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The diffusivity of hydrogen in cold-rolled pure iron is investigated using permeation and desorption methods. Electrochemical charging, electro-permeation and thermal desorption spectroscopy (TDS) experiments are conducted. Firstly, the…

Materials Science · Physics 2021-12-02 A. Zafra , Z. Harris , C. Sun , E. Martínez-Pañeda

The presence of hydrogen traps within a metallic alloy influences the rate of hydrogen diffusion. The electro-permeation (EP) test can be used to assess this: the permeation of hydrogen through a thin metallic sheet is measured by suitable…

Chemical Physics · Physics 2023-07-12 A. Raina , V. S. Deshpande , E. Martínez-Pañeda , N. A. Fleck

The electrochemical permeation test is one of the most used methods for characterising hydrogen diffusion in metals. The flux of hydrogen atoms registered in the oxidation cell might be fitted to obtain apparent diffusivities. The magnitude…

Materials Science · Physics 2019-12-06 A. Díaz , I. I. Cuesta , E. Martínez-Pañeda , J. M. Alegre

This paper describes the impedance spectroscopy adapted for analysis of small electrochemical changes in fluids. To increase accuracy of measurements the differential approach with temperature stabilization of fluid samples and electronics…

Instrumentation and Detectors · Physics 2016-07-26 S. Kernbach , I. Kuksin , O. Kernbach

Hydrogen diffusion and trapping in ferritic steels containing (Ti,Cr)C particles was investigated using electrochemical permeation (EP) and thermal desorption spectroscopy (TDS). The trapping parameters for the test materials were evaluated…

Materials Science · Physics 2025-07-22 Nicholas Winzer

This tutorial review focuses on the basic theoretical backgrounds, their working principles, and implementation of impedance spectroscopy in both electroceramics and electrochemical research and technological applications. Various…

Applied Physics · Physics 2024-06-26 Subrata Karmakar

Electron microscopy prevalently uses energy-dispersive x-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS) for elemental analysis. EDS and EELS energy resolutions are commonly between 30-100 eV or 0.01-1 eV, respectively.…

There is a need for numerical models capable of predicting local accumulation of hydrogen near stress concentrators and crack tips to prevent and mitigate hydrogen assisted fracture in steels. The experimental characterisation of trapping…

Applied Physics · Physics 2020-10-27 A. Díaz , A. Zafra , E. Martínez-Pañeda , J. M. Alegre , J. Belzunce , I. I. Cuesta

Photoelectrochemical impedance spectroscopy (PEIS) is a useful tool for the characterization of photoelectrodes for solar water splitting. However, the analysis of PEIS spectra often involves a priori assumptions that might bias the…

Chemical Physics · Physics 2020-12-10 Dino Klotz , Daniel A. Grave , Hen Dotan , Avner Rothschild

We have introduced a new method of estimating the electron temperature and density of H II regions by using single dish observations. In this method, multiple hydrogen radio recombination lines of different bands are computed under the…

Solar and Stellar Astrophysics · Physics 2019-11-14 F. -Y. Zhu , Q. -F. Zhu , J. -Z. Wang , J. -S Zhang

We explore the strengths and limitations of using a standard Michelson interferometer to sample line-of-sight-averaged temperature in water via two experimental setups: slow-varying temperature in static fluid and fast temperature…

Fluid Dynamics · Physics 2023-11-01 Xinyang Ge , Joanna A. Zielińska , Sergio Maldonado

We present a detailed study of the absolute Doppler-broadened absorption of a probe beam scanned across the potassium D lines in a thermal vapour. Spectra using a weak probe were measured on the 4S $\rightarrow$ 4P transition and compared…

Atomic Physics · Physics 2015-10-05 Ryan K. Hanley , Philip D. Gregory , Ifan G. Hughes , Simon L. Cornish

A technique to measure the band gap of dielectric materials with high refractive index by means of energy electron loss spectroscopy (EELS) is presented. The technique relies on the use of a circular (Bessel) aperture and suppresses…

Using transient grating spectroscopy (TGS) we measure the thermal diffusivity of tungsten exposed to different levels of 20 MeV self-ion irradiation. Damage as low as 3.2 x 10^-4 displacements per atom (dpa) causes a measurable reduction in…

Materials Science · Physics 2020-02-05 Abdallah Reza , Hongbing Yu , Kenichiro Mizohata , Felix Hofmann

Dissipation and decoherence of quantum systems in thermal environments is important to various spectroscopies. It is generally believed that dissipation can broaden the line shape of spectroscopies, and thus stronger system-bath interaction…

Quantum Physics · Physics 2024-05-07 Ru-Qiong Deng , Cheng-Ge Liu , Yi-Xuan Yao , Jing-Yi-Ran Jin , Hao-Yue Zhang , Yin Song , Qing Ai

Dicke narrowing is a phenomena that dramatically reduces the Doppler width of spectral lines, due to frequent velocity-changing collisions. A similar phenomena occurs for electromagnetically induced transparency (EIT) resonances, and…

Quantum Physics · Physics 2007-08-18 M. Shuker , O. Firstenberg , R. Pugatch , A. Ben-Kish , A. Ron , N. Davidson

Using electrochemical impedance spectroscopy, we have devised a method of sensing the microscopic surface conditions on the surface of niobium as it is undergoing an electrochemical polishing (EP) treatment. The method uses electrochemical…

Materials Science · Physics 2025-01-16 Eric Viklund , Vijay Chouhan , Davida Smith , Tim Ring , David N. Seidman , Sam Posen

We have used a photothermal technique, in which chopped light heats the front surface of a small ( ~ 1 mm2) sample and the chopping frequency dependence of thermal radiation from the back surface is measured with a liquid nitrogen cooled…

Materials Science · Physics 2016-01-20 J. W. Brill , Maryam Shahi , Marcia M. Payne , Jesper Edberg , Y. Yao , Xavier Crispin , J. E. Anthony

Modification of surfaces to enable dropwise condensation is a promising approach for achieving high condensation rates. In this work, we present an experimental study on condensation of water on copper surfaces coated with an ultrathin, 5…

Electrochemical Impedance Spectroscopy (EIS) is a crucial technique for assessing corrosion of a metallic materials. The analysis of EIS hinges on the selection of an appropriate equivalent circuit model (ECM) that accurately characterizes…

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