Related papers: Probing computational methodologies in predicting …
The PAH model predicts many weak emission features in the 1-5 $\mu$m region that can resolve significant questions that it has faced since its inception in the mid-80s. These features contain fundamental information about the PAH population…
Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules that are ubiquitous in a variety of astrophysical objects and environments. In this work, we use JWST/MIRI MRS spectroscopy of three Seyferts to compare their nuclear PAH…
Emission from polycyclic aromatic hydrocarbons (PAHs) is a promising tool for estimating star formation rate (SFR) in galaxies, but the origin of its sources of excitation, which include not only young but possibly also old stars, remains…
Infrared (IR) emission spectra are calculated for dust composed of mixtures of amorphous silicate and graphitic grains, including varying amounts of polycyclic aromatic hydrocarbon (PAH) particles. The models are constrained to reproduce…
We present $Spitzer$/IRS mid-infrared spectral maps of the Galactic star-forming region M17 as well as IRSF/SIRIUS Br$\gamma$ and Nobeyama 45-m/FOREST $^{13}$CO ($J$=1--0) maps. The spectra show prominent features due to polycyclic aromatic…
Planet-forming disks of gas and dust around young stars contain polycyclic aromatic hydrocarbons (PAHs). We aim to characterize how the charge state of PAHs can be used as a probe of flows of gas through protoplanetary gaps. In this…
Pair atomic density fitting (PADF) is a promising strategy to reduce the scaling with system size of quantum chemical methods for the calculation of the correlation energy like the direct random phase approximation (RPA) or second-order…
Polycyclic Aromatic Hydrocarbons (PAHs) constitute a significant fraction of the Universe's carbon budget, playing a key role in the cosmic carbon cycle and dominating the mid-infrared spectra of astrophysical environments in which they…
We use the long-slit spectroscopy mode of the VISIR-NEAR experiment to perform diffraction-limited observations of eight nearby Herbig Ae protoplanetary disks. We extract spectra for various locations along the slit with a spectral…
Polycyclic aromatic hydrocarbon (PAH) emission is widely used to trace the distribution of molecular gas in the interstellar medium, exhibiting a tight correlation with CO(2-1) emission across nearby galaxies. Using PHANGS-JWST and…
A gas-phase optical spectrum of a large polycyclic aromatic hydrocarbon (PAH) cation - C78H26 +- in the 410-610 nm range is presented. This large all-benzenoid PAH should be large enough to be stable with respect to photodissociation in the…
We study the effect of anisotropic radiation illumination on the alignment of polycyclic aromatic hydrocarbons (PAHs) and report that cross-sectional mechanism of alignment earlier considered in terms of gas-grain interactions can also be…
In a series of two recent papers, the frequency and size distribution dependence of extinction spectra for astronomical silicate and graphite grains was analyzed by us in the context of MRN type interstellar dust models. These grains were…
We investigate the emission properties of polycyclic aromatic hydrocarbons (PAHs) in various metallicity environments with the Infrared Spectrograph on board Spitzer. Local giant HII regions are used as references as they enable access to…
For star-forming galaxies, we investigate a global relation between polycyclic aromatic hydrocarbon (PAH) emission luminosity at 3.3 um, L_PAH3.3, and infrared (8-1000 um) luminosity, L_IR, to understand how the PAH 3.3 um feature relates…
Two ultracompact H II regions (IRAS 19181+1349 and 20178+4046) and one compact molecular clump (20286+4105) have been observed at far infrared wavelengths using the TIFR 1 m balloon-borne telescope and at mid infrared wavelengths using ISO.…
We investigate the presence of silicon atoms adsorbed on the surface of interstellar polycyclic aromatic hydrocarbons (PAHs) to form SiPAH pi-complexes. We use quantum chemistry calculations to obtain structural, thermodynamic and mid-IR…
The chemistry of astronomical hydrocarbons, responsible for the well-known infrared emission features detected in a wide variety of targets, remains enigmatic. Here we focus on the group of young intermediate-mass Herbig Ae stars. We have…
We present adaptive optics high angular resolution ($\sim0.1\arcsec$) spectroscopic observations in the 3 \um region of eight well known Herbig Ae/Be stars with circumstellar disks. We detect the aromatic emission feature at 3.3 \um for…
Dust grains absorb half of the radiation emitted by stars throughout the history of the universe, re-emitting this energy at infrared wavelengths. Polycyclic aromatic hydrocarbons (PAHs) are large organic molecules that trace…