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Superconductivity in the family of spinel oxides is very rare owing to their robust Mott-insulating nature. About half a century ago, LiTi$_2$O$_4$ became the first reported spinel compound to show superconductivity with a 12K transition…

Superconductivity · Physics 2023-05-16 Dibyendu Dey , T. Maitra , A. Taraphder

Spinel compounds have demonstrated rich functionalities but rarely shown superconductivity. Here, we report the emergence of superconductivity in the spinel $\mathrm{MgTi}_2\mathrm{O}_4$, known to be an insulator with a complicated order.…

Spinel oxides are well-known functional materials but rarely show superconductivity. Recently, emergent superconductivity was discovered in MgTi$_2$O$_4$, which is attributed to the increase of electron doping and the suppression of orbital…

Superconductivity · Physics 2023-03-23 Qizhi Li , Abhishek Nag , Xiquan Zheng , Fucong Chen , Jie Yuan , Kui Jin , Yi Lu , Ke-Jin Zhou , Yingying Peng

LiTi2O4 is a unique material in that it is the only known oxide spinel superconductor. Although bulk studies have demonstrated that superconductivity can be generally described by the Bardeen-Cooper-Schreiffer theory, the microscopic…

Superconductivity · Physics 2010-05-27 Rajesh V. Chopdekar , Elke Arenholz , Yuri Suzuki

Magnetic field dependence of low temperature specific heat of spinel oxide superconductor LiTi_2O_4 has been elaborately investigated. In the normal state, the obtained electronic coefficient of specific heat gamma_n = 19.15 mJ/mol K2, the…

Superconductivity · Physics 2009-11-10 C. P. Sun , J. -Y. Lin , S. Mollah , P. L. Ho , H. D. Yang , F. C. Hsu , Y. C. Liao , M. K. Wu

We report pressure-induced superconductivity in the spinel CuIr$_{2}$S$_{4}$ with a transition temperature ($T_{\text{c}}$) reaching \textbf{18.2 K}, establishing a new record for this class of materials and surpassing the decades-old limit…

Transition-metal oxides offer an opportunity to explore unconventional superconductors, where the superconductivity (SC) is often interrelated with novel phenomena such as spin/charge order, fluctuations, and Fermi surface instability…

We have discovered that samples of a new material produced by special processing of crystals of Sr2RuO4 (which is known to be a triplet superconductor with Tc values ~1.0-1.5K) exhibit signatures of superconductivity (zero DC resistance and…

The associations between emergent physical phenomena (e.g., superconductivity) and orbital, charge, and spin degrees of freedom of $3d$ electrons are intriguing in transition metal compounds. Here, we successfully manipulate the…

We report the effect of Pt doping on the superconductivity in CuRh2Se4 spinel using a combined experimental and theoretical study. Our XRD results reveal that the Cu(Rh1-xPtx)2Se4 crystallizes in the structure with a space group of Fd3-m…

Superconductivity · Physics 2022-03-14 Yiyi He , Yi-Xin You , Lingyong Zeng , Shu Guo , Huawei Zhou , Kuan Li , Yanhao Huang , Peifeng Yu , Chao Zhang , Chao Cao , Huixia Luo

The evolution from superconducting LiTi2O4-delta to insulating Li4Ti5O12 thin films has been studied by precisely adjusting the oxygen pressure during the sample fabrication process. In the superconducting LiTi2O4-delta films, with the…

Superconductivity · Physics 2017-06-26 Yanli Jia , Ge He , Wei Hu , Hua Yang , Zhenzhong Yang , Heshan Yu , Qinghua Zhang , Jinan Shi , Zefeng Lin , Jie Yuan , Beiyi Zhu , Lin Gu , Hong Li , Kui Jin

The charge frustration with the mixed-valence state inherent to LiTi$_2$O$_4$, which is found to be a unique spinel oxide superconductor, is the impetus for paying special attention to reveal the existence of intriguing superconducting…

Superconductivity · Physics 2023-01-18 Huanyi Xue , Lijie Wang , Zhongjie Wang , Guanqun Zhang , Wei Peng , Shiwei Wu , Chunlei Gao , Zhenghua An , Yan Chen , Wei Li

We report the observation of superconductivity in the CuIr2Se4 spinel induced by partial substitution of Pt for Ir. The optimal doping level for superconductivity in Cu(Ir1-xPtx)2Se4 is x = 0.2, where Tc is 1.76 K. A superconducting Tc vs.…

A systematic study is performed on the spinel oxide, i.e. LiTi2O4 thin films oriented along [111]-, [110]-, and [001]-directions, to reveal the crystallographic dependence of transport properties. With decreasing temperature, the LiTi2O4…

Superconductivity · Physics 2016-08-25 Yanli Jia , Ge He , Heshan Yu , Wei Hu , Zhenzhong Yang , Jinan Shi , Zefeng Lin , Jie Yuan , Beiyi Zhu , Kai Liu , Lin Gu , Hong Li , Kui Jin

The superconducting transition temperature, Tc, of bilayers comprising underdoped La2-xSrxCuO4 films capped by a thin heavily overdoped metallic La1.65Sr0.35CuO4 layer, is found to increase with respect to Tc of the bare underdoped films.…

Superconductivity · Physics 2008-08-12 Ofer Yuli , Itay Asulin , Leonid Iomin , Gad Koren , Oded Millo , Dror Orgad

High-field electrical transport and point-contact tunneling spectroscopy were used to investigate superconducting properties of the unique spinel oxide, LiTi$_2$O$_{4-\delta}$ films with various oxygen content. We find that the upper…

$(TMTSF)_2ClO_4$ is a quasi-one dimensional organic conductor and superconductor with $T_c=1.4$K, and one of at least two Bechgaard salts observed to have upper critical fields far exceeding the paramagnetic limit. Nevertheless, the…

Strongly Correlated Electrons · Physics 2007-05-23 J. Shinagawa , Y. Kurosaki , F. Zhang , C. Parker , S. E. Brown , D. Jerome , J. B. Christensen , K. Bechgaard

We demonstrate that Mn-doping in the layered sulfides Bi_4O_4S_3 leads to stable Bi_4-x Mn_x O_4 S_3 compounds that exhibit both long-range ferromagnetism and enhanced superconductivity for 0.075 < = x < = 0.15, with a possible record…

The family of titanium oxide superconductors exhibits many intriguing phenomena comparable to cuprates and iron pnictides/chalcogenides, and thus provides an ideal platform to contrastively study the unconventional pairing mechanism of…

Unique superconductivity at surfaces/interfaces, as exemplified by LaAlO3/SrTiO3 interfaces, and the high transition temperature in ultrathin FeSe films, have triggered intense debates on how superconductivity is affected in atomic and…

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