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We propose mixed quantum-classical equations of motion that unify electronic coherence and phase evolution simultaneously within the exact factorization framework. Our derivation shows that incorporating the second-order electron-nuclear…

Chemical Physics · Physics 2026-03-03 Jong-Kwon Ha , Seong Ho Kim , Seung Kyu Min

Quantum systems are dynamic systems restricted by the principles of quantum mechanics (linearity of dynamic equations, linear transformation of the wave function etc.). One suggests to investigate the quantum systems simply as dynamic…

General Physics · Physics 2007-05-23 Yuri A. Rylov

The quantum dynamics of electron-nuclear systems is analyzed from the perspective of the exact factorization of the wavefunction, with the aim of defining gauge invariant equations of motion for both the nuclei and the electrons. For pure…

Chemical Physics · Physics 2023-10-16 Rocco Martinazzo , Irene Burghardt

We consider quantum dynamics of systems with fast spatial modulation of the Hamiltonian. Employing the formalism of supersymmetric quantum mechanics and decoupling fast and slow spatial oscillations we demonstrate that the effective…

Quantum Physics · Physics 2019-04-10 Viktor Novičenko , Julius Ruseckas , Egidijus Anisimovas

Molecular science is governed by the dynamics of electrons, atomic nuclei, and their interaction with electromagnetic fields. A reliable physicochemical understanding of these processes is crucial for the design and synthesis of chemicals…

Quantum Physics · Physics 2022-03-21 Hongbin Liu , Guang Hao Low , Damian S. Steiger , Thomas Häner , Markus Reiher , Matthias Troyer

The quantum dynamic equation (QDE) of machine learning is obtained based on Schr\"odinger equation and potential energy equivalence relationship. Through Wick rotation, the relationship between quantum dynamics and thermodynamics is also…

Quantum Physics · Physics 2024-07-30 Peng Wang , Maimaitiniyazi Maimaitiabudula

The rotating-wave approximation to light-matter interactions is widely used in the quantum electrodynamics Hamiltonian; however, its validity has long been a matter of debate. In this article, we explore the impact of the rotating-wave…

Quantum Physics · Physics 2024-03-04 Yi-Ting Chuang , Liang-Yan Hsu

The algebraic reformulation of molecular Quantum Electrodynamics (mQED) at finite temperatures is applied to Nuclear Magnetic Resonance (NMR) in order to provide a foundation for the reconstruction of much more detailed molecular…

Quantum Physics · Physics 2020-09-25 Kolja Them

The master equation describing non-equilibrium one-dimensional problems like diffusion limited reactions or critical dynamics of classical spin systems can be written as a Schr\"odinger equation in which the wave function is the probability…

High Energy Physics - Theory · Physics 2016-09-06 Francisco C. Alcaraz , Michel Droz , Malte Henkel , Vladimir Rittenberg

The assumption that an ensemble of classical particles is subject to nonclassical momentum fluctuations, with the fluctuation uncertainty fully determined by the position uncertainty, has been shown to lead from the classical equations of…

General Relativity and Quantum Cosmology · Physics 2008-11-26 Michael J. W. Hall

Cooling atoms to ultralow temperatures has produced a wealth of opportunities in fundamental physics, precision metrology, and quantum science. The more recent application of sophisticated cooling techniques to molecules, which has been…

Atomic Physics · Physics 2017-09-21 John L Bohn , Ana Maria Rey , Jun Ye

The Heisenberg equations of motion for a quantum particle of mass $m$ are deduced from the infinitesimal qr-number equations of motion for the particle. The infinitesimal qr-number equations, and hence the standard quantum mechanical…

General Physics · Physics 2019-01-28 John V Corbett

The internal dynamics of strongly interacting systems and that of biomolecules such as proteins display several important analogies, despite the huge difference in their characteristic energy and length scales. For example, in all such…

Biological Physics · Physics 2015-05-30 Pietro Faccioli

Several methods in nonadiabatic molecular dynamics are based on Madelung's hydrodynamic description of nuclear motion, while the electronic component is treated as a finite-dimensional quantum system. In this context, the quantum potential…

Mathematical Physics · Physics 2024-06-04 François Gay-Balmaz , Cesare Tronci

We study the quantum dynamics of diatomic molecule driven by a circularly polarized resonant electric field. We look for a quantum effect due to classical chaos appearing due to the overlapping of nonlinear resonances associated to the…

Quantum Physics · Physics 2015-05-20 G. V. Lopez , J. G. T. Zanudo

Based on the mean-field approximation and the phase space analysis, we study the dynamics of an atom-molecule conversion system subject to particle loss. Starting from the many-body dynamics described by a master equation, an effective…

Quantum Physics · Physics 2015-05-27 B. Cui , L. C. Wang , X. X. Yi

A generalized formalism of the so-called non-adiabatic quantum molecular dynamics is presented, which applies for atomic many-body systems in external laser fields. The theory treats the nuclear dynamics and electronic transitions…

Atomic Physics · Physics 2007-05-23 Thomas Kunert , Ruediger Schmidt

Torque is ubiquitous in many molecular systems, including collisions, chemical reactions, vibrations, electronic excitations and especially rotor molecules. We present a straightforward theoretical method based on forces acting on atoms and…

Chemical Physics · Physics 2016-11-23 Rui-Qin Zhang , Yan-Ling Zhao , Fei Qi , Klaus Hermann , Michel A. Van Hove

The rotation of trapped molecules offers a promising platform for quantum technologies and quantum information processing. In parallel, quantum error correction codes that can protect quantum information encoded in rotational states of a…

In the book the mathematical methods of nuclear cross sections and phases of elastic scattering, energy and characteristics of bound states in two- and three-particle nuclear systems, when the potentials of interaction contain not only…

Nuclear Theory · Physics 2010-12-07 S. B. Dubovichenko