Quantum Physics · Physics 2019-07-03 Oscar Higgott , Daochen Wang , Stephen Brierley

Quantum computer versus quantum algorithm processor in CMOS are compared to find (in parallel) all Hamiltonian cycles in a graph with m edges and n vertices, each represented by k bits. A quantum computer uses quantum states analogous to…

Hardware Architecture · Computer Science 2007-05-23 John Robert Burger

We present quantum algorithms for solving two problems regarding stochastic processes. The first algorithm prepares the thermal Gibbs state of a quantum system and runs in time almost linear in $\sqrt{N \beta/{\cal Z}}$ and polynomial in…

Quantum Physics · Physics 2017-01-11 Anirban Narayan Chowdhury , Rolando D. Somma

While most work on the quantum simulation of chemistry has focused on computing energy surfaces, a similarly important application requiring subtly different algorithms is the computation of energy derivatives. Almost all molecular…

Quantum computers have the potential to efficiently simulate large-scale quantum systems for which classical approaches are bound to fail. Even though several existing quantum devices now feature total qubit numbers of more than one…

Quantum Physics · Physics 2023-03-29 Hongye Yu , Yusheng Zhao , Tzu-Chieh Wei

We develop a quantum-classical hybrid algorithm to calculate the analytical second-order derivative of the energy for the orbital-optimized variational quantum eigensolver (OO-VQE), which is a method to calculate eigenenergies of a given…

Chemical Physics · Physics 2023-04-19 Yuya O. Nakagawa , Jiabao Chen , Shotaro Sudo , Yu-ya Ohnishi , Wataru Mizukami

Quantum computing is a winsome field that concerns with the behaviour and nature of energy at the quantum level to improve the efficiency of computations. In recent years, quantum computation is receiving much attention for its capability…

Quantum Physics · Physics 2020-05-26 Amandeep Singh Bhatia , Ajay Kumar

We present a quantum information-inspired ansatz for the variational quantum eigensolver (VQE) and demonstrate its efficacy in calculating ground-state energies of atomic systems. Instead of adopting a heuristic approach, we start with an…

Quantum Physics · Physics 2025-08-19 Abdul Kalam , Prasenjit Deb , Akitada Sakurai , B. K. Sahoo , V. S. Prasannaa , B. P. Das

Modeling low energy eigenstates of fermionic systems can provide insight into chemical reactions and material properties and is one of the most anticipated applications of quantum computing. We present three techniques for reducing the cost…

Quantum fidelity estimation is essential for benchmarking quantum states and processes on noisy quantum devices. While stabilizer operations form the foundation of fault-tolerant quantum computing, non-stabilizer resources further enable…

Quantum Physics · Physics 2025-06-17 Zhiping Liu , Kun Wang , Xin Wang

Efficiently calculating the low-lying eigenvalues of Hamiltonians, written as sums of Pauli operators, is a fundamental challenge in quantum computing. While various methods have been proposed to reduce the complexity of quantum circuits…

Quantum Physics · Physics 2025-08-08 Abhinav Anand , Kenneth R. Brown

Universal fault-tolerant quantum computers will require error-free execution of long sequences of quantum gate operations, which is expected to involve millions of physical qubits. Before the full power of such machines will be available,…

The accurate and efficient energy estimation of quantum Hamiltonians consisting of Pauli observables is an essential task in modern quantum computing. We introduce a Resource-Optimized Grouping Shadow (ROGS) algorithm, which optimally…

Quantum Physics · Physics 2025-04-09 Min Li , Mao Lin , Matthew J. S. Beach