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Spectro-temporal processing is essential in reaching ultimate per-photon information capacity in optical communication and metrology. In contrast to the spatial domain, complex multimode processing in the time-frequency domain is however…

Spectral and temporal mode matching are required for the efficient interaction of photons and quantum memories. In our previous work, we proposed a new route to spectrally compress broadband photons to achieve spectral mode matching with…

Quantum Physics · Physics 2022-03-23 Karthik V. Myilswamy , Andrew M. Weiner

The procedure for simulating the nuclear magnetic resonance spectrum linked to the spin system of a molecule for a certain nucleus entails diagonalizing the associated Hamiltonian matrix. As the dimensions of said matrix grow exponentially…

Quantum Physics · Physics 2024-10-29 Joaquín Ossorio-Castillo , Alexandre Rodríguez-Coello

A reliable and efficient computation of the entire single-particle spectrum of correlated molecules is an outstanding challenge in the field of quantum chemistry, with standard density functional theory approaches often giving an inadequate…

Chemical Physics · Physics 2021-10-08 Oliver J. Backhouse , Alejandro Santana-Bonilla , George H. Booth

Resonant spectroscopies, which involve intermediate states with finite lifetimes, provide essential insights into collective excitations in quantum materials that are otherwise inaccessible. However, theoretical understanding in this area…

Strongly Correlated Electrons · Physics 2025-09-30 Prakash Sharma , Luogen Xu , Fei Xue , Yao Wang

For complex molecules, nuclear degrees of freedom can act as an environment for the electronic `system' variables, allowing the theory and concepts of open quantum systems to be applied. However, when molecular system-environment…

Quantum Physics · Physics 2021-01-05 Angus J. Dunnett , Alex W. Chin

We present a time-domain method to detect and correct spectral alterations of signals by employing statistical characterization of waveforms and a pattern-recognition procedure using simple Artificial Neural Networks. The proposed strategy…

Signal Processing · Electrical Eng. & Systems 2022-12-29 Guillermo H. Bustos , Héctor H. Segnorile

Nonlinear spectroscopy employs a series of laser pulses to interrogate dynamics in large interacting many-body systems, and has become a highly successful method for experiments in chemical physics. Current quantum optical experiments…

Quantum Physics · Physics 2016-10-19 Frank Schlawin , Manuel Gessner , Shaul Mukamel , Andreas Buchleitner

Multispectral imaging provides valuable information on tissue composition such as hemoglobin oxygen saturation. However, the real-time application of this technique in interventional medicine can be challenging due to the long acquisition…

A universal quantum computer of large scale is not available yet, however, intermediate models of quantum computation would still permit demonstrations of a quantum computational advantage over classical computing and could challenge the…

Quantum Physics · Physics 2024-11-15 Raphael A. Abrahao , Arman Mansouri , Austin P. Lund

Spectroscopy underpins modern scientific discovery across diverse disciplines. While experimental spectroscopy probes material properties through scattering or radiation measurements, computational spectroscopy combines theoretical models…

We discuss a symmetry-adapted algebraic (or vibron) model for molecular spectroscopy. The model is formulated in terms of tensor operators under the molecular point group. In this way, we have identified interactions that are absent in…

Chemical Physics · Physics 2017-11-02 R. Bijker , A. Frank , R. Lemus , J. M. Arias , F. Perez-Bernal

Quantum computing has shown great potential in various quantum chemical applications such as drug discovery, material design, and catalyst optimization. Although significant progress has been made in quantum simulation of simple molecules,…

Quantum Physics · Physics 2023-05-30 Changsu Cao , Jinzhao Sun , Xiao Yuan , Han-Shi Hu , Hung Q. Pham , Dingshun Lv

Conducting precise electronic-vibrational dynamics simulations of molecular systems poses significant challenges when dealing with realistic environments composed of numerous vibrational modes. Here, we introduce a technique for the…

Problems in the field of open quantum systems often involve an environment that strongly influences the dynamics of excited states. Here we present a numerical method to model optical spectra of non-Markovian open quantum systems. The…

Quantum Physics · Physics 2025-05-01 Roosmarijn de Wit , Jonathan Keeling , Brendon W. Lovett , Alex W. Chin

With advanced fabrication techniques it is possible to make nanoscale electronic structures that have discrete energy levels. Such structures are called artificial atoms because of analogy with true atoms. Examples of such atoms are quantum…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 David Gunnarsson , Jani Tuorila , Antti Paila , Jayanta Sarkar , Erkki Thuneberg , Yuriy Makhlin , Pertti Hakonen

Measuring the vibronic spectrum probes dynamical processes in molecular systems. When interpreted via suitable theoretical tools, the experimental data provides comprehensive information about the system in question. For complex many-body…

Chemical Physics · Physics 2018-12-05 Sven Karsten , Sergei D. Ivanov , Sergey I. Bokarev , Oliver Kühn

Vibrational spectroscopy is a cornerstone technique for molecular characterization and offers an ideal target for the computational investigation of molecular materials. Building on previous comprehensive assessments of efficient methods…

Simulating the unitary dynamics of a quantum system is a fundamental problem of quantum mechanics, in which quantum computers are believed to have significant advantage over their classical counterparts. One prominent such instance is the…

Quantum Physics · Physics 2024-09-04 John M. Martyn , Yuan Liu , Zachary E. Chin , Isaac L. Chuang

Quantum computers promise to revolutionize our ability to simulate molecules, and cloud-based hardware is becoming increasingly accessible to a wide body of researchers. Algorithms such as Quantum Phase Estimation and the Variational…

Quantum Physics · Physics 2021-12-21 Kyle Sherbert , Frank Cerasoli , Marco Buongiorno Nardelli