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We investigated thermal properties of the epoxy-based composites with a high loading fraction - up to f=45 vol.% - of the randomly oriented electrically conductive graphene fillers and electrically insulating boron nitride fillers. It was…

We propose a type of thermal interface materials incorporating insulating nanowires with partially metallic coating in insulating polymer matrix.Large thermal conductivity can be obtained due to thermal percolation while the electrical…

Applied Physics · Physics 2024-06-19 Jinxin Zhong , Qing Xi , Jixiong He , Jun Liu , Jun Zhou

Polymers are widely used in industry and in our daily life because of their diverse functionality, light weight, low cost and excellent chemical stability. However, on some applications such as heat exchangers and electronic packaging, the…

Materials Science · Physics 2018-05-16 Congliang Huang , Xin Qian , Ronggui Yang

While classical percolation is well understood, percolation effects in randomly packed or jammed structures are much less explored. Here we investigate both experimentally and theoretically the electrical percolation in a binary composite…

Materials Science · Physics 2021-04-20 Shiva Pokhrel , Brendon Waters , Solveig Felton , Zhi-Feng Huang , Boris Nadgorny

We noted that the tunneling-percolation framework is quite well understood at the extreme cases of percolation-like and hopping-like behaviors but that the intermediate regime has not been previously discussed, in spite of its relevance to…

Materials Science · Physics 2015-05-18 G. Ambrosetti , C. Grimaldi , I. Balberg , T. Maeder , A. Danani , P. Ryser

Polymers are usually considered as thermal insulators and their applications are limited by their low thermal conductivity. However, recent studies showed that certain polymers have surprisingly high thermal conductivity, some of which are…

Mesoscale and Nanoscale Physics · Physics 2018-05-17 Xiangfan Xu , Jie Chen , Jun Zhou , Baowen Li

In the work, a modified effective medium theory is constructed for calculating the effective properties of thermoelectric composites with different values of percolation thresholds. It is shown that even at concentrations beyond the…

Materials Science · Physics 2020-06-23 Snarskii Andrei , Yuskevich Pavel

The pyroresistive response of conductive polymer composites (CPCs) has attracted much interest because of its potential applications in many electronic devices requiring a significant responsiveness to changes in external physical…

Soft Condensed Matter · Physics 2024-06-11 Ettore Barbieri , Emiliano Bilotti , Yi Liu , Claudio Grimaldi

In this work we present a molecular dynamics investigation of thermal transport in a silica-gallium nitride nanocomposite. A surprising enhancement of the thermal conductivity for crystalline volume fractions larger than 5% is found, which…

The effective quasistatic conductivity of composite polymeric electrolytes is studied in terms of a hard-core--penetrable-layer model. Used to incorporate the interface phenomena (such as amorphization of the polymer matrix around filler…

Materials Science · Physics 2019-11-05 M. Ya. Sushko , A. K. Semenov

To push upper boundaries of effective thermal conductivity in polymer composites, a fundamental understanding of thermal transport mechanisms is crucial. Although there is intensive simulation research, systematic experimental investigation…

Numerical methods are developed to solve the problem of abnormal changes of current (conductivity) in polymer composite films which may be used as current, pressure or temperature sensors. General nonlinear model includes the heat equation,…

Materials Science · Physics 2014-10-31 D. V. Vlasov

The thermal properties of an epoxy-based binary composites comprised of graphene and copper nanoparticles are reported. It is found that the "synergistic" filler effect, revealed as a strong enhancement of the thermal conductivity of…

Micro/nano porous polymeric material is considered a unique industrial material due to its extremely low thermal conductivity, low density, and high surface area. Therefore, it is necessary to establish an accurate thermal conductivity…

Computational Physics · Physics 2021-08-31 Haiyan Yu , Haochun Zhang , Jinchuan Zhao , Jing Liu , Xinlin Xia , Xiaohu Wu

Thermal conduction in polymer nanocomposites depends on several parameters including the thermal conductivity and geometrical features of the nanoparticles, the particle loading, their degree of dispersion and formation of a percolating…

Applied Physics · Physics 2021-01-25 Alessandro di Pierro , Alberto Fina

In this article we discuss in detail the effective approaches to enhance the thermal conductivity in polymer composites. It is shown from numerical simulations that maximizing interfacial area between filler and polymer enhances very…

Applied Physics · Physics 2020-06-02 Vijendra Kumar , Abhishek Barnwal , R. K. Shukla , Jyoti Shakya

We report on a model of polymer nanocomposites with fibrous fillers which explicitly considers the microscopic filler features and replicates the composites as random distributions of particles interconnected via electron tunneling. By…

Disordered Systems and Neural Networks · Physics 2009-09-22 G. Ambrosetti , C. Grimaldi , T. Maeder , A. Danani , P. Ryser

A two-dimensional three-phase conducting composite with coated circular inclusions, periodically distributed in a parallelogram, is studied. The phases are assumed to be isotropic, and perfect contact conditions at the interfaces are…

We consider the problem of electron transport in segregated conductor-insulator composites in which the conducting particles are connected to all others via tunneling conductances, thus forming a global tunnelingconnected resistor network.…

Disordered Systems and Neural Networks · Physics 2012-01-23 B. Nigro , C. Grimaldi , P. Ryser

In this article, we review thermal transport in polymers with different morphologies from aligned fibers to bulk amorphous states. We survey early and recent efforts in engineering polymers with high thermal conductivity by fabricating…

Materials Science · Physics 2020-12-22 Xingfei Wei , Zhi Wang , Zhiting Tian , Tengfei Luo
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