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Thermal operations are a generic description for allowed state transitions under thermodynamic restrictions. However, the quest for simpler methods to encompass all these processes remains unfulfilled. We resolve this challenge through the…

Quantum Physics · Physics 2024-10-16 Jeongrak Son , Nelly H. Y. Ng

What are the fundamental limits and advantages of using a catalyst to aid thermodynamic transformations between quantum systems? In this work, we answer this question by focusing on transformations between energy-incoherent states under the…

Quantum Physics · Physics 2024-08-28 Jakub Czartowski , A. de Oliveira Junior

The laws of thermodynamics are usually formulated under the assumption of infinitely large environments. While this idealization facilitates theoretical treatments, real physical systems are always finite and their interaction range is…

Quantum Physics · Physics 2021-09-22 Ivan Henao , Raam Uzdin

Quantum thermodynamics is a research field that aims at fleshing out the ultimate limits of thermodynamic processes in the deep quantum regime. A complete picture of quantum thermodynamics allows for catalysts, i.e., systems facilitating…

Quantum Physics · Physics 2015-09-02 Nelly Huei Ying Ng , Laura Mančinska , Cristina Cirstoiu , Jens Eisert , Stephanie Wehner

We examine the problem of state transformations in the framework of Gaussian thermal resource theory in the presence of catalysts. To this end, we introduce an expedient parametrisation of covariance matrices in terms of principal mode…

Quantum Physics · Physics 2022-08-10 Benjamin Yadin , Hyejung H. Jee , Carlo Sparaciari , Gerardo Adesso , Alessio Serafini

So-called Thermal Operations seem to describe the most fundamental, and reasonable, set of operations allowable for state transformations at an ambient inverse temperature $\beta$. However, a priori, they require experimentalists to…

Understanding the fundamental limits of state convertibility is crucial for establishing the boundaries of quantum information processing and thermodynamic efficiency. While auxiliary systems, catalysts, can facilitate otherwise impossible…

Quantum Physics · Physics 2026-03-06 Jingsong Ao , Aby Philip , Alexander Streltsov

Catalysis, the acceleration of product formation by a substance that is left unchanged, typically results from multiple elementary processes, including diffusion of the reactants toward the catalyst, chemical steps, and release of the…

Chemical Physics · Physics 2023-12-27 Yann Sakref , Maitane Muñoz-Basagoiti , Zorana Zeravcic , Olivier Rivoire

In this thesis, I investigate various aspects of one of the most fundamental questions in thermodynamics: what state transformations can quantum systems undergo while interacting with a thermal bath under specific constraints? These…

Quantum Physics · Physics 2024-04-02 A de Oliveira Junior

The class of possible thermodynamic conversions can be extended by introducing an auxiliary system called catalyst, which assists state conversion while remaining its own state unchanged. We reveal a complete characterization of catalytic…

Quantum Physics · Physics 2022-09-13 Naoto Shiraishi , Takahiro Sagawa

In quantum information and computation, a central challenge is to determine which quantum states can be transformed into one another under restricted sets of free operations. While many transformations are impossible directly, catalytic…

Quantum Physics · Physics 2025-10-02 Máté Weisz , Sergii Strelchuk

Elementary thermal operations are thermal operations that act non-trivially on at most two energy levels of a system at the same time. They were recently introduced in order to bring thermal operations closer to experimental feasibility. A…

Quantum Physics · Physics 2025-08-01 Pedro Hack , Christian B. Mendl

Thermodynamics plays an important role both in the foundations of physics and in technological applications. An operational perspective adopted in recent years is to formulate it as a quantum resource theory. At the core of this theory is…

Quantum Physics · Physics 2023-12-13 Thomas Theurer , Elia Zanoni , Carlo Maria Scandolo , Gilad Gour

Thermal operations are quantum channels that have taken a prominent role in deriving fundamental thermodynamic limitations in quantum systems. We show that these channels are uniquely characterized by a purely quantum information theoretic…

Quantum Physics · Physics 2025-07-23 Seok Hyung Lie , Jeongrak Son , Paul Boes , Nelly H. Y. Ng , Henrik Wilming

The generalized second laws of quantum thermodynamics are usually formulated in terms of R\'enyi divergences and the associated family of generalized free energies. In catalytic thermal transformations, this framework typically certifies…

Quantum Physics · Physics 2026-04-24 Ali Can Günhan , Onur Pusuluk , Thomas Oikonomou , G. Baris Bagci

Catalysis lies at the heart of chemical reactivity, yet its foundational principles remain fragmented across the distinct domains of homogeneous, heterogeneous, and enzymatic systems Here, we propose a unifying theoretical model that…

Chemical Physics · Physics 2025-05-05 Frank Nelson Crespilho

The extension of thermodynamic principles to active matter remains a challenge due to the non-equilibrium nature inherent to active systems. In this study, we introduce a framework to assess entropy in our minimal macroscopic experiment…

Soft Condensed Matter · Physics 2024-09-26 Francesco Romanò , Michael Riedl

Catalysis refers to the possibility of enabling otherwise inaccessible quantum state transitions by supplying an auxiliary system, provided that the auxiliary is returned to its initial state at the end of the protocol. We show that…

Recent work using tools from quantum information theory has shown that at the nanoscale where quantum effects become prevalent, there is not one thermodynamical second law but many. Derivations of these laws assume that an experimenter has…

Quantum Physics · Physics 2018-12-19 Chris Perry , Piotr Ćwikliński , Janet Anders , Michał Horodecki , Jonathan Oppenheim

We consider locally thermal states (for two qubits) with certain amount of quantum entanglement present between them. Unlike previous protocols we show how work can be extracted by performing local unitary operations on this state by…

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