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A phase-field formulation is introduced to simulate quantitatively microstructural pattern formation in alloys. The thin-interface limit of this formulation yields a much less stringent restriction on the choice of interface thickness than…

Materials Science · Physics 2016-08-31 Alain Karma

We further develop a recently introduced phase-field model of rapid alloy solidification [Ji et al., PRL 2023]. This model utilizes enhanced solute diffusivity within the spatially diffuse interface region to quantitatively capture solute…

Materials Science · Physics 2025-08-11 Kaihua Ji , Mingwang Zhong , Alain Karma

We present a detailed derivation and thin interface analysis of a phase-field model that can accurately simulate microstructural pattern formation for low-speed directional solidification of a dilute binary alloy. This advance with respect…

Materials Science · Physics 2009-11-10 Blas Echebarria , Roger Folch , Alain Karma , Mathis Plapp

Understanding rapid solidification behavior at velocities relevant to additive manufacturing (AM) is critical to controlling microstructure selection. Although in-situ visualization of solidification dynamics is now possible, systematic…

This study addresses microstructure selection mechanisms in rapid solidification, specifically targeting the transition from cellular/dendritic to planar interface morphologies under conditions relevant to additive manufacturing. We use a…

The effect of nonequilibrium solute trapping by a growing solid under rapid solidification conditions is studied using a phase-field model. Considering a continuous steady-state concentration profile across the diffuse solid-liquid…

Materials Science · Physics 2007-05-23 Denis Danilov , Britta Nestler

Microsegregation-free microstructures can form by solidifying at velocities beyond the absolute stability limit ($V_{\text{abs}}$), where solute partitioning is suppressed by a stable, planar solid-liquid interface. Producing such…

We study initial transient stages in directional solidification by means of a non-variational phase field model with fluctuations. This model applies for the symmetric solidification of dilute binary solutions and does not invoke…

Materials Science · Physics 2016-08-16 R. Benítez , L. Ramírez-Piscina

Planar solidification from an undercooled melt has been considered using the phase-field model. The solute and the phase fields have been found in the limit of small impurity concentration. These solutions in the limit of vanishing velocity…

Materials Science · Physics 2007-05-23 Denis Danilov

In this paper the development of a physically consistent phase-field theory of solidification shrinkage is presented. The coarse-grained hydrodynamic equations are derived directly from the N-body Hamiltonian equations in the framework of…

Materials Science · Physics 2020-02-28 Gyula I. Toth , Wenyue Ma

Directional solidification of water-based solutions has emerged as a versatile technique for templating hierarchical porous materials. However, the underlying mechanisms of pattern formation remain incompletely understood. In this work, we…

Materials Science · Physics 2026-03-20 Kaihua Ji , Alain Karma

A new diffuse interface model has been proposed in this study for simulating binary alloy solidification under universal cooling conditions, involving both equilibrium and non-equilibrium solute partitioning. Starting from the Gibbs-Thomson…

Materials Science · Physics 2023-09-22 Chuanqi Zhu , Yusuke Seguchi , Masayuki Okugawa , Yuichiro Koizumi

We study spacing selection in directional solidification of Al-Cu alloys under transient growth conditions. New experimental results are presented which reveal that dendritic spacing versus solidification rate evolves in an almost step-wise…

Materials Science · Physics 2010-02-09 Morteza Amoorezaei , Sebastian Gurevich , Nikolas Provatas

In the literature, two quite different phase-field formulations for the problem of alloy solidification can be found. In the first, the material in the diffuse interfaces is assumed to be in an intermediate state between solid and liquid,…

Materials Science · Physics 2011-11-23 Mathis Plapp

During the directional solidification of peritectic alloys, two stable solid phases (parent and peritectic) grow competitively into a metastable liquid phase of larger impurity content than either solid phase. When the parent or both solid…

Materials Science · Physics 2009-10-31 Tak Shing Lo , Alain Karma , Mathis Plapp

An asymptotic interface equation for directional solidification near the absolute stabiliy limit is extended by a nonlocal term describing a shear flow parallel to the interface. In the long-wave limit considered, the flow acts…

Condensed Matter · Physics 2009-11-07 Yannick Marietti , Jean-Marc Debierre , Thomas-Michael Bock , Klaus Kassner

In this study, an alloy phase-field model is used to simulate solidification microstructures at different locations within a solidified molten pool. The temperature gradient $G$ and the solidification velocity $V$ are obtained from a…

Materials Science · Physics 2017-06-12 Supriyo Ghosh , Li Ma , Nana Ofori-Opoku , Jonathan E. Guyer

Phase-field models of microstructural pattern formation during alloy solidification are commonly solved numerically using the finite-difference method, which is ideally suited to carry out computationally efficient simulations on massively…

Materials Science · Physics 2022-02-17 Kaihua Ji , Amirhossein Molavi Tabrizi , Alain Karma

The simulations of the solidification of ternary Al-Cu-Ni alloys by means of a general multi-phase-field model for an arbitrary number of phases reveal that the real microstructure can be generated by coupling the real thermodynamic…

Materials Science · Physics 2013-07-15 J. Kundin , E. Pogorelov , H. Emmerich

The near-rapid solidification conditions during additive manufacturing can lead to selection of non-equilibrium phases. Sharp interface models via interface response functions have been used earlier to explain the microstructure selection…

Materials Science · Physics 2023-03-15 V. S. Hariharan , B. S. Murty , Gandham Phanikumar
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