Related papers: Apparent line tension induced by surface-active im…
We study filling phenomena in 3D wedge geometries paying particular attention to the role played by a line tension associated with the wedge bottom. Our study is based on transfer matrix analysis of an effective one dimensional model of 3D…
The surfactant-driven spreading of droplets is an essential process in many applications ranging from coating flow technology to enhanced oil recovery. Despite the significant advancement in describing spreading processes in…
Alkane mixtures are model systems where the influence of surface tension gradients during the spreading and the evaporation of wetting drops can be easily studied. The surface tension gradients are mainly induced by concentration gradients,…
Evaporation of water droplets deposited on metal and polymer substrates was studied. The evaporated droplet demonstrates different behaviors on low-pinning (polymer) and strong-pinning (metallic) surfaces. When deposited on polymer…
An interface between two miscible fluids is transient, existing as a non-equilibrium state before complete molecular mixing is reached. However, during the existence of such an interface, which typically be at short timescales, composition…
Classical hydrodynamic models predict that infinite work is required to move a three-phase contact line, defined here as the line where a liquid/vapor interface intersects a solid surface. Assuming a slip boundary condition, in which the…
Polyelectrolyte surfactant mixtures and their interactions with fluid interfaces are an important research field due to their use in technological applications. Most of the existing knowledge on these systems is based on models in which the…
Patterning solid surfaces with varying wettability is important to manage droplets in microfluidics, heat transfer and printing. Solid surface roughness poses fundamental limitations including contact-line pinning and solid friction. Here,…
Thermocapillary convection is particularly effective for the control of thin liquid film topography or for the actuation of microparticles at the liquid-air interface. Experiments with water are challenging, however, as its interface is…
The shape of a liquid drop placed in a cone is analyzed macroscopically. Depending on the values of the cone opening angle, the Young angle and the line tension four different interfacial configurations may be realized. The phase diagram in…
The three-phase contact line formed by the intersection of a liquid-vapor interface of an electrolyte solution with a charged planar substrate is studied in terms of classical density functional theory applied to a lattice model. The…
The long-range contribution to dispersion forces is known to have a major impact on the properties of inhomogeneous fluids, and its correct treatment is increasingly recognized as being a necessary requirement to avoid cutoff-related…
We present a theory for the kinetics of surfactant adsorption at the interface between an aqueous solution and another fluid (air, oil) phase. The model relies on a free-energy formulation. It describes both the diffusive transport of…
A hydrophilic liquid, such as water, forms hydrogen bonds with a hydrophilic substrate. The strength and locality of the hydrogen bonding interactions prohibit slip of the liquid over the substrate. The question then arises how the contact…
When the theoretical values of the interfacial tension -resulting from the homogeneous distribution of ionic surfactant molecules amongst the interface of emulsion drops- are plotted against the total surfactant concentration, they produce…
We study numerically and experimentally the breakup of a pendant droplet loaded with a soluble surfactant. We consider the limit in which surfactant sorption is limited only by diffusion. Surfactant transfer toward the interface is enhanced…
The impact of a heavier droplet into a deep pool of lighter liquid is investigated using three-dimensional numerical simulations. Unprecedented to any numerical simulations, we demonstrate that the heavier droplets can hang from the surface…
The formation, deformation, and break-up of liquid interfaces are ubiquitous phenomena in nature. In the present article we discuss the deformation of a liquid interface produced by optical radiation forces. Usually, the bending of such an…
We have developed a multi-phase SPH method to simulate arbitrary interfaces containing surface active agents (surfactants) that locally change the properties of the interface, such the surface tension coefficient. Our method incorporates…
We estimate the liquid-vapour surface tension from simulations of TIP4P/2005 water nanodroplets of size $N$=100 to 2880 molecules over a temperature $T$ range of 180 K to 300 K. We compute the planar surface tension $\gamma_p$, the…