Related papers: Ergodicity in glass relaxation
We present a study of orientational relaxation dynamics in thin films of a low-molecular-weight glass-former as a function of temperature and film thickness. The relaxation is probed by second-harmonic generation after release of a poling…
Metallic glasses exhibit fast mechanical relaxations at temperatures well below the glass transition, one of which shows little variation with temperature known as nearly constant loss (NCL). Despite the important implications of this…
Relaxation processes significantly influence the properties of glass materials. However, understanding their specific origins is difficult, even more challenging is to forecast them theoretically. In this study, using microseconds molecular…
We describe a model for the thermodynamics and dynamics of glass-forming liquids in terms of excitations from an ideal glass state to a Gaussian manifold of configurationally excited states. The quantitative fit of this three parameter…
The Kovacs or crossover effect is one of the peculiar behaviours exhibited by glasses and other complex, slowly relaxing systems. Roughly it consists in the non-monotonic relaxation to its equilibrium value of a macroscopic property of a…
Within the shoving model of the glass transition, the relaxation time and the viscosity are related to the local cage rigidity. This approach can be extended down to the atomic-level in terms of the interatomic interaction, or potential of…
We consider experimental data on the dynamics of water (1) in glass-forming aqueous mixtures with glass transition temperature Tg approaching the putative Tg=136 K of water from above and below, (2) in confined spaces of nanometer in size…
The glass transition temperature and its connection to statistical properties of confined and free-standing polymer films of varying thickness containing unentangled to highly entangled bead-spring chains are studied by molecular dynamics…
We have recently applied the second law to an isolated system, consisting of a system {\Sigma} such as a glass surrounded by an extremely large medium {\Sigma}, to show that the instantaneous temperature T(t), thermodynamic entropy S(T_0,t)…
Three different vortex glass models are studied by examining the energy barrier against vortex motion across the system. In the two-dimensional gauge glass this energy barrier is found to increase logarithmically with system size which is…
A picture for thermodynamics of the glassy state is introduced. It assumes that one extra parameter, the effective temperature, is needed to describe the glassy state. This explains the classical paradoxes concerning the Ehrenfest relations…
The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…
Using mean-field approximations, this paper identifies a phase transition in a three-dimensional Electron Glass lattice model. The density of states of the eigenvalue distribution of the inverse susceptibility matrix is used to identify the…
A model of spinless interacting electrons in presence of randomness is examined using an extended dynamical mean-field formulation. When the interaction strength is large as compared to the Fermi energy, a low temperature glassy phase is…
The origin of stretched exponential relaxation in supercooled glass-forming liquids is one of the central questions regarding the anomalous dynamics of these fluids. The dominant explanation for this phenomenon has long been the proposition…
We investigate the heterogeneous dynamics in a model, where chemical gelation and glass transition interplay, focusing on the dynamical susceptibility. Two independent mechanisms give raise to the correlations, which are manifested in the…
We discuss the slow relaxation phenomenon in glassy systems by means of replicas by constructing a static field theory approach to the problem. At the mean field level we study how criticality in the four point correlation functions arises…
In the context of a classical example of glass-formation in 3-dimensions we exemplify how to construct a statistical mechanical theory of the glass transition. At the heart of the approach is a simple criterion for verifying a proper choice…
Thermodynamic multi-component solution solidification approach to liquid-to-glass transition is proposed and actual mechanisms underlying vitrification, other than viscous slowdown, are identified. Due to polydisperse aggregation in liquid…
We consider the relaxation process and the out-of-equilibrium dynamics of natural generalizations to arbitrary dimensions of the well known one dimensional East process. These facilitated models are supposed to catch some of the main…