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Precision spectroscopy of atomic systems is an invaluable tool for the advancement of our understanding of fundamental interactions and symmetries. Recently, highly charged ions (HCI) have been proposed for sensitive tests of physics beyond…

Direct laser cooling of molecules has made significant progress in recent years. However, the selective cooling and manipulation of molecules based on their isotopic composition, which is ubiquitous in atomic laser cooling, has not yet been…

Coherent optical bichromatic forces have been shown to be effective tools for rapidly slowing and cooling simple atomic systems. While previous estimates suggest that these forces may also be effective for rapidly decelerating molecules or…

Atomic Physics · Physics 2016-01-27 L. Aldridge , S. E. Galica , E. E. Eyler

We reported a detailed experimental study of the cold collision of Barium monofluoride (BaF) with buffer gas and the high-resolution spectroscopy relevant with direct laser cooling. BaF molecules are efficiently produced with laser ablation…

Atomic Physics · Physics 2017-03-22 Wenhao Bu , Tao Chen , Guitao Lv , Bo Yan

Organic - inorganic heterostructures (HS) combine the strong light absorption and exciton generation capabilities of organic molecules with the unique excitonic properties of layered transition metal dichalcogenides (TMDs), where the…

Materials Science · Physics 2026-01-16 Šimun Mandić , Ana Senkić , Nataša Vujičić

Optical spectroscopy of molecular radicals is an important tool in physical chemistry, and is a prerequisite for many experiments which use molecules for quantum science and precision measurement. However, even the simplest molecules have…

Chemical Physics · Physics 2025-05-07 Ashay N. Patel , Madison I. Howard , Timothy C. Steimle , Nicholas R. Hutzler

We demonstrate multiple photon cycling and radiative force deflection on the triatomic free radical strontium monohydroxide (SrOH). Optical cycling is achieved on SrOH in a cryogenic buffer-gas beam by employing the rotationally closed…

Atomic Physics · Physics 2016-06-22 Ivan Kozyryev , Louis Baum , Kyle Matsuda , Boerge Hemmerling , John M. Doyle

We demonstrate a laser frequency stabilization technique for laser cooling of Potassium atoms, based on saturated absorption spectroscopy in the C-Band optical telecommunication window, using ro-vibrationel transitions of the acetylene…

Molecules with heavy, radioactive nuclei promise extreme sensitivity to fundamental nuclear and particle physics. However, these nuclei are available in limited quantities, which challenges their use in precision measurements. Here we…

We demonstrate buffer-gas cooling, high-resolution spectroscopy and cycling fluorescence of cold barium monofluoride (BaF) molecules. Our source produces an intense and internally cold molecular beam containing the different BaF…

Atomic Physics · Physics 2020-01-13 Ralf Albrecht , Michael Scharwaechter , Tobias Sixt , Lucas Hofer , Tim Langen

We present high-resolution rovibronic spectroscopy of calcium monohydride molecular ions (CaH$^+$) co-trapped in a Coulomb crystal with calcium ions ($^{40}$Ca$^+$), focusing on rotational transitions in the $|X^1\Sigma^+, \nu" = 0>…

Atomic Physics · Physics 2026-02-10 Swapnil Patel , Kenneth R. Brown

Designing closed, laser-induced optical cycling transitions in trapped atoms or molecules is useful for quantum information processing, precision measurement, and quantum sensing. Larger molecules that feature such closed transitions are…

Atomic Physics · Physics 2023-08-23 Claire E. Dickerson , Cecilia Chang , Han Guo , Anastassia N. Alexandrova

The rotational spectrum of the formaldehyde isotopologue H$_2$C$^{17}$O was investigated between 0.56 and 1.50 THz using a sample of natural isotopic composition. In addition, transition frequencies were determined for H$_2$C$^{18}$O and…

Astrophysics of Galaxies · Physics 2019-03-13 Holger S. P. Müller , Frank Lewen

We examine the prospects for utilizing the optical bichromatic force (BCF) to greatly enhance laser deceleration and cooling for near-cycling transitions in small molecules. We discuss the expected behavior of the BCF in near-cycling…

Atomic Physics · Physics 2015-05-30 M. A. Chieda , E. E. Eyler

We report on hyperfine-resolved laser spectroscopy of the A$^2\Pi \leftarrow $X$^2\Sigma^+$ transition of MgF, relevant for laser cooling. We recorded 25 rotational transitions with an absolute accuracy of better than 20 MHz, assigned 56…

Atomic Physics · Physics 2022-04-13 M. Doppelbauer , S. C. Wright , S. Hofsäss , B. G. Sartakov , G. Meijer , S. Truppe

Four-wave-mixing-based quantum cascade laser frequency combs (QCL-FC) are a powerful photonic tool, driving a recent revolution in major molecular fingerprint regions, i.e. mid- and far-infrared domains. Their compact and frequency-agile…

The particular advantages of using the diatomic molecule radium monofluoride (RaF) as a versatile molecular probe for physics beyond the Standard Model are highlighted. i) RaF was previously suggested as being potentially amenable to direct…

Chemical Physics · Physics 2020-05-25 T. A. Isaev , R. Berger

Recently a number of diatomic and polyatomics molecules has been identified as a prospective systems for Doppler/Sisyphus cooling. Doppler/Sisyphus cooling allows to decrease the kinetic energy of molecules down to microkelvin temperatures…

Chemical Physics · Physics 2017-11-22 T. A. Isaev , A. V. Zaitsevskii , E. Eliav

Herein, we show that single molecules containing multiple optical cycling centers (CaO moieties) can exhibit superradiant phenomena. We demonstrate the accuracy of the Frenkel exciton model at describing these superradiant states via…

Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…

Atomic Physics · Physics 2009-05-24 Anh-Thu Le , R. R. Lucchese , M. T. Lee , C. D. Lin