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We consider a question motivated by the third law of thermodynamics: can there be a local temperature arbitrarily close to absolute zero in a nonequilibrium quantum system? We consider nanoscale quantum conductors with the source reservoir…

Mesoscale and Nanoscale Physics · Physics 2016-03-01 Abhay Shastry , Charles A. Stafford

In contrast to the canonical ensemble where thermodynamic functions are smooth for all finite system sizes, the microcanonical entropy can show nonanalytic points also for finite systems, even if the Hamiltonian is smooth. The relation…

Statistical Mechanics · Physics 2007-05-23 Lapo Casetti , Michael Kastner

It is shown that the von Neumann entropy, a measure of quantum entanglement, does have its classical counterpart in thermodynamic systems, which we call partial entropy. Close to the critical temperature the partial entropy shows perfect…

Strongly Correlated Electrons · Physics 2009-11-11 Junpeng Cao , Xiaoling Cui , Zhang Qi , Wengang Lu , Qian Niu , Yupeng Wang

We compute the topological entropy of the toric code models in arbitrary dimension at finite temperature. We find that the critical temperatures for the existence of full quantum (classical) topological entropy correspond to the…

Quantum Physics · Physics 2012-11-27 Dalimil Mazac , Alioscia Hamma

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

Quantum Physics · Physics 2010-07-22 Barbara Fresch , Giorgio J. Moro

We present an exact microcanonical formulation, in the thermodynamic limit, for a system of $N$ noninteracting particles with $p$ equally spaced energy levels $\{0,\epsilon,2\epsilon,\ldots,(p-1)\epsilon\}$. Writing the microcanonical…

Statistical Mechanics · Physics 2026-05-05 J. Ricardo de Sousa

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this…

Quantum Physics · Physics 2025-12-02 J. M. Z. Choquehuanca

We study the energy and entropies for $N$ independent harmonic oscillators in the microcanonical and the canonical ensembles in the Tsallis classical and the Tsallis quantum statistics of entropic parameter $q$, where $N$ is the number of…

Statistical Mechanics · Physics 2023-02-01 Masamichi Ishihara

We consider the concept of temperature in a setting beyond the standard thermodynamics prescriptions. Namely, rather than restricting to standard coarse-grained measurements, we consider observers able to master any possible quantum…

Quantum Physics · Physics 2012-04-19 Alessandro Ferraro , Artur Garcia-Saez , Antonio Acin

Microcanonical thermodynamics (MCTh) is contrasted to canonical thermodynamics (CTh). At phase transitions of 1.order the two ensembles are NOT equivalent even in the thermodynamic limit . Energy fluctuations do not vanish and phase…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

A pure quantum state can fully describe thermal equilibrium as long as one focuses on local observables. Thermodynamic entropy can also be recovered as the entanglement entropy of small subsystems. When the size of the subsystem increases,…

Statistical Mechanics · Physics 2018-05-31 Yuya O. Nakagawa , Masataka Watanabe , Hiroyuki Fujita , Sho Sugiura

We propose a method to calculate finite-temperature properties of a quantum many-body system for a microcanonical ensemble by introducing a pure quantum state named here an energy-filtered random-phase state, which is also a potentially…

Quantum Physics · Physics 2022-10-06 Kazuhiro Seki , Seiji Yunoki

In this work we will show that there exists a fundamental difference between microscopic quantum thermodynamics and macroscopic classical thermodynamics. It will be proved that the entropy production in quantum thermodynamics always…

Quantum Physics · Physics 2020-02-26 B. Ahmadi , S. Salimi , A. S. Khorashad

We consider a regular chain of elementary quantum systems with nearest neighbor interactions and assume that the total system is in a canonical state with temperature $T$. We analyze under what condition the state factors into a product of…

Statistical Mechanics · Physics 2015-06-25 Michael Hartmann , Guenter Mahler , Ortwin Hess

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

The thermodynamics for a system with given temperature, density, and volume is described by the Canonical ensemble. The thermodynamics for a corresponding system with the same temperature, volume, and average density is described by the…

Statistical Mechanics · Physics 2016-01-12 Debajit Chakraborty , James Dufty , Valentin V. Karasiev

The role of quantum entanglement in thermodynamical systems remains elusive. Does entanglement result in thermodynamic advantages or does it impose fundamental limitations? Here, we unambiguously quantify the amount of heat and work in a…

Quantum Physics · Physics 2026-03-23 Joan Alba , Laura Ares , Jan Sperling , Julien Pinske

Thermal properties of nanomaterials are crucial to not only improving our fundamental understanding of condensed matter systems, but also to developing novel materials for applications spanning research and industry. Since quantum effects…

Quantum Physics · Physics 2022-08-26 Connor Powers , Lindsay Bassman Oftelie , Daan Camps , Wibe A. de Jong

We study the time evolution of eleven microscopic entropy definitions (of Boltzmann-surface, Gibbs-volume, canonical, coarse-grained-observational, entanglement and diagonal type) and three microscopic temperature definitions (based on…

Statistical Mechanics · Physics 2024-11-27 Philipp Strasberg , Joseph Schindler