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A new approach for describing the effective electronic states of "atoms in compounds" to study the properties of molecules and condensed matter which are circumscribed by the operators heavily concentrated in atomic cores is proposed. Among…

Chemical Physics · Physics 2014-12-02 Anatoly V. Titov , Yuriy V. Lomachuk , Leonid V. Skripnikov

According to the correspondence principle, classical mechanics and quantum mechanics agree in the semiclassical limit, although presently it has become more and more clear how intriguing would be to try to fix a boundary between them. Here…

Chemical Physics · Physics 2019-12-18 Andrea Carati , Luigi Galgani , Fabrizio Gangemi , Roberto Gangemi

The concept of chemical bonding can ultimately be seen as a rationalization of the recurring structural patterns observed in molecules and solids. Chemical intuition is nothing but the ability to recognize and predict such patterns, and how…

Chemical Physics · Physics 2014-11-14 Piero Gasparotto , Michele Ceriotti

We derive a generalized wave-particle duality relation for arbitrary multipath quantum interference phenomena. Beyond the conventional notion of the wave nature of a quantum system, i.e., the interference fringe visibility, we introduce a…

Quantum Physics · Physics 2015-07-23 Manabendra Nath Bera , Tabish Qureshi , Mohd Asad Siddiqui , Arun Kumar Pati

Wave-particle duality, intertwining two inherently contradictory properties of quantum systems, remains one of the most conceptually profound aspects of quantum mechanics. By using the concept of energy capacity, the ability of a quantum…

Quantum Physics · Physics 2025-06-11 Yan-Han Yang , Xin-Zhu Liu , Jun-Li Jiang , Hu Chen , Xue Yang , Xiao-Feng Qian , Shao-Ming Fei , Ming-Xing Luo

A textbook interpretation of quantum physics is that quantum objects can be described in a particle or a wave picture, depending on the operations and measurements performed. Beyond this widely held believe, we demonstrate in this…

Wave-particle duality and entanglement are two fundamental characteristics of quantum mechanics. All previous works on experimental investigations in wave{particle properties of single photons (or single particles in general) show that a…

Quantum Physics · Physics 2023-03-27 Kai Wang , Daniel R. Terno , Caslav Brukner , Shining Zhu , Xiao-Song Ma

We investigate the relationships among the wave property, particle property and mixedness of quantum states based on the lp-norm coherence. By conforming that the lp-norm coherence is an appropriate measure of wave property and introducing…

Quantum Physics · Physics 2025-11-11 Wei-Ning Li , Ming Fang , Yuan-Hong Tao , Liu Sun , Shao-Ming Fei

We develop an approximate second quantization method for describing the many-particle systems in the presence of bound states of particles at low energies (the kinetic energy of particles is small in comparison to the binding energy of…

Quantum Physics · Physics 2015-06-26 Sergey V. Peletminskii , Yuriy V. Slyusarenko

We first argue that the covalent bond and the various closed-shell interactions can be thought of as symmetry broken versions of one and the same interaction, viz., the multi-center bond. We use specially chosen molecular units to show that…

Strongly Correlated Electrons · Physics 2017-06-16 Jon C. Golden , Vinh Ho , Vassiliy Lubchenko

Since pioneering works of Hanbury-Brown and Twiss, intensity-intensity correlations have been widely used in astronomical systems, for example to detect binary stars. They reveal statistics effects and two-particle interference, and offer a…

We present exact energy spectrum and eigenfunctions of the one-dimensional hydrogen atom in the presence of the minimal length uncertainty. By requiring the self-adjointness property of the Hamiltonian, we completely determine the…

Quantum Physics · Physics 2012-11-29 Pouria Pedram

Wave-particle duality relations express the fact that knowledge about the path a particle took suppresses information about its wave-like properties, in particular, its ability to generate an interference pattern. Recently, duality…

Quantum Physics · Physics 2018-09-26 Emilio Bagan , John Calsamiglia , Janos A. Bergou , Mark Hillery

Wave-particle duality is certainly one of the most curious concepts of contemporary physics, which ascribes mutually exclusive behaviors to quantum systems that cannot be observed simultaneously. In the context of two-path interferometers,…

The conditions for observation of the particle coordinates, required by logic of the Special Relativity and filtering the quantum field effects, are described. A general relation between the corresponding density of probability and the wave…

Quantum Physics · Physics 2008-07-03 V. F. Krotov

The Hanbury-Brown Twiss correlation function for two identical particles is studied for systems with cylindrical symmetry. Its shape for small values of the relative momentum is derived in a model independent way. In addition to the usual…

High Energy Physics - Phenomenology · Physics 2022-02-23 Scott Chapman , Pierre Scotto , Ulrich Heinz

The entanglement of general pure Gaussian two-mode states is examined in terms of the coefficients of the quadrature components of the wavefunction. The entanglement criterion and the entanglement of formation are directly evaluated as a…

Quantum Physics · Physics 2009-11-11 R. W. Rendell , A. K. Rajagopal

We introduce a complete set of complementary quantities in bipartite, two-dimensional systems. Complementarity then relates the quantitative entanglement measure concurrence which is a bipartite property to the single-particle quantum…

Quantum Physics · Physics 2007-05-23 Matthias Jakob , Janos A. Bergou

We discuss electronic properties and their evolution for the linear chain of $H_2$ molecules in the presence of a uniform external force $f$ acting along the chain. The system is described by an extended Hubbard model within a fully…

Materials Science · Physics 2018-08-15 Andrzej Biborski , Andrzej P. Kądzielawa , Józef Spałek

We derive two complementarity relations that constrain the individual and bipartite properties that may simultaneously exist in a multi-qubit system. The first expression, valid for an arbitrary pure state of n qubits, demonstrates that the…

Quantum Physics · Physics 2009-11-10 Tracey E. Tessier