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Large scale molecular dynamics simulations for bidisperse nanoparticle suspensions with an explicit solvent are used to investigate the effects of evaporation rates and volume fractions on the nanoparticle distribution during drying. Our…

Soft Condensed Matter · Physics 2018-06-20 Yanfei Tang , Gary S. Grest , Shengfeng Cheng

Large scale molecular dynamics simulations are used to study the dispersion of nanoparticles (NPs) in a polymer film during solvent evaporation. As the solvent evaporates, a dense polymer-rich skin layer forms at the liquid/vapor interface,…

Soft Condensed Matter · Physics 2016-05-23 Shengfeng Cheng , Gary S. Grest

Large-scale molecular dynamics simulations are used to simulate a layer of nanoparticles diffusing on the surface of a liquid. Both a low viscosity liquid, represented by Lennard-Jones monomers, and a high viscosity liquid, represented by…

Soft Condensed Matter · Physics 2013-01-10 Shengfeng Cheng , Gary S. Grest

Large scale molecular dynamics simulations are used to study drying suspensions of a binary mixture of large and small particles in explicit and implicit solvents. The solvent is first modeled explicitly and then mapped to a uniform viscous…

Soft Condensed Matter · Physics 2019-06-12 Yanfei Tang , Gary S. Grest , Shengfeng Cheng

While evaporating solvent is a widely used technique to assemble nano-sized objects into desired superstructures, there has been limited work on how the assembled structures are affected by the physical aspects of the process. We present…

Soft Condensed Matter · Physics 2013-11-20 Shengfeng Cheng , Gary S. Grest

The dynamic behavior of a partially wetting polymer droplet driven over a nanostructured interface is studied using molecular dynamics simulations. We consider the bead-spring model to represent a polymeric liquid that partially wets a…

Soft Condensed Matter · Physics 2020-06-17 Anish Thomas , Nikolai V. Priezjev

We investigated theoretically water evaporation from concentrated supramolecular mixtures, such as solutions of polymers or amphiphilic molecules, using numerical resolutions of a one dimensional model based on mass transport equations.…

Soft Condensed Matter · Physics 2017-10-25 Jean-Baptiste Salmon , Frédéric Doumenc , Béatrice Guerrier

An energy-based liquid-vapor interface detection method is presented using molecular dynamics (MD) simulations of liquid menisci confined between two parallel plates under equilibrium and evaporation/condensation conditions. This method…

Chemical Physics · Physics 2021-09-02 Mustafa Ozsipahi , Yigit Akkus , Chinh Thanh Nguyen , Ali Beskok

In drying liquid films of polymer-colloid mixtures, the stratification in which polymers are placed on top of larger colloids is studied. It is often presumed that the formation of segregated polymer-colloid layers is solely due to the…

Soft Condensed Matter · Physics 2020-03-12 Kyoungmun Lee , Siyoung Q. Choi

In this paper, we present a mathematical model and numerical simulation of the evaporation and drying process of a liquid droplet containing suspended solids. This type of drying is commonly encountered in manufacturing processes such as…

Fluid Dynamics · Physics 2025-11-27 Anurag Bhattacharjee , Aswin Gnanaskandan

A potential strategy for controlling stratification in a drying suspension of bidisperse particles is studied using molecular dynamics simulations. When the suspension is maintained at a constant temperature during fast drying, it can…

Soft Condensed Matter · Physics 2019-03-29 Yanfei Tang , Gary S. Grest , Shengfeng Cheng

We propose and study a one-dimensional model which consists of two cross-diffusion systems coupled via a moving interface. The motivation stems from the modelling of complex diffusion processes in the context of the vapor deposition of thin…

Analysis of PDEs · Mathematics 2024-07-23 Clément Cancès , Jean Cauvin-Vila , Claire Chainais-Hillairet , Virginie Ehrlacher

The vaporization of a freely moving drop in a uniform, high-temperature gas stream is investigated through direct numerical simulation. The incompressible Navier-Stokes equations with surface tension and phase change are solved in…

Fluid Dynamics · Physics 2023-10-03 Bradley Boyd , Sid Becker , Yue Ling

Drainage and evaporation can occur simultaneously during the drying of porous media, but the interactions between these processes and their effects on drying are rarely studied. In this work, we develop a pore network model that considers…

Soft Condensed Matter · Physics 2020-03-23 Haiyi Wu , Chao Fang , Rui Wu , Rui Qiao

We consider the spreading of a thin two-dimensional droplet on a planar substrate as a prototype system to compare the contemporary model for contact line motion based on interface formation of Shikhmurzaev [Int. J. Multiphas. Flow 19, 589…

Fluid Dynamics · Physics 2012-08-17 David N. Sibley , Nikos Savva , Serafim Kalliadasis

Recent advances in nano-rheology require that new methods and models be developed to describe the equilibrium and non-equilibrium properties of entangled polymeric materials and their interfaces at a molecular level of detail. In this work…

Soft Condensed Matter · Physics 2022-11-11 Ludwig Schneider , Juan de Pablo

Particles added to a fluid interface can be used as a surface stabilizer in the food, oil and cosmetic industries. As an alternative to rigid particles, it is promising to consider highly deformable particles that can adapt their…

Soft Condensed Matter · Physics 2016-10-27 Hadi Mehrabian , Jens Harting , Jacco H. Snoeijer

Many multiphase fluid systems, such as those involving immiscible polymers or liquid-liquid systems with surfactants, have shown a breakdown of the no-slip condition at the material interface. This results in systems where the tangential…

Fluid Dynamics · Physics 2023-04-05 Afsoun Rahnama Falavarjani , David Salac

When a film of a liquid suspension of nanoparticles or a polymer solution is deposited on a surface, it may dewet from the surface and as the solvent evaporates the solute particles/polymer can be deposited on the surface in regular line…

Soft Condensed Matter · Physics 2013-03-25 Lubor Frastia , Andrew J. Archer , Uwe Thiele

A colloidal particle placed in an inhomogeneous solution of smaller non-adsorbing polymers will move towards regions of lower polymer concentration, in order to reduce the free energy of the interface between the surface of the particle and…

Soft Condensed Matter · Physics 2017-12-13 Richard P. Sear , Patrick B. Warren
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