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Mid-infrared (IR) observations of polycyclic aromatic hydrocarbons (PAHs) and molecular hydrogen emission are a potentially powerful tool to derive physical properties of dense environments irradiated by intense UV fields. We present new,…

Astrophysics of Galaxies · Physics 2014-11-20 O. Berne , A. Fuente , J. R. Goicoechea , P. Pilleri , M. Gonzalez-Garcia , C. Joblin

In this paper, we explore the detectability of polycyclic aromatic hydrocarbons (PAHs) under diverse planetary conditions, aiming to identify promising targets for future observations of planetary atmospheres. Our primary goal is to…

Earth and Planetary Astrophysics · Physics 2024-11-13 Rosa Arenales-Lope , Karan Molaverdikhani , Dwaipayan Dubey , Barbara Ercolano , Fabian Grübel , Christian Rab

The interstellar medium (ISM) consists of a diversity of structures across a range of spatial scales, intimately tied to galactic evolution. In this work, Fourier analysis is used to characterize the spatial structures of dust and…

Astrophysics of Galaxies · Physics 2025-04-04 Charlie Lind-Thomsen , Albert Sneppen , Charles L. Steinhardt

A novel theoretical method is developed to study the polycyclic aromatic hydrocarbon - diffuse interstellar band (PAH-DIB) hypothesis. In this method, a computer program is used to enumerate all PAH molecules with up to a specific number of…

Astrophysics · Physics 2007-05-23 Xiaofeng Tan

Quantifying the effect of anharmonicity on the infrared spectrum of large molecules such as polycyclic aromatic hydrocarbons (PAHs) at high temperature is the focus of a number of theoretical and experimental studies, many of them motivated…

Chemical Physics · Physics 2019-06-19 Shubhadip Chakraborty , Giacomo Mulas , Karine Demyk , Christine Joblin

Clusters of polycyclic aromatic hydrocarbon (PAH) molecules are modelled using explicit all-atom potentials using a rigid body approximation. The PAH's considered range from pyrene (C10H8) to circumcoronene (C54H18), and clusters containing…

Chemical Physics · Physics 2016-09-28 M. Rapacioli , F. Calvo , F. Spiegelman , C. Joblin , D. J. Wales

We explore the relationships between the Polycyclic Aromatic Hydrocarbon (PAH) feature strengths, mid-infrared continuum luminosities, far-infrared spectral slopes, optical spectroscopic classifications, and silicate optical depths within a…

A reliable and compact chemical mechanism of gas-phase methane pyrolysis leading to formation of large polycyclic aromatic hydrocarbon (PAH) molecules has been developed. This model is designed for studies of carbon nanostructure synthesis…

Chemical Physics · Physics 2023-11-03 Alexander Khrabry , Igor D. Kaganovich , Yuri Barsukov , Sumathy Raman , Emre Turkoz , David Graves

Nuclear Magnetic Resonance (NMR) is one of the most powerful experimental techniques to characterize the structure of molecules and confined liquids. Nevertheless, the complexity of the systems under investigation usually requires…

We examine the UV reprocessing efficiencies of warm dust and polycyclic aromatic hydrocarbons (PAHs) through an analysis of the mid- and far-infrared surface luminosity densities of 85 nearby H$\alpha$-selected star-forming galaxies…

Astrophysics of Galaxies · Physics 2015-06-22 Jason E. Young , Caryl Gronwall , John J. Salzer , Jessica L. Rosenberg

Virtually all detailed gas-phase models of the chemistry of dense interstellar clouds exclude polycyclic aromatic hydrocarbons (PAH's). This omission is unfortunate because from the few studies that have been done on the subject, it is…

Astrophysics · Physics 2009-11-13 Valentine Wakelam , Eric Herbst

As a part of interstellar dust, polycyclic aromatic hydrocarbons (PAHs) are processed by the interaction with vacuum ultraviolet (VUV) photons that are emitted by hot young stars. This interaction leads to the emission of the well-known…

Interstellar polycyclic aromatic hydrocarbon (PAHs) are an important component of the interstellar medium of galaxies, containing some 10 percent of the elemental carbon. Their vibrational emission dominates the mid-infrared spectra of…

Astrophysics of Galaxies · Physics 2026-03-06 A. G. G. M. Tielens

We report new properties of the 11 and 12.7 {\mu}m emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution \textit{Spitzer} Space Telescope data, we study in…

Astrophysics of Galaxies · Physics 2016-06-29 M. J. Shannon , D. J. Stock , E. Peeters

We propose to evaluate the contribution of polycyclic aromatic hydrocarbon molecules that carry side groups to the mid-infrared emission spectra. Within this framework, the IR absorption spectra of 2- and 9-vinylanthracene were measured in…

Solar and Stellar Astrophysics · Physics 2015-06-05 Anju Maurya , Shantanu Rastogi , G. Rouillé , Friedrich Huisken , Thomas Henning

We explore the relationships between the 3.3 {\mu}m polycyclic aromatic hydrocarbon (PAH) feature and active galactic nucleus (AGN) properties of a sample of 54 hard X-ray selected bright AGNs, including both Seyfert 1 and Seyfert 2 type…

Astrophysics of Galaxies · Physics 2015-06-22 Angel Castro , T. Miyaji , M. Shirahata , K. Ichikawa , S. Oyabu , D. Clark , M. Imanishi , T. Nakagawa , Y. Ueda

Polycyclic aromatic hydrocarbons (PAHs) are a ubiquitous component of the interstellar medium (ISM) in z~0 massive, star-forming galaxies and play key roles in ISM energy balance, chemistry, and shielding. Wide field of view, high…

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in astrophysical environments, as revealed by their pronounced emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 $\mu$m commonly ascribed to the C--H and C--C vibrational modes.…

Astrophysics of Galaxies · Physics 2017-07-19 Han Zhang , Charles M. Telesco , Thiem Hoang , Aigen Li , Eric Pantin , Christopher M. Wright , Dan Li , Peter Barnes

Recognized as important interstellar constituents, polycyclic aromatic hydrocarbons (PAHs) have been intensively studied in astrochemistry and their spectroscopy, thermodynamics, dynamics, and fragmentations are now amply documented. There…

Chemical Physics · Physics 2017-06-13 Georges Trinquier , Aude Simon , Mathias Rapacioli , Florent Xavier Gadéa

One of the major challenges to identification of the 3.3, 6.2, 7.7, 8.6, and 11.3um interstellar IR emission bands with polycyclic aromatic hydrocarbon (PAH) molecules has been the recent detection of these bands in regions with little UV…

Astrophysics · Physics 2009-11-07 Aigen Li , B. T. Draine
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