Related papers: Observation and dynamic control of a new pathway o…
We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH$_3$OH) as an alternative route for the production of H$_3^+$ in dense clouds. The measurements were taken at…
We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar CH$_3$-X type organic molecules like methanol (CH$_3$OH), methylamine (CH$_3$NH$_2$) and acetonitrile (CH$_3$CN) as…
H$_3^+$ emission is the dominant cooling mechanism in Jupiter's thermosphere and a useful probe of temperature and ion densities. The H$_3^+$ ion is predicted to form in the thermospheres of close-in `hot Jupiters' where its emission would…
The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…
Fragmentation of highly charged molecular ions or clusters consisting of more than two atoms can proceed in an onestep synchronous manner where all bonds break simultaneously or sequentially by emitting one ion after the other. We separated…
We consider the possibility that solid molecular hydrogen is present in interstellar space. If so cosmic-rays and energetic photons cause ionisation in the solid leading to the formation of H6+. This ion is not produced by gas-phase…
We develop the theory of radiative association of an atom and a diatomic molecule within a close-coupling framework. We apply it to the formation of H$_3^-$ after the low energy collision (below 0.5 eV) of H$_2$ with H$^-$. Using recently…
Femtosecond laser pulses are utilized to drive multiple ionization in gas-phase formic acid dimers and ions are studied using time-of-flight mass spectrometry. The interaction of formic acid dimer with 200 fs linearly polarized laser pulses…
We develop a flexible one-dimensional code to model the escape of hydrogen and helium from a hot Jupiter as a result of photoionization from extreme-ultraviolet (EUV) radiation. We include stellar spectrum heating and ionization, radiative…
The triatomic hydrogen ion H3+ is one of the most important species for the gas phase chemistry of the interstellar medium. Observations of H3+ are used to constrain important physical and chemical parameters of interstellar environments.…
The product formation channels of ground state carbon atoms, C(3P), reacting with ammonia, NH3, have been investigated using two complementary experiments and electronic structure calculations. Reaction products are detected in a gas flow…
We report a femtosecond time-resolved strong-field study of ammonia borane (AB, BH3NH3) following both single and double ionization, revealing ultrafast fragmentation dynamics and hydrogen release. Mass spectrometry, combined with fragment…
The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…
Water dimer $(\text{H}_2\text{O})_2$ -- a vital component of the earth's atmosphere -- is an important prototypical hydrogen-bonded system. It provides direct insight into fundamental chemical and biochemical processes, e.g., proton…
The present study is devoted to the possibility that tri-atomic molecules were formed during or shortly after the Big Bang. For this purpose we consider the ordinary $H_3^{+}$ and $H_3$ and the primitive tri-atomic molecular system,…
The reactions of carbon atoms with dihydrogen have been investigated in liquid helium droplets at $T$ = 0.37 K. A calorimetric technique was applied to monitor the energy released in the reaction. The barrierless reaction between a single…
The formation of positive ions of antihydrogen $\bar{\rm{H}}^+$ via the three body reaction (i) $\rm{e}^+ + \rm{e}^- + \bar{\rm{H}} \rightarrow \rm{e}^- + \bar{\rm{H}}^+$ is considered. In reaction (i), free positrons $\rm{e}^+$ are…
Experimental and theoretical studies are presented on the reactivity of the radical cation isomers methanimine and aminomethylene with ethyne. Selective isomer generation is performed via dissociative photoionization of suitable neutral…
Roaming reactions involving a neutral fragment of a molecule that transiently wanders around another fragment before forming a new bond are intriguing and peculiar pathways for molecular rearrangement. Such reactions can occur for example…
The chemistry in the diffuse interstellar medium initiates the gradual increase of molecular complexity during the life cycle of matter. A key molecule that enables build-up of new molecular bonds and new molecules via proton-donation is…