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In this article, we study experimentally the dispersion of colloids in a two-dimensional, time independent, Rayleigh-B\'enard flow in the presence of salt gradients. Due to the additional scalar, the colloids do not follow exactly the…

Fluid Dynamics · Physics 2026-01-14 Florence Raynal , Menghua Zhao , Romain Volk

We study analytically the joint dispersion of Gaussian patches of salt and colloids in linear flows, and how salt gradients accelerate or delay colloid spreading by diffusiophoretic effects. Because these flows have constant gradients in…

Phoresis, the drift of particles induced by scalar gradients in a flow, can result in an effective compressibility, bringing together or repelling particles from each other. Here, we ask whether this effect can affect the transport of…

Fluid Dynamics · Physics 2017-11-15 Vishwanath Shukla , Romain Volk , Mickaël Bourgoin , Alain Pumir

Predicting and controlling the transport of colloids in porous media is essential for applications ranging from contaminant remediation to drug delivery. In these complex environments, solute gradients are ubiquitous and could drive…

Soft Condensed Matter · Physics 2026-05-27 Aditya R. Pujari , Amir A. Pahlavan

Predicting and controlling the transport of colloids in porous media is essential for a broad range of applications, from drug delivery to contaminant remediation. Chemical gradients are ubiquitous in these environments, arising from…

Soft Condensed Matter · Physics 2026-04-13 Yiran Li , Mobin Alipour , Amir Pahlavan

We study numerically joint mixing of salt and colloids by a chaotic velocity field $\mathbf{V}$, and how salt inhomogeneities accelerate or delay colloid mixing by inducing a velocity drift $\mathbf{V}_{\rm dp}$ between colloids and fluid…

Gradients in temperature, concentration or electrostatic potential cannot exert forces on a bulk fluid; they can, however, exert forces on a fluid in a microscopic boundary layer surrounding a (nano)colloidal solute, resulting in so-called…

Soft Condensed Matter · Physics 2020-01-23 Jiachen Wei , Simón Ramírez-Hinestrosa , Jure Dobnikar , Daan Frenkel

In an externally imposed electrolyte (salt) concentration gradient, charged colloids drift at speeds of order one micrometre per second. This phenomenon is known as diffusiophoresis. In systems with multiple salts and 'crossed' salt…

Soft Condensed Matter · Physics 2023-11-27 Ian Williams , Patrick B. Warren , Richard P. Sear , Joseph L. Keddie

A change of solute dispersion regime with the flow velocity has been studied both at the macroscopic and pore scales in a transparent array of capillary channels using an optical technique allowing for simultaneous local and global…

Fluid Dynamics · Physics 2007-05-23 Maria Veronica D'Angelo , Harold Auradou , Catherine Allain , Jean-Pierre Hulin

Diffusiophoresis, a ubiquitous phenomenon that induces particle transport whenever solute concentration gradients are present, was recently observed in the context of microsystems and shown to strongly impact colloidal transport (patterning…

Understanding how colloids move in crowded environments is key for gaining control over their transport in applications such as drug delivery, filtration, contaminant/microplastic remediation and agriculture. The classical models of colloid…

Soft Condensed Matter · Physics 2026-04-15 Mobin Alipour , Yiran Li , Haoyu Liu , Amir A. Pahlavan

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

Soft Condensed Matter · Physics 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

We study the joint mixing of colloids and salt released together in a stagnation point or in a globally chaotic flow. In the presence of salt inhomogeneities, the mixing time is strongly modified depending on the sign of the…

Fluid Dynamics · Physics 2019-09-04 Florence Raynal , Romain Volk

Electrolytic diffusiophoresis refers to directional migration of colloids due to interfacial forces that develop in response to local electrolytic concentration ($c$) gradients. This physicochemical transport provides an efficient…

Soft Condensed Matter · Physics 2025-06-27 Kushagra Tiwari , Jitendra Dhakar , Kapil Upadhyaya , Akash Choudhary

Diffusiophoresis (DP) refers to the migration of particles driven by a solute concentration gradient in a liquid. Observations in the case of molecular neutral solutes are rather scarce, due to the low drift velocities in dilute solutions,…

Solute gradients next to an interface drive a diffusioosmotic flow, the origin of which lies in the intermolecular interactions between the solute and the interface. These flows on the surface of colloids introduce an effective slip…

Soft Condensed Matter · Physics 2025-06-09 Haoyu Liu , Amir A. Pahlavan

A standard model for the study of scalar dispersion through advection and molecular diffusion is a two-dimensional periodic flow with closed streamlines inside periodic cells. Over long time scales, the dispersion of a scalar in this flow…

Fluid Dynamics · Physics 2015-06-18 P. H. Haynes , J. Vanneste

Shear flow significantly affects the transport of swimming algae in suspension. For example, viscous and gravitational torques bias bottom-heavy cells to swim towards regions of downwelling fluid (gyrotaxis). It is necessary to understand…

Biological Physics · Physics 2015-03-20 O. A. Croze , G. Sardina , M. Ahmed , M. A. Bees , L. Brandt

We consider phoretic self-propulsion of a chemically active colloid where solute is consumed at both the colloid boundary and within the bulk solution. Assuming first-order kinetics, the dimensionless transport problem is governed by the…

Fluid Dynamics · Physics 2023-10-10 Rodolfo Brandão , David Saintillan , Ehud Yariv

Under a thermodynamic gradient, for example, the concentration or temperature gradients, the colloidal particles immersed in the solvent can exhibit a directional migration along or against the gradient -- phoresis, a cross transport…

Soft Condensed Matter · Physics 2026-03-31 Yuxing Jiao , Qing Yang , Mingcheng Yang
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