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One of the major computational bottlenecks in one-body reduced density matrix (1RDM) functional theory is the evaluation of approximate 1RDM functionals and their derivatives. The reason is that more advanced approximate functionals are…

Computational Physics · Physics 2016-02-15 Klaas J. H. Giesbertz

Molecular collisions can be studied at very low relative kinetic energies, in the milliKelvin range, by merging codirectional beams with much higher translational energies, extending even to the kiloKelvin range, provided that the beam…

Chemical Physics · Physics 2015-06-05 Qi Wei , Igor Lyuksyutov , Dudley Herschbach

Vibrational properties of solids are key to determining stability, response and functionality. However, they are challenging to computationally predict at Ab-Initio accuracy, even for elemental systems. Ab-Initio methods for modeling atomic…

Materials Science · Physics 2024-06-25 Mgcini Keith Phuthi , Yang Huang , Michael Widom , Venkatasubramanian Viswanathan

The computation of the nuclear quantum dynamics of molecules is challenging, requiring both accuracy and efficiency to be applicable to systems of interest. Recently, theories have been developed for employing time-dependent basis functions…

We present a mesoscopic approach to granular crystal dynamics, which comprises a three-dimensional finite-element model and a one-dimensional regularized contact model. The approach investigates the role of vibrational-energy trapping…

Materials Science · Physics 2016-02-09 Marcial Gonzalez , Jinkyu Yang , Chiara Daraio , Michael Ortiz

In this paper, we analyze the embedding cell method, an algorithm which has been developed for the numerical homogenization of metal-ceramic composite materials. We show the convergence of the iteration scheme of this algorithm and the…

Numerical Analysis · Mathematics 2016-12-20 Wolf-Patrick Düll , Bastian Hilder , Guido Schneider

We use first-principles computational methods to examine hole trapping in organic molecular crystals. We present a computational scheme based on the tuning of the fraction of exact exchange in hybrid density functional theory to eliminate…

Materials Science · Physics 2011-06-21 Na Sai , Paul F. Barbara , Kevin Leung

In order to get insight into the connection between the vibrational dynamics and the atomic level Green-Kubo stress correlation function in liquids we consider this connection in a model crystal instead. Of course, vibrational dynamics in…

Soft Condensed Matter · Physics 2014-06-24 V. A. Levashov

For moir\'e bilayer TMD superlattices, full-configuration-interaction (FCI) calculations are presented that take into account both the intra-moir\'e-quantum-dot (MQD) charge-carrier Coulombic interactions, as well as the crystal-field…

Mesoscale and Nanoscale Physics · Physics 2024-12-17 Constantine Yannouleas , Uzi Landman

A new type of the single-molecule magnet [Mn_4 O_3 Cl_4 (O_2 CEt)_3(py)_3] forms dimers. Recent magnetic hysteresis measurements on this single-molecular magnet revealed interesting phenomena: an absence of quantum tunneling at zero…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson , Noam Bernstein

Molecular Density Functional Theory (MDFT) offers an efficient implicit- solvent method to estimate molecule solvation free-energies whereas conserving a fully molecular representation of the solvent. Even within a second order ap-…

Soft Condensed Matter · Physics 2014-06-12 Volodymyr P. Sergiievskyi , Guillaume Jeanmairet , Maximilien Levesque , Daniel Borgis

First principles calculations based on density functional theory are having an incerasing impact on our understanding of molecule-surface interactions. For example, calculations of the multi-dimensional potential energy surface have…

Materials Science · Physics 2007-05-23 O. Gulseren , D. M. Bird , S. E. Humphreys

High precision atomic data is indispensable for experiments involving studies of fundamental interactions, astrophysics, atomic clocks, plasma science, and others. We develop new parallel atomic structure codes and explore the difficulties…

Atomic Physics · Physics 2021-03-11 C. Cheung , M. S. Safronova , S. G. Porsev

Hybrid precoding plays a key role in realizing massive multiple-input multiple-output (MIMO) transmitters with controllable cost. MIMO precoders are required to frequently adapt based on the variations in the channel conditions. In hybrid…

Signal Processing · Electrical Eng. & Systems 2023-01-03 Ortal Lavi , Nir Shlezinger

Improving coherence is a fundamental challenge in quantum simulation and sensing experiments with trapped ions. Here we discuss, experimentally demonstrate, and estimate the potential impacts of two different protocols that enhance, through…

We consider collisional properties of weakly bound heteronuclear molecules (dimers) formed in a two-species mixture of atoms with a large mass difference. We focus on dimers containing light fermionic atoms as they manifest collisional…

Statistical Mechanics · Physics 2008-03-15 B. Marcelis , S. J. J. M. F. Kokkelmans , G. V. Shlyapnikov , D. S. Petrov

We describe a fast implementation of the quasi-centroid molecular dynamics (QCMD) method in which the quasi-centroid potential of mean force is approximated as a separable correction to the classical interaction potential. This correction…

Chemical Physics · Physics 2021-11-24 Theo Fletcher , Andrew Zhu , Joseph E. Lawrence , David E. Manolopoulos

Finding an optimal match between two different crystal structures underpins many important materials science problems, including describing solid-solid phase transitions, developing models for interface and grain boundary structures. In…

Materials Science · Physics 2020-02-21 Félix Therrien , Peter Graf , Vladan Stevanović

Small displacement methods have been successfully used to calculate the lattice dynamical properties of crystals. It involves displacing atoms by a small amount in order to calculate the induced forces on all atoms in a supercell for the…

Materials Science · Physics 2020-10-16 Chee Kwan Gan , Yun Liu , Tze Chien Sum , Kedar Hippalgaonkar

Spectral density functions are central to the simulation of complex many body systems. Their determination requires to make approximations not only to the dynamics but also to the underlying electronic structure theory. Here, blending…

Chemical Physics · Physics 2018-05-23 Per-Arno Plötz , Jörg Megow , Thomas Niehaus , Oliver Kühn