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Understanding the dynamic behavior of polar fluids is essential for modeling complex systems such as electrolytes and biological media. In this work, we develop and apply a Stochastic Density Functional Theory (SDFT) framework to describe…

Soft Condensed Matter · Physics 2025-07-23 Sleeba Varghese , Pierre Illien , Benjamin Rotenberg

Density functional theory (DFT) underpins modern atomistic simulations of transition-metal surfaces. It can predict key properties linked to catalytic performance, such as adsorption energies and barrier heights, enabling new paradigms in…

Materials Science · Physics 2026-03-23 Benjamin X. Shi , Timothy C. Berkelbach

We formulate a time-dependent density-matrix functional theory (TDDMFT) approach for higher-order correlation effects like biexcitons in optical processes in solids based on the reduced two-particle density-matrix formalism within the…

Materials Science · Physics 2015-05-19 Volodymyr Turkowski , Carsten A. Ullrich , Talat S. Rahman , Michael N. Leuenberger

We present a generalized extension of the recently developed electron/hole-transfer Dynamically-weighted State-Averaged Constrained CASSCF (eDSC/hDSC) method to model charge transfer in the presence of spin-orbit coupling (SOC) for systems…

Chemical Physics · Physics 2026-02-13 Alok Kumar , Zhen Tao , Joseph E. Subotnik , Tian Qiu

Motivated by the insulating behavior of $\alpha$-(BEDT-TSeF)$_2$I$_3$ at low temperatures ($T$'s), we first performed first-principles calculations based on the crystal structural data at 30 K under ambient pressure, and we constructed a…

Mesoscale and Nanoscale Physics · Physics 2020-12-11 Daigo Ohki , Kazuyoshi Yoshimi , Akito Kobayashi

We consider a system of particles interacting via a purely repulsive, soft-core potential recently introduced to model effective pair interactions between dendrimers, which is expected to lead to the formation of crystals with multiple…

Soft Condensed Matter · Physics 2015-05-11 Davide Pini

Nonequilibrium dynamical mean-field theory (DMFT) is developed for the case of the charge-density-wave ordered phase. We consider the spinless Falicov-Kimball model which can be solved exactly. This strongly correlated system is then placed…

Strongly Correlated Electrons · Physics 2016-03-31 O. P. Matveev , A. M. Shvaika , T. P. Devereaux , J. K. Freericks

In recent years, the theoretical description of electrical noise and fluctuation-induced effects in electrolytes has gained a renewed interest, enabled by stochastic field theories like stochastic density functional theory (SDFT). Such…

Soft Condensed Matter · Physics 2025-03-25 Pierre Illien , Antoine Carof , Benjamin Rotenberg

We present dynamic density functional theory (DDFT) incorporating general inhomogeneous, incompressible, time dependent background flows and inertia, describing externally driven passive colloidal systems out of equilibrium. We start by…

Soft Condensed Matter · Physics 2024-09-11 Rory D. Mills-Williams , Benjamin D. Goddard , Andrew J. Archer

We propose a generalized Dirac fermion description for the electronic state of graphene terminated by a zigzag edge. This description admits a spin-orbit coupling needed to preserve time-reversal invariance of the zigzag confinement,…

Mesoscale and Nanoscale Physics · Physics 2011-07-20 Grigory Tkachov , Martina Hentschel

We theoretically investigate electron spin injection and spin-polarization sensitive current detection at Schottky contacts between a ferromagnetic metal and an n-type or p-type semiconductor. We use spin-dependent continuity equations and…

Condensed Matter · Physics 2009-11-10 J. D. Albrecht , D. L. Smith

The formalism of density functional theory (DFT) can be easily extended to the time dependent case (TDDFT). However, while in the static case the theory is well established and is expected to be, at least in principle, an exact approach for…

Condensed Matter · Physics 2007-05-23 Sandro Stringari

We report various phase transitions in half-Heusler TbPtBi compound using Density Functional Theory (DFT). Specifically, inclusion of spin-orbit coupling (SOC) leads to band inversion resulting in transition from the metallic to the…

Site density functional theory (SDFT) provides a rigorous framework for statistical mechanics analysis of inhomogeneous molecular liquids. The key defining feature of these systems is the presence of two very distinct interactions scales…

Statistical Mechanics · Physics 2020-11-24 Gennady N. Chuev , Marina V. Fedotova , Marat Valiev

van der Waals heterostructures assembled from atomically thin crystals are ideal model systems to study spin-orbital coupled transport because they exhibit a strong interplay between spin, lattice and valley degrees of freedom that can be…

Mesoscale and Nanoscale Physics · Physics 2021-08-18 Carmen Monaco , Aires Ferreira , Roberto Raimondi

An accurate description of the two-electron density, crucial for magnetic coupling in spin systems, provides in general a major challenge for density functional theory calculations. It affects, e.g., the calculated zero-field splitting…

Quantum Physics · Physics 2020-05-06 Timur Biktagirov , Wolf Gero Schmidt , Uwe Gerstmann

The dynamics of disordered nuclear spin ensembles are the subject of nuclear magnetic resonance studies. Due to the through-space long-range dipolar interaction generically many spins are involved in the time evolution, so that exact brute…

Materials Science · Physics 2026-05-11 Timo Gräßer , Götz S. Uhrig , Matthias Ernst

Spin Hall effects are a collection of phenomena, resulting from spin-orbit coupling, in which an electrical current flowing through a sample can lead to spin transport in a perpendicular direction and spin accumulation at lateral…

Mesoscale and Nanoscale Physics · Physics 2007-09-18 Hans-Andreas Engel , Emmanuel I. Rashba , Bertrand I. Halperin

The fractional quantum Hall effect remains a captivating area in condensed matter physics, characterized by strongly correlated topological order, which manifests as fractionalized excitations and anyonic statistics. Numerical simulations,…

Strongly Correlated Electrons · Physics 2025-10-27 Yi Yang , Yayun Hu , Zi-Xiang Hu

Schwinger boson mean-field theory (SBMFT) is a non-perturbative approach which treats ordered and disordered phases of magnetic systems on equal footing. We leverage its versatility to evaluate the spin correlators which determine…

Strongly Correlated Electrons · Physics 2023-07-07 Derek Reitz , Yaroslav Tserkovnyak