Related papers: Strong coupling in chiral cavities: nonperturbativ…
Separation of the two mirror images of a chiral molecule, the enantiomers, is a historically complicated problem of major relevance for biological systems. Since chiral molecules are optically active, it has been speculated that strong…
Chirality, the absence of mirror symmetry, is a fundamental molecular property with far-reaching consequences from chemistry to biology. Yet enantiosensitive optical responses are very weak. Here, we introduce a theoretical framework in…
A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…
The development of new methodologies for the selective synthesis of individual enantiomers is still one of the major challenges in synthetic chemistry. Many biomolecules, and therefore many pharmaceutical compounds, are indeed chiral. While…
Strong light-matter coupling in chiral cavities has been proposed as an effective way to selectively interact with an enantiomer that shares the same handedness as the cavity's chiral mode. We show that surface plasmons supported by a…
Chirality is ubiquitous in nature and of fundamental importance in science. The present work focuses on understanding the conditions required to modify the chirality during ultrafast electronic motion by bringing enantiomers…
Distinguishing between the left- and right-handed versions of a chiral molecule (enantiomers) is vital, but also inherently difficult. Traditional optical methods using elliptically or circularly polarized light rely on weak linear effects…
Molecules that only differ by their chirality, so called enantiomers, often possess different properties with respect to their biological function. Therefore, the separation of enantiomers presents a prominent challenge in molecular biology…
Chiral excited electronic states of molecules have an intrinsic sense of handedness, or twist, and are the active component in energy efficient display technologies and in new photosynthetic routes to produce pharmaceuticals. Creating…
We consider the discriminatory interaction of a chiral molecule with circularly polarised modes inside a cavity. Starting from a generalised Jaynes--Cummings model that includes both electric and magnetic dipole couplings, we derive the…
We propose a method to realize enantiodiscrimination of chiral molecules based on quantum correlation function in a driven cavity-molecule system, where the chiral molecule is coupled with a quantized cavity field and two classical light…
Mirror symmetry is among the most fundamental concepts of physics and its spontaneous breaking at the molecular level allows chiral molecules to exist in two enantiomers that are mirror images of each other. The majority of chiro-optical…
Geometrical chirality is a universal property encountered on very different length scales ranging from geometrical shapes of living organisms to protein and DNA molecules. Interaction of chiral matter with chiral light - that is,…
A novel approach for the state-specific enantiomeric enrichment and the spatial separation of enantiomers is presented. Our scheme utilizes techniques from strong-field laser physics, specifically an optical centrifuge in conjunction with a…
Optical fields can exert forces of chiral nature on molecules and nanoparticles, which would prove extremely valuable in the separation of enantiomers with pharmaceutical applications, yet it is inherently complex, and the varied frameworks…
The coherent strong coupling of molecules with confined light fields to create polaritons - part matter, part light - is opening exciting opportunities ranging from extended exciton transport and inter-molecular energy transfer to modified…
Chiral molecules are instrumental for molecular recognition in living organisms. Distinguishing between two opposite enantiomers, the mirror twins of the same chiral molecule, is both vital and challenging. Photoelectron circular dichroism…
Distinguishing between enantiomers is crucial in the study of chiral molecules in chemistry and pharmacology. Many optical approaches rely on enantiospecific cyclic electric-dipole transitions induced by three microwave or laser beams.…
Strong coupling with circularly polarized vacuum fluctuations offers a viable route to manipulate molecular chirality. While experiments are advancing toward the realization of chiral cavities, a mean-field theoretical framework for…
We propose a method to separate enantiomers using parity violation in the Casimir-Polder potential between chiral mirrors and chiral molecules. The proposed setup involves a molecular beam composed of chiral molecules passing through a…