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A classical spin model derived ab initio for rare-earth-based permanent magnet compounds is presented. Our target compound, NdFe$_{12}$N, is a material that goes beyond today's champion magnet compound Nd$_{2}$Fe$_{14}$B in its intrinsic…

Materials Science · Physics 2016-09-26 Munehisa Matsumoto , Hisazumi Akai , Yosuke Harashima , Shotaro Doi , Takashi Miyake

Results of crystallographic refinement, the relationship between electron counts and structural stability, and magnetic characterization of YT$_x$Ge$_2$ (T= Cr, Mn, Fe, Co, and Ni) prepared using the arc melting method are presented. These…

Materials Science · Physics 2017-12-25 Lea Gustin , Lingyi Xing , Max T. Pan , Rongying Jin , Weiwei Xie

Magnetism in SmPd2Al3 was investigated on a single crystal by magnetometry and neutron diffraction. SmPd2Al3 represents a distinctive example of the Sm magnetism exhibiting complex magnetic behavior at low temperatures with four consecutive…

The effect of Ge substitution on the magnetic, magnetocaloric and transport properties of Ni45Co5Mn38Sb12-xGex (x=0-3) has been investigated. The decrease in the exchange interaction brought by Ge substitution can be seen from the reduction…

Strongly Correlated Electrons · Physics 2015-06-11 Roshnee Sahoo , Ajaya K. Nayak , K. G. Suresh , A. K. Nigam

In order to tune the magnetic properties of the cleavable high-Curie temperature ferromagnet Fe$_{5-x}$GeTe$_2$, the effect of increasing the electron count through arsenic substitution has been investigated. Small additions of arsenic (2.5…

Materials Science · Physics 2021-11-15 Andrew F. May , Jiaqiang Yan , Raphael Hermann , Mao-Hua Du , Michael A. McGuire

Heusler alloy Fe2CrAl exhibits a ferromagnetic behaviour below Curie temperature (TC) ~ 202 K along with presence of cluster glass (CG) phase near freezing temperature (Tf) ~ 3.9 K and Griffiths phase (GP) above 300 K. The physical…

Materials Science · Physics 2021-10-22 Kavita Yadav , K. Mukherjee

We provide experimental and theoretical evidence for a novel type of pressure-induced insulator-metal transition characterized by site-selective delocalization of the electrons. M\"ossbauer spectroscopy, X-ray diffraction and electrical…

Strongly Correlated Electrons · Physics 2018-09-19 E. Greenberg , I. Leonov , S. Layek , Z. Konopkova , M. P. Pasternak , L. Dubrovinsky , R. Jeanloz , I. A. Abrikosov , G. Kh. Rozenberg

A detailed study on the crystal structure and bulk magnetic properties of Cr substituted Ising type lanthanide gallium garnets $Ln_3\text{CrGa}_4\text{O}_{12}$ ($Ln$ = Tb, Dy, Ho) has been carried out using room temperature powder X-Ray and…

Materials Science · Physics 2017-09-05 Paromita Mukherjee , Siân E. Dutton

We report a comprehensive study of the temperature-dependent structural, magnetic, vibrational, and dielectric properties of Al-substituted M-type hexaferrites SrFe$_{12-x}$Al$_x$O$_{19}$. Neutron powder diffraction and M\"ossbauer…

The rotating magnetocaloric effect (RMCE) induced by self-demagnetization has been investigated in the giant magnetocaloric effect (GMCE) material Gd$_5$Si$_2$Ge$_2$. This shape-dependent effect had thus far only been reported in pure Gd,…

Disorder induced by chemical inhomogeneity and Jahn-Teller (JT) distortions is often observed in mixed valence perovskite manganites. The main reasons for the evolution of this disorder are connected with the cationic size differences and…

Materials Science · Physics 2021-11-30 Sagar Ghorai , Sergey A. Ivanov , Ridha Skini , Petter Ström , Peter Svedlindh

The temperature dependence of the local structure of V_2O_3 in the vicinity of the metal to insulator transition (MIT) has been investigated using hard X-ray absorption spectroscopy. It is shown that the vanadium pair distance along the…

Strongly Correlated Electrons · Physics 2009-11-11 P. Pfalzer , G. Obermeier , M. Klemm , S. Horn , M. L. denBoer

We study the electronic and magnetic properties of monolayer Fe$_3$GeTe$_2$ within the DFT+DMFT approach in the paramagnetic phase. We argue that this compound is sufficiently far from the local magnetic moment limit, demonstrating…

Strongly Correlated Electrons · Physics 2026-03-13 A. A. Katanin , A. N. Rudenko , D. I. Badrtdinov , M. I. Katsnelson

Polycrystalline samples of the RE$_{5}$Rh$_2$In$_4$ (RE = Gd--Tm) intermetallics have been investigated by means of X-ray diffraction (XRD) as well as by DC and AC magnetometric measurements. The XRD data confirm that the compounds…

Materials Science · Physics 2025-05-22 Altifani Rizky Hayyu , Stanisław Baran , Aleksandra Deptuch , Andrzej Szytuła

The inverse magnetocaloric effect taking place at the antiferro-to-ferromagnetic transition of (Co,Fe)MnP phosphides has been characterized by magnetic and direct {\Delta}Tad measurements. In Co0.53Fe0.47MnP, entropy change of 1.5 Jkg-1K-1…

Materials Science · Physics 2015-06-17 F. Guillou , E. Brueck

The p-electrons of carbon in the interstitial compound Fe3C hybridize with the Fe d-band and enhance the valence electron concentration of Fe from 8 to 8.67. At this concentration, substitutional 3d transition metals and alloys exhibit…

Materials Science · Physics 2007-05-23 E. Duman , M. Acet , E. F. Wassermann , J. P. Itie , F. Baudelet , O. Mathon , S. Pascarelli

In this paper we report the existence of a giant magnetocaloric effect (MCE) in a intermetallic compound non-containing rare-earth. This effect is associated with the concomitant occurrence of a structural and a magnetic transition. The…

Materials Science · Physics 2009-11-07 L. Pareti , M. Solzi , F. Albertini , A. Paoluzi

The effect of Si and Ga substitutions on the magnetic and the magnetocaloric properties in Heusler based system Ni46Co4Mn38Sb12-xZx (Z=Si and Ga) has been studied. From the M(T) plots it is found that Si substitution stabilizes the…

Strongly Correlated Electrons · Physics 2015-05-20 Roshnee Sahoo , Ajaya K. Nayak , K. G. Suresh , A. K. Nigam

A series of in-plane substituted compounds, including Cu-site (SrZn$_x$Cu$_{2-x}$(BO$_3$)$_2$), and B-site (SrCu$_2$(Si$_x$B$_{1-x}$O$_3$)$_2$) substitution, were synthesized by solid state reaction. X-ray diffraction measurements reveal…

Strongly Correlated Electrons · Physics 2009-11-11 G. T. Liu , J. L. Luo , Y. Q. Guo , S. K. Su , P. Zheng , N. L. Wang , D. Jin , T. Xiang

The magnetic and magnetocaloric properties of Ga1-xCMn3+x have been investigated. Reversible magnetocaloric effect (MCE) occurs near the Curie temperature TC. The magnetic entropy change decreases with increasing x, though TC and…

Strongly Correlated Electrons · Physics 2009-05-18 B. S. Wang , P. Tong , Y. P. Sun , X. B. Zhu , X. Luo , G. Li , W. H. Song , Z. R. Yang , J. M. Dai
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